全文获取类型
收费全文 | 1469篇 |
免费 | 34篇 |
国内免费 | 7篇 |
专业分类
化学 | 1150篇 |
晶体学 | 12篇 |
力学 | 10篇 |
数学 | 85篇 |
物理学 | 253篇 |
出版年
2023年 | 8篇 |
2022年 | 15篇 |
2021年 | 12篇 |
2020年 | 21篇 |
2019年 | 26篇 |
2018年 | 20篇 |
2017年 | 12篇 |
2016年 | 34篇 |
2015年 | 31篇 |
2014年 | 26篇 |
2013年 | 72篇 |
2012年 | 85篇 |
2011年 | 81篇 |
2010年 | 49篇 |
2009年 | 58篇 |
2008年 | 97篇 |
2007年 | 89篇 |
2006年 | 79篇 |
2005年 | 94篇 |
2004年 | 91篇 |
2003年 | 73篇 |
2002年 | 70篇 |
2001年 | 27篇 |
2000年 | 16篇 |
1999年 | 20篇 |
1998年 | 13篇 |
1997年 | 13篇 |
1996年 | 18篇 |
1995年 | 11篇 |
1994年 | 17篇 |
1993年 | 20篇 |
1992年 | 17篇 |
1991年 | 13篇 |
1990年 | 12篇 |
1989年 | 14篇 |
1987年 | 7篇 |
1986年 | 5篇 |
1985年 | 16篇 |
1984年 | 12篇 |
1983年 | 15篇 |
1982年 | 7篇 |
1981年 | 11篇 |
1980年 | 10篇 |
1979年 | 13篇 |
1978年 | 9篇 |
1977年 | 14篇 |
1976年 | 4篇 |
1975年 | 9篇 |
1974年 | 4篇 |
1967年 | 3篇 |
排序方式: 共有1510条查询结果,搜索用时 15 毫秒
191.
Mukai C Inagaki F Yoshida T Yoshitani K Hara Y Kitagaki S 《The Journal of organic chemistry》2005,70(18):7159-7171
[reaction: see text] Rhodium(I)-catalyzed PKR of allenynes was found to be applicable for constructing azabicyclo[5.3.0]decadienone as well as oxabicyclo[5.3.0]decadienone frameworks. In addition, a reliable procedure for constructing a 10-monosubstituted bicyclo[5.3.0]deca-1,7-dien-9-one ring system by the rhodium(I)-catalyzed PKR of allenynes was developed under the condition of 10 atm of CO. Investigation of the rhodium(I)-catalyzed cycloisomerization of 4-phenylsulfonylnona-2,3-dien-8-ynes under nitrogen atmosphere gave the corresponding cyclohexene derivatives, whereas the C1-homologated allenynes produced cycloheptene derivatives and/or bicyclo[5.2.0]nonene skeletons depending on the substitution pattern at the allenic terminus. Thus, proper choice of the starting allenynes and reaction conditions led to the selective formation of 2-phenylsulfonylbicyclo[5.3.0]deca-1,7-dien-9-ones (Pauson-Khand-type product), 3-alkylidene-1-phenylsulfonyl-2-vinylcycloheptene derivatives, and bicyclo[5.2.0]nonene frameworks. 相似文献
192.
A regio-/chemoselective silylation reaction of various functionalized terminal alkenes in the presence of titanocene dichloride, based on a newly designed dianion-type zincate, was developed. The present silylation of terminal alkenes is a powerful tool for the one-pot generation of regiocontrolled functionalized allysilanes, which are available for various transformation reactions, such as hydroxyalkylation, epoxidation, and hydroboration. 相似文献
193.
Jun-ichi Matsuo Ryosuke Okuno Kosuke Takeuchi Mizuki Kawano Hiroyuki Ishibashi 《Tetrahedron letters》2010,51(29):3736-3737
Optimized reaction conditions for the preparation of various 2-monosubstituted 3-ethoxycyclobutanones are described. 2-Monoalkyl 3-ethoxycyclobutanones were efficiently prepared by the reaction of the corresponding carboxylic acid chlorides and an excess amount of ethyl vinyl ether in the presence of diisopropylethylamine at 90 °C in a sealed tube. 2-Monoaryl 3-ethoxycyclobutanones were prepared by using 2,6-lutidine as a base in the above-mentioned procedure. 相似文献
194.
195.
196.
197.
The 7-endo Friedel-Crafts cyclization of arylpropyl vinyloxiranes was found to proceed regio- and stereoselectively to afford polyfunctional seven-membered carbocycles in excellent yields. 相似文献
198.
PVTx relationships and solid-liquid equilibria for the m-xylene-p-xylene system under high pressures
PVTx relationships of the m-xylene-p-xylene system have been measured with a glass piezometer at 283.15 and 298.15 K and pressures up to 200 MPa, or up to the point of solidification of m-xylene where this occurred at a lower pressure. Freezing pressures of m-xylene were observed as a discontinuity in the volume at increasing pressure. Approximate solid-liquid equilibria under high pressures were obtained from the freezing pressure measurement. The Carnahan-Starling-van der Waals (CS-vdW) equation of state was used to correlate the PVTx data. The solid-liquid equilibria under high pressures were calculated with the CS-vdW equation of state for the liquid phase and a simple equation of state for the solid phase. In order to test the validity of the calculation method, the solid-liquid equilibrium relationships of the benzene-cyclohexane system were also calculated. It was found that the solid molar volume should be treated as a function of temperature and/or pressure to fit the experimental data. 相似文献
199.
Tetsuya Yuasa Shinji Tanosaki Yoshiaki Sasaki Michiaki Takagi Akira Ishikawa Hiroshi Taniguchi Balasigamani Devaraj Takao Akatsuka 《Analytical sciences》2002,18(12):1329-1333
The coherent detection imaging (CDI) method uses the optical heterodyne detection technique. CW and single frequency lasers having long coherence lengths are used to exploit the maximum advantages of heterodyne detection, such as high directionality, selectivity and sensitivity. The CDI method based on optical heterodyne detection enables selective filtering of the directional coherence-retaining emergent photons, which leads to image reconstruction from projections, similar to X-ray computed tomography (CT). So far we have demonstrated the advantages and capabilities of the measurement technique for transillumination optical computed tomography in biomedicine. Here, we investigate the fundamental imaging properties of CDI method, such as its high directionality and quantitativeness, with preliminary physical phantom experiments. The results show that the CDI method satisfies the requirements for CT reconstruction under the first order approximation, and enables quantitative measurements in the sense that the relationship between estimated and actual concentration retains a satisfactory linearity. 相似文献
200.
Takeshi Ishikawa Yuji Mochizuki Shinji Amari Tatsuya Nakano Shigenori Tanaka Kiyoshi Tanaka 《Chemical physics letters》2008,463(1-3):189-194
We have developed a method named ‘fragment interaction analysis based on local MP2’ (abbreviated as FILM). This method enables us to decompose the interaction energy associated with dispersion interactions into contributions of localized occupied orbitals. In this study, the basis set dependence of the results derived from FILM was examined. The results suggested that the individual ratio of pair correlation energies of selected orbital pairs to the total dispersion interaction was almost independent of the basis set size. As an illustrative example, detailed analysis was performed on the human immunodeficiency virus type 1 protease complexed with lopinavir molecule. 相似文献