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91.
It has been considered since the first discovery of a high-T(c) cuprate that an antiferromagnetic (AF) state and a superconducting (SC) state are separated in it. However, it is very intriguing that the coexistence of the AF and SC states has recently been observed in HgBa(2)Ca(4)Cu(5)O(12+) (Hg-1245). Moreover, it is very novel that this coexistence of these two states appears if the SC-transition temperature T(c) is higher than the AF-transition temperature T(N). The mode-mode coupling theory can provide a clear elucidation of this novel phenomenon. A key point of this theory is that the AF susceptibility consists of the random-phase-approximation (RPA) term and the mode-mode coupling one. The RPA term works to make a positive contribution to the emergence of the antiferromagnetic critical point (AF-CP). In contrast, the mode-mode coupling term works to make a negative contribution to the emergence of the AF-CP. However, the growth of the SC-gap function in the d(x(2)-y(2))-wave SC state works to suppress the negative contribution of the mode-mode coupling term to the emergence of the AF-CP. Moreover, the effect of SC fluctuations near the SC-transition temperature T(c) suppresses the mode-mode coupling term of the AF susceptibility that works to hinder the AF ordering. For these two reasons, there is a possibility that the d(x(2)-y(2))-wave SC state is likely to promote the emergence of the AF-CP. Namely, the appearance of the above-mentioned novel coexistence of the AF and SC states observed in Hg-1245 can be explained qualitatively on the basis of this idea. 相似文献
92.
Tsuyoshi Satoh Takayuki Kuramoto Shingo Ogata Hiroyuki Watanabe Takahito Saitou Makoto Tadokoro 《Tetrahedron: Asymmetry》2010,21(1):1-5
Treatment of enantiomerically pure 1-chlorovinyl p-tolyl sulfoxides, derived from cyclic ketones and (R)-chloromethyl p-tolyl sulfoxide, with the lithium enolate of tert-butyl carboxylates gave adducts in quantitative yields as single diastereomers. The adducts were treated with i-PrMgCl in toluene to afford optically active bicyclo[n.1.0]alkanes bearing a tert-butyl carboxylate moiety in up to 99% enantiomeric excess through the enantioselective 1,3-CH insertion reaction of the generated chiral magnesium carbenoids. This is the first example of the enantioselective 1,3-CH insertion reaction of magnesium carbenoid. 相似文献
93.
[reaction: see text] A combined system of boron trifluoride and molecular sieves is an efficient promoter for the carbonyl-ene reaction of alpha-methylsyrenes with paraformaldehyde. The coexistence of BF3 x OEt2 and molecular sieves 4A is essential for obtaining high yields of ene products. 相似文献
94.
Ryuichi Kusaka Shohei Ohgi Kenta Shigemori Tetsuya Fujimoto 《Physical Therapy Research》2008,11(1):15-21
The aims of this study were to analyze 1) whether there was the relationship between the neonatal behavioral characteristics and amount of crying in premature infants at term age, and 2) what kind of difference between infants with high levels of crying and cry less on neonatal behavioral characteristics using the Neonatal Behavioral Assessment Scale (NBAS). The study participants consisted of 69 healthy low birth-weight infants who were admitted to the NICU at the Nagasaki University Hospital, Nagasaki, Japan. This study analyzed the relationship between NBAS scores measured neonatal behavioral performance and crying at term age. This study results indicate that there was significant statistical negative correlation between the amount of total daily crying and Habituation, Range of state, Regulation of state, and Autonomic stability cluster scores and some individual items scores (Response decrement to light, Response decrement to tactile of foot, Alert responsiveness, Examiner persistence, Motor maturity, Irritability, General irritability, Cuddliness, Consolability, Self-quieting activity, and State regulation). The high levels crying group also showed higher responsivity than less crying group in the items of Peak of excitement, Rapidity of build-up, Irritability and General irritability. In conclusion, neonatal behavioral characteristics such as poor inhibit discrete stimuli while asleep, hyper-responsivity and poor state regulation abilities were risk factors of high levels of crying. 相似文献
95.
Let X
1
,...,X
n
be a random sample drawn from distribution function F(x) with density function f(x) and suppose we want to estimate X(x). It is already shown that kernel estimator of F(x) is better than usual empirical distribution function in the sense of mean integrated squared error. In this paper we derive integrated squared error of kernel estimator and compare the error with that of the empirical distribution function. It is shown that the superiority of kernel estimators is not necessarily true in the sense of integrated squared error. 相似文献
96.
The relativistic field equations of the axistationary vacuum are derived in Ernst coordinates in full detail. The derivation of the Kerr metric is given from the field equations. 相似文献
97.
M Fujimoto Y Tsukinoki K Hirose K Kuruma R Konaka T Okabayashi 《Chemical & pharmaceutical bulletin》1980,28(5):1378-1386
98.
Hiroshi Endo Teruo Fujimoto Mitsuru Nagasawa 《Journal of Polymer Science.Polymer Physics》1971,9(2):345-362
Under steady shear flow, the normal stress and the shear stress in both dilute and concentrated solutions of monodisperse poly-α-methylstyrenes and their blends were measured. It was confirmed that the molecular theories of Rouse and Zimm extended to concentrated solutions can explain the relation between the zero-shear normal stress coefficient and the zero-shear steady-flow viscosity for both monodisperse and polydisperse systems. Shear-rate dependence of steady-flow viscosity can be understood fairly well by the molecular entanglement concept proposed by Graessley so long as the polymer is monodisperse or the amount of the higher molecular weight component is high. However, zero-shear viscosity of blended systems cannot be explained quantitatively by the theory of Graessley. The shear-rate dependence of steady-state compliance of blended systems was also observed, and it can well be explained by the theory of Tanaka, Yamamoto, and Takano which interpreted the shear rate-dependent steady-state compliance in terms of the relaxation time spectrum and its variation with shear rate. 相似文献
99.
100.
This paper describes a novel, sensitive detection system for biomolecules (DNA and proteins etc.) that is integrated in a lab-on-a-chip utilizing optical compact discs (CDs) and bio-nanofibers. The new method comprises a microchannel containing CD grating that confines fragments of unique bacterial cellulose fibrils (BC), which have nanometre scale fibers and holes. A maximum of six times higher sensitivity to detect DNA was obtained with this CD and BC system compared to a conventional method. We also demonstrate an effective light-confining effect for biological application with the new method. 相似文献