Specific heat of tin nanoparticles, which are embedded in porous glass with average pore size ~7 nm, has been investigated in the low-temperature region in magnetic fields up to 2 T. The temperatures of the transition into the superconducting state in various magnetic fields have been determined for tin nanostructured in porous glass. The Hc-Tc phase diagram has been constructed. The upper critical field has been evaluated and the electronic specific heat coefficient and the Debye temperature have been refined. These results have been discussed within the structural model of tin nanoparticles in porous glass. 相似文献
Some results of AC loss measurements are presented for 19, 61, 127-filamentary Bi-2223/Ag tapes prepared by the ‘powder-in-tube' method. All measurements have been made at T=77 K under sinusoidal transport current with frequency in the range of 30–600 Hz and the current amplitude up to 30 A. The measurements have been carried out both in self field conditions and at the external magnetic field applied to the tape at the different angles. The dependencies of the AC losses on current amplitude and frequency have been obtained. It is found that for all tapes the current amplitude dependencies of the AC losses show good agreement with the Norris prediction for an elliptical or strip geometry. The AC loss dependencies on frequency were linear. The measurements of AC losses in external magnetic field show that the change of AC losses is only through the change of the critical current. So the transport AC losses in the tapes are the ‘saturation losses' that is they are different from classic hysteresis losses. 相似文献
Magnetic susceptibility, heat capacity, thermal expansion, and resistivity of a high-quality single crystal of MnSi were carefully
studied at ambient pressure. The calculated change in magnetic entropy in the temperature range 0–30 K is less than 0.1R, a low value that emphasizes the itinerant nature of magnetism in MnSi. A linear temperature term dominates the behavior
of the thermal expansion coefficient in the range 30–150 K, which correlates to a large enhancement of the linear electronic
term in the heat capacity. A surprising similarity between variation of the heat capacity, the thermal expansion coefficient,
and the temperature derivative of resistivity through the phase transition in MnSi is observed. Specific forms of the heat
capacity, thermal expansion coefficient, and temperature derivative of resistivity at the phase transition to a helical magnetic
state near 29 K are interpreted as a combination of sharp first-order features and broad peaks or shallow valleys of yet unknown
origin. The appearance of these broad satellites probably hints at a frustrated magnetic state in MnSi slightly above the
transition temperature. Present experimental findings bring the current views on the phase diagram of MnSi into question.
The text was submitted by the authors in English. 相似文献
The low-temperature specific heat of a La1.85Sr0.15CuO4 superconducting single crystal was investigated in magnetic fields up to 8 T and with four orientations — in the a-b plane (along the (100) and (110) directions) and at angles of 45° and 90° with respect to the a-b plane (along the (103) and (001) directions). Anisotropy was observed in the field dependence of the specific heat in the
a-b plane. The specific heat was found to be minimum with the field oriented in the direction of the a axis and maximum with the field oriented in a direction making an angle of 45° with the a axis. This can be explained by the anisotropy of the energy gap, whose minimum lies along the (110) direction. For all orientations
of the magnetic field the specific heat of the mixed state at low temperatures is a nonlinear function of the magnetic field
strength.
Pis’ma Zh. éksp. Teor. Fiz. 66, No. 11, 683–687 (10 December 1997) 相似文献
There are many reports1 of the pyrolysis of fluorinated organic compounds, including the defluorination of cyclic fluorocarbons over iron to give aromatic compounds. Extending this technique we have investigated the flow pyrolysis of some readily accessible unsaturated fluorocarbons, such as I, II, and III, and found these to be synthetically useful routes to fluorinated dienes, cyclobutenes, and furans. Pyrolyses were carried out using a nitrogen flow over platinum, iron or caesium fluoride heated at 430–700°. The various products can all be rationalized in terms of intermediate allylic radicals, and the solid substrate influences which allylic radicals are formed.We are also investigating the chemistry of those now accessible compounds, such as IV, V, and VI, and some of the preliminary results are described. For example the fluoride ion induced dimerisation of IV gave two major products VII and VIII via a particular interesting mechanism.相似文献
The impact of the composition of natural deep eutectic solvents (NADES) and extraction conditions on the simultaneous extraction of hydrophilic ascorbic acid (AA), phlorotannins (TPhC), and lipophilic fucoxanthin (FX) from Fucus vesiculosus was investigated for the first time. In biological tests, the NADES extracts showed the promising ability to scavenge DPPH radicals. A positive correlation was observed between DPPH scavenging activity and AA, TPhC, and FX contents. We calculate the synergistic effect of antioxidants extracted by NADES from F. vesiculosus based on the mixture effect (ME). The addition of 30% water to the NADES and the prolongation of sonication time from 20 min up to 60 min were favorable for the ME. The ME for extracts with the NADES was increased by two folds (ME > 2). In contrast, conventional extraction by maceration with steering at 60 °C does not lead to the synergistic effect (ME = 1). It is notable that the NADES provides high stability and preserves the antioxidant activity of the extracts from F. vesiculosus during storage. 相似文献
The heat capacity of Zr70Pd30 and Zr80Pt20 icosahedral quasicrystals and their amorphous counterparts is studied in the temperature range 1.5–500 K in order to establish a correlation between the short-range atomic order and the physical properties of these compounds. A comparison of the data made it possible to reveal changes in the vibrational spectra within the low-and high-energy ranges, as well as in the density of states, superconducting characteristics, electron-phonon interaction, and anharmonicity of the lattice thermal vibrations and to calculate the main average frequencies (moments) characterizing the vibrational spectra. The lower superconducting transition temperature Tc of the quasicrystals as compared to that of the amorphous counterparts can be associated with the decrease in the density of states on the Fermi surface, the hardening of the phonon spectrum, and the weakening of the electron-phonon coupling. 相似文献
JPC – Journal of Planar Chromatography – Modern TLC - A selective high-performance thin-layer chromatographic (HPTLC) method for the quantification of vitamin D3 was developed and... 相似文献
Two chromatographic methods, high-performance TLC (HPTLC) and HPLC, were developed and used for separation and quantitative determination of chlorogenic acid in green coffee bean extracts. For HPTLC silica gel Kieselgel 60 F 254 plates with ethyl acetate/dichlormethane/formic acid/acetic acid/water (100:25:10:10:11, v/v/v/v/v) as mobile phase were used. Densitometric determination of chlorogenic acid by HPTLC was performed at 330 nm. A gradient RP HPLC method was carried out at 330 nm. All necessary validation tests for both methods were developed for their comparison. There were no statistically significant differences between HPLC and HPTLC for quantitative determination of chlorogenic acid according to the test of equality of the means. 相似文献