全文获取类型
收费全文 | 231篇 |
免费 | 10篇 |
专业分类
化学 | 152篇 |
晶体学 | 5篇 |
力学 | 11篇 |
数学 | 6篇 |
物理学 | 67篇 |
出版年
2023年 | 1篇 |
2022年 | 2篇 |
2021年 | 3篇 |
2020年 | 4篇 |
2019年 | 5篇 |
2018年 | 7篇 |
2017年 | 2篇 |
2016年 | 7篇 |
2015年 | 7篇 |
2014年 | 5篇 |
2013年 | 9篇 |
2012年 | 21篇 |
2011年 | 19篇 |
2010年 | 12篇 |
2009年 | 4篇 |
2008年 | 19篇 |
2007年 | 13篇 |
2006年 | 9篇 |
2005年 | 6篇 |
2004年 | 13篇 |
2003年 | 8篇 |
2002年 | 3篇 |
2001年 | 10篇 |
2000年 | 8篇 |
1998年 | 3篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1995年 | 1篇 |
1994年 | 6篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 7篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1980年 | 1篇 |
1975年 | 3篇 |
排序方式: 共有241条查询结果,搜索用时 375 毫秒
51.
Yusa H Shirako Y Akaogi M Kojitani H Hirao N Ohishi Y Kikegawa T 《Inorganic chemistry》2012,51(12):6559-6566
High-pressure structural phase transitions in NaNiF(3) and NaCoF(3) were investigated by conducting in situ synchrotron powder X-ray diffraction experiments using a diamond anvil cell. The perovskite phases (GdFeO(3) type) started to transform into postperovskite phases (CaIrO(3) type) at about 11-14 GPa, even at room temperature. The transition pressure is much lower than those of oxide perovskites. The anisotropic compression behavior led to heavily tilted octahedra that triggered the transition. Unlike oxide postperovskites, fluoropostperovskites remained after decompression to 1 atm. The postperovskite phase in NaCoF(3) broke down into a mixture of unknown phases after laser heating above 26 GPa, and the phases changed into amorphous ones when the pressure was released. High-pressure and high-temperature experiments using a multianvil apparatus were also conducted to elucidate the phase relations in NaCoF(3). Elemental analysis of the recovered amorphous samples indicated that the NaCoF(3) postperovskite disproportionated into two phases. This kind of disproportionation was not evident in NaNiF(3) even after laser heating at 54 GPa. In contrast to the single postpostperovskite phase reported in NaMgF(3), such a postpostperovskite phase was not found in the present compounds. 相似文献
52.
A fast vortex method has been developed by using a special-purpose computer, MDGRAPE-3. MDGRAPE-3, successor of MDGRAPE-2, has been applied to the same calculations (Sheel et al. in Comput. Fluids 36:1319–1326, 2007) and the improvement in speed was 1000 times faster when compared with the ordinary PC Xeon 5160 (3.0 GHz) for N = 106. The simultaneous use of the fast multipole method, Pseudo-particle multipole method with the special-purpose computers gives further acceleration of vortex method calculations. In addition, performances and efficiency have been investigated carefully. Further possibility has been investigated carefully and compared the present result with the previous one. 相似文献
53.
H Ohno M Anzai A Toda S Ohishi N Fujii T Tanaka Y Takemoto T Ibuka 《The Journal of organic chemistry》2001,66(14):4904-4914
Whereas palladium-catalyzed reaction of N-arylsulfonyl-alpha-amino allenes with an aryl iodide (4 equiv) in the presence of potassium carbonate (4 equiv) in DMF at around 70 degrees C affords the corresponding 3-pyrroline derivatives, the reaction in refluxing 1,4-dioxane under otherwise identical conditions yields exclusively or most predominantly the corresponding 2-alkenylaziridines bearing an aryl group on the double bond. Similarly, N-arylsulfonyl-beta-amino allenes can be also cyclized into the corresponding alkenylazetidines bearing a 2,4-cis-configuration under palladium-catalyzed cyclization conditions in DMF. 相似文献
54.
55.
The low-noise operation of fluoride-based erbium-doped fiber amplifiers (EDFA's) is demonstrated with (4)I(11/2)-level pumping for what we believe to be the first time. A noise figure as low as 3.5 +/- 0.5 dB at 1550 nm is achieved by means of 970-nm pumping. It is shown that it is possible to construct fluoride-based EDFA's with a noise figure as low as that of silica-based EDFA's. 相似文献
56.
57.
58.
59.
Kohei Yamashita Yuji Kume Seiya Ashibe Cicilia A. D. Puspita Kotaro Tanigawa Naoki Michihata Prof. Dr. Shinnosuke Wakamori Prof. Dr. Kazutada Ikeuchi Prof. Dr. Hidetoshi Yamada 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(69):16408-16421
The total synthesis of mallotusinin, which bears a tetrahydroxydibenzofuranoyl (THDBF) bridge between the 2-oxygen and 4-oxygen of glucose on corilagin with a 3,6-O-(R)-hexahydroxydiphenoyl (HHDP) bridge, is described. The key features of the total synthesis are: 1) improvements of our previously reported method to synthesize corilagin; 2) establishment of the THDBF skeleton via an unusual intramolecular SNAr reaction of an HHDP analogue, and 3) the application of a two-step bislactonization strategy for a HHDP bridge construction into the 2,4-O-THDBF bridge. Oxidative phenol coupling of 1,2,4-orthoacetyl-3,6-di-(4-O-benzylgalloyl)-α-d -glucopyranose and the orthoester cleavage of the coupling product without the pyranose-furanose ring transformation are key reactions for the improved synthesis of corilagin, which enabled the adequate supply of a corilagin precursor that was required to develop the mallotusinin synthesis. These established methods are expected to help develop the synthesis of other ellagitannins with a bridge between the two oxygens of corilagin. 相似文献
60.
Shinnosuke Takegasa Ming Min Lee Kei Tokuhiro Dr. Ryo Nakano Prof. Makoto Yamashita 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(58):e202201870
Rhodium-catalyzed acrylate synthesis from CO2 and ethylene was accomplished by using a guanidine-based NCN pincer ligand. The repulsion between pπ-electron of guanidine sidearms and occupied dπ orbital of rhodium center raised the level of d-electrons close to those of formerly known d8-ruthenium catalyst, thereby promoting the metallalactone formation from carbon dioxide and ethylene. This work fills the absence of group-9 metal based catalyst for the acrylate synthesis and provides a designing approach for pincer-ligated d8-metal catalysts to utilize pπ-dπ interaction for promoting desirable redox processes. 相似文献