Stretching and collapse of neutral polymer layers under association with ionic surfactants

We provide experimental evidence for stretching and collapse of neutral polymer layers, already adsorbed at an oil-in-water interface, due to its interaction with surfactants. Upon stretching, the first interaction length (2L(0)) follows a power law dependence on surfactant concentration ( proportional, variant C(x)(s), where x approximately 0.5 for cationic surfactants) and collapses in the presence of salt, as a relatively weak power law (C(-y)(s), where y=0.17), in good agreement with brush length decay for polyelectrolyte brushes.     

Electronic structure of non-magnetic impurities in dilute alloys of Al

The electronic structure of substitutional non-magnetic impurities Cu, Ag, Cd, Mg, Zn, Ga, In, Ge, Si and Sn in Al is studied using density functional theory. A simple physical model is proposed to calculate the effective charges on impurities in trivalent metal Al. A linear relation is found between the effective charges on impurities and impurity vacancy capture radii. The spherical solid model (SSM) is used to account for discrete nature of the host. The impurity-induced change in charge density, scattering phase shifts, host-impurity potential, residual resistivity and impurity self-energy are calculated. Higher order scattering phase shifts are found significant and the host-impurity potential is found proportional to effective charge on impurity in its vicinity. The self-consistently calculated potential is used to calculate the electric field gradients (EFGs) at the first and second nearest neighbours (1NNs, 2NNs) of impurity. The calculated values are in agreement with the experimental results.     

Target mass dependence of charged particle multiplicity inp-nucleus interactions

The shower particle multiplicity (〈n _s 〉) in thep-nucleus interactions for different targets, in the incident energy range of ～6–500 GeV has been studied. The variation of multiplicity parameters with target mass (A) or with number of interactions that the incident hadron suffers inside the nucleus (v _A ) and with the changed particle multiplicity inp-p interactions (〈n _ch〉) has been examined in the light of the various models of multiparticle production. The present analysis favours the hydrodynamical model though some other models can not be conclusively ruled out.     

Eine Apparatur zur raschen Mikrobestimmung des pH- und pCl-Wertes von L?sungen

Ohne Zusammenfassung     

Kinetics of oxidation of hypophosphite ion by Au(III) in hydrochloric acid medium

Hypophosphite ion is oxidised by Au(III) in aqueous hydrochloric acid to give phosphorus acid and Au(I). The kinetics of the reaction has been studied spectrophotometrically in the UV region at different temperatures. The oxidation of hypophosphorous acid is first order with respect to both Au(III) and substrate. Hydrogen ion has no effect on the rate in acid media (0.15–1.0)M. The energy and entropy of activations are 128 ± 3.0kJ mol^?1 and 135.8 ± 6.5 JK^?1 mol^?1 respectively. The results are interpreted in terms of the probable formation of intermediate Au(lI).     

Steady pulse propagation in an inhomogeneously broadened resonant medium

Steady propagation of a single pulse in an inhomogeneously broadened resonant medium is studied. 2π-pulse solutions which are slightly different from those given in the literature are reported and it is shown that π-pulse solutions do not exist.     

A method for the simultaneous estimation of228Th and229Th

A simple method is reported in this paper to estimate²²⁹Th in the presence of²²⁸Th. The total activity of²²⁹Th and²²⁸Th was determined by following the alpha activity growth (using a liquid scintillation counter and proportional counter) of purified thorium samples. The activity ratio of²²⁹Th/²²⁸Th was determined by alpha spectrometry. From the initial total activity and ratio, disintegration rates of²²⁹Th and²²⁸Th were calculated. The values obtained for the activities have a precision better than ±2%.