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排序方式: 共有384条查询结果,搜索用时 9 毫秒
91.
Adriano D'Addio Juraj Malinčik Dr. Olaf Fuhr Prof. Dr. Dieter Fenske Prof. Dr. Daniel Häussinger Prof. Dr. Marcel Mayor 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(56):e202201678
Orthogonal joints, understood as connections with an angle of 90°, were introduced in the design of the “Geländer” model compounds 1 and 2 . The banister, consisting of a conjugated carbazole dimer linked by either 1,3-butadiyne ( 2 ) or a single thiophene ( 1 ), wraps around an axis composed of a phthalimide dimer due to the dimensional mismatch of both subunits, which are interconnected by phenylene rungs. The “Geländer” structure was assembled from a monomer comprising the 1,4-diaminobenzene rung with one amino substituent as part of a 4-bromo phthalimide subunit forming the orthogonal junction to the axis, and the other as part of a masked 2-ethynyl carbazole as orthogonal joint to the banister. The macrocycle was obtained by two sequential homocoupling steps. A first dimerization by a reductive homocoupling assembled the axis, while an oxidative acetylene coupling served as ring-closing reaction. The formed butadiyne was further derivatized to a thiophene, rendering all carbons of the model compound sp2 hybridized. Both helical structures were fully characterized and chirally resolved. Assignment of the enantiomers was achieved by simulation of chiroptical properties and enantiopure synthesis. 相似文献
92.
Garti Shimon Hayut Yair Horowitz Haim Magidor Menachem 《Periodica Mathematica Hungarica》2022,84(2):250-258
Periodica Mathematica Hungarica - We study the Galvin property. We show that various square principles imply that the cofinality of the Galvin number is uncountable (or even greater than $$\aleph... 相似文献
93.
We introduce a model-theoretic characterization of Magidor cardinals, from which we infer that Magidor filters are beyond ZFC-inconsistency. 相似文献
94.
95.
Amir Goldbourt Shifi Kababya Shimon Vega P. K. Madhu 《Solid state nuclear magnetic resonance》2000,18(1-4)
A rigorous examination of the various multiple-quantum magic angle spinning sequences is carried out with reference to sensitivity enhancement in the isotropic dimension and the lineshapes of the corresponding MAS peaks in the anisotropic dimension. An echo efficiency parameter is defined here, which is shown to be an indicator of the performance aspects of the various sequences. This can be used in the design of further new experiments in this field. A consequence of such a systematic analysis has been the combination of a spin-lock pulse for excitation of multiple-quantum coherences and an amplitude-modulated pulse for their conversion to observable single-quantum coherences. This approach has resulted in an improved performance over other sequences with respect to both the anisotropic lineshapes and the isotropic intensities. 相似文献
96.
97.
We theoretically demonstrate that, for a given diameter of the core-pumped metal-dielectric nanowire, there is an optimum thickness of the metallic cladding that provides the maximum propagation length of the lowest-order surface plasmon polariton (SPP) modes. If the nanowire is fabricated with the optimum cladding thickness, the lowest pumping power is required to fully compensate for the SPP propagation losses. We also show that a strong confinement of SPPs within the nanowire can be achieved, but at the expense of either high optical gains or large nanowire diameters. For example, a gain of 565 cm(-1) would suffice to make up for the decay of SPPs in a 250-nm-thick silver-GaAs nanowire; the confinement of optical power within such nanowires exceeds 90%, which makes them ideal interconnects for nanophotonic circuitry. 相似文献
98.
Shimon Garti 《Comptes Rendus Mathematique》2018,356(4):351-359
We prove the consistency of ? with the negation of Galvin's property. On the other hand, we show that superclub implies Galvin's property. We also prove the consistency of with for a supercompact cardinal κ. 相似文献
99.
Balaraman E Gnanaprakasam B Shimon LJ Milstein D 《Journal of the American Chemical Society》2010,132(47):16756-16758
The selective, direct hydrogenation of amides to the corresponding alcohols and amines with cleavage of the C-N bond was discovered. The expected products of C-O cleavage are not formed (except as traces in the case of anilides). The reaction proceeds under mild pressure and neutral, homogeneous conditions using a dearomatized, bipyridyl-based PNN Ru(II) pincer complex as a catalyst. The postulated mechanism involves metal-ligand cooperation by aromatization-dearomatization of the heteroaromatic pincer core and does not involve hydrolytic cleavage of the amide. The simplicity, generality, and efficiency of this environmentally benign process make it attractive for the direct transformations of amides to alcohols and amines in good to excellent yields. 相似文献
100.
Using the technology of ethyl alcohol production as an example, a scheme of the transformation of admixed components in rectifying
columns was considered and procedures for the minimization of negative side processes by chemical and instrumental-technological
methods were offered. 相似文献