全文获取类型
收费全文 | 164篇 |
免费 | 3篇 |
国内免费 | 2篇 |
专业分类
化学 | 129篇 |
晶体学 | 2篇 |
力学 | 10篇 |
数学 | 5篇 |
物理学 | 23篇 |
出版年
2021年 | 1篇 |
2020年 | 2篇 |
2019年 | 1篇 |
2015年 | 2篇 |
2014年 | 4篇 |
2013年 | 7篇 |
2012年 | 5篇 |
2011年 | 2篇 |
2010年 | 5篇 |
2009年 | 8篇 |
2008年 | 1篇 |
2007年 | 3篇 |
2006年 | 10篇 |
2005年 | 6篇 |
2004年 | 1篇 |
2003年 | 3篇 |
2002年 | 3篇 |
2001年 | 5篇 |
2000年 | 1篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1995年 | 7篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 10篇 |
1986年 | 4篇 |
1985年 | 10篇 |
1983年 | 5篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 5篇 |
1977年 | 2篇 |
1976年 | 10篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1973年 | 3篇 |
1972年 | 3篇 |
1971年 | 2篇 |
1966年 | 1篇 |
排序方式: 共有169条查询结果,搜索用时 336 毫秒
31.
We demonstrate low-loss chalcogenide (As(2)S(3)) waveguides on a LiNbO(3) substrate for the mid-IR wavelength (4.8 μm). Designed for single-mode propagation, they are fabricated through photolithography and dry-etching technology and characterized on a mid-IR measurement setup with a quantum cascade laser. For straight waveguides, propagation loss as low as 0.33 dB/cm is measured and low-loss bends on the order of 100 μm are simulated, with measurement results showing <3 dB for a 250 μm bend radius. The coupling efficiency is estimated to be 81%. In addition, the influences of variations in width and bend radius are also investigated. 相似文献
32.
This study investigates ultra-thin potassium chloride (KCl) films on the Si(1 0 0)-2 × 1 surfaces at near room temperature. The atomic structure and growth mode of this ionic solid film on the covalent bonded semiconductor surface is examined by synchrotron radiation core level photoemission, scanning tunneling microscopy and ab initio calculations. The Si 2p, K 3p and Cl 2p core level spectra together indicate that adsorbed KCl molecules at submonolayer coverage partially dissociate and that KCl overlayers above one monolayer (ML) have similar features in the valance band density of states as those of the bulk KCl crystal. STM results reveal a novel c(4 × 4) structure at 1 ML coverage. Ab initio calculations show that a model that comprises a periodic pyramidal geometry is consistent with experimental results. 相似文献
33.
Chung JY Cvetovich RJ McLaughlin M Amato J Tsay FR Jensen M Weissman S Zewge D 《The Journal of organic chemistry》2006,71(22):8602-8609
Compound 1 is a p38 MAP kinase inhibitor potentially useful for the treatment of rheumatoid arthritis and psoriasis. A novel six-step synthesis suitable for large-scale preparation was developed in support of a drug development program at Merck Research Laboratories. The key steps include a tandem Heck-lactamization, N-oxidation, and a highly chemoselective Grignard addition of 4-(N-tert-butylpiperidinyl)magnesium chloride to a naphthyridone N-oxide. The N-oxide exerted complete chemoselectivity via chelation in directing the Grignard addition to the alpha position as opposed to 1,4-addition on the ene-lactam. The dihydropyridyl adduct was in situ aromatized with isobutylchloroformate followed by heating in pyridine. Syntheses of Grignard precursor, N-tert-butyl-4-chloro-piperidine, were accomplished via transamination with a quaternary ammonium piperidone or via addition of methylmagnesium chloride to an iminium ion. Utilizing this chemistry, multi-kilogram preparation of compound 1 was successfully demonstrated. 相似文献
34.
35.
36.
37.
38.
Shiow-Fon Tsay Shou-Yih Wang T. J. Watson Yang 《Zeitschrift für Physik B Condensed Matter》1992,88(3):255-260
A simplified model for YBa2Cu3O7 system composed of CuO2 layers and Cu–O chains has been calculated with the long range effect of the all-neighbors Coulombice-e interactions taken into consideration. Dispersion relations have been worked out and discussed. The most striking consequence from the all-neighbors interaction is that the plasmons have, in the long wavelength limit, in addition to the usual vanishingly small two-dimensional acoustic plasmon energies which result from only nearest neighbor interactions, a non-zero
P
*
consistent with the bulk plasma frequency of a three dimensional system. The data of an optical reflectance from an EELS experiment has been refitted based on calculated results for plasmon dispersion relations in the YBa2Cu3O7 system. 相似文献
39.
Hybrid approach to the synthesis of highly luminescent CdTe/ZnS and CdHgTe/ZnS nanocrystals 总被引:2,自引:0,他引:2
Tsay JM Pflughoefft M Bentolila LA Weiss S 《Journal of the American Chemical Society》2004,126(7):1926-1927
We report the synthesis of highly luminescent CdTe/ZnS and CdHgTe/ZnS core/shell semiconductor nanocrystals (NCs). A hybrid of two synthesis routes leads to novel nanocrystal compositions and small core/shell sizes (4-5 nm) that emit in the far-red and near-infrared regions. These particles exhibit higher resistance to oxidation and photobleaching, have high quantum yields, and could be used for biological labeling and imaging. 相似文献
40.
Watson William H. Kashyap Ram P. Krawiec Mariusz Marchand Alan P. Tsay Fuh-Rong 《Structural chemistry》1994,5(1):21-35
5-Methyl-2-phenylpentacyclo[5.4.0.02, 6.03, 10.05, 9]undecane-8, 11-dione,5-methyl-2-phenylpentacyclo [5.4.0.02,6.03,10.05,9]undecane-8-one-11-ol,and 5-methyl-2-phenylpentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-diol are three cage compounds which differ only in the oxidation state at C(8) and C(11). The three compounds contain a four-membered, a six-membered, and four five-membered rings fused into a cagelike structure. An X-ray structure analysis shows the C(1)-C(7) and C(9)-C(10) bonds in the diketo cage to be 1.606(2) and 1.586(2) Å, which are significantly longer than in the other two molecules. In order to assess the effects of strain, steric, and electronic factors in these compounds, we investigated the unsubstituted parent cage compounds and a series of derivatives by molecular mechanics (MM3), AMPAC (AM1), MOPAC (PM3), and GAUSSIAN 90 calculations. These data suggest that dipolar through space interactions are responsible for the bond elongation and not a
–
* interaction, which has been postulated in parallel-systems originating from a common bond. A small degree of
–
* through-bond interaction may contribute to the lengthening in the dimethylene cage analogues. 相似文献