Through-space R3-HETCOR experiments between spin-1/2 and half-integer quadrupolar nuclei in solid-state NMR

We present several new methods that allow to obtain through-space 2D HETCOR spectra between spin-1/2 and half-integer quadrupolar nuclei in the solid state. These methods use the rotary-resonance concept to create hetero-nuclear coherences through the dipolar interaction instead of scalar coupling into the HMQC and refocused INEPT experiments for spin n/2 (n>1). In opposite to those based on the cross-polarization transfer to quadrupolar nuclei, the methods are very robust and easy to set-up.     

Λ型双模激光的朗之万理论

采用朗之万激光理论讨论型双模激光近阈运行的模式耦合特性，双模既可以呈相互抑制和相互支持，又可以呈现一模被抑制另一模被支持以及一模或双模既不被支持又不被抑制。耦合特性不仅取决于双模失谐量，而且与原子三能级初始布居紧密相关。     

2，5─哌嗪二酮与α，β─不饱和醛反应研究

综合运用了多种波谱学方法及化学手段确证并归属了２，５－哌嗪二酮与α，β－不饱和醛在超声波分散金属钾及双季铵盐作用下反应产物的立体化学与核磁共振信号，为研究这个反应提供了有用的信息．     

用CCD分析光源的辐射光谱

本文介绍了利用光电图象技术对光源光谱进行分析的工作。利用ＣＣＤ线阵器件和计算机，我们获得了黑体、灰体及单色光源的光谱特性以及有关数据。     

Study of synthetic diamonds by dynamic nuclear polarization-enhanced13C nuclear magnetic resonance spectroscopy

Four I_b-type synthetic diamond crystals were studied by dynamic nuclear polarization (DNP)-enhanced high resolution solid state¹³C nuclear magnetic resonance (NMR) spectroscopy. The home built DNP magic-angle-spinning (MAS) NMR spectrometer operates at a field strength of 1.9 T and the highest DNP enhancement factor of synthetic diamonds came near to 10³. Comparing with I_b-type natural diamonds, the¹³C NMR linewidths of synthetic diamonds in static spectra are broader. The¹³C spin-lattice relaxation time and DNP polarization time of synthetic diamond are shorter than those of I_b-type natural diamond. From the hyperfine structure of the DNP enhancement curve, four kinds of nitrogen-centred free radicals could be identified in synthetic diamond.     

CCD自动调光设计

介绍一种在89C51单片机的智能控制系统中,用A/D536等器件组成的真有效值电路作为CCD视频信号的检测电路,采取程序控制方式对天空背景下的目标进行自动调光控制.     

BP神经网络用于肝炎患者舌诊近红外光谱的研究

为了对肝炎患者进行快速无创检测,用BP人工神经网络(ANN)方法在健康人与肝炎患者之间对人体舌面近红外光谱的反射率的关系进行关联方面的研究。分别采集了健康人和肝炎患者的舌左边、舌右边、舌下左边络脉、舌下右边络脉以及舌尖各部位各25例受试者的光谱数据,构造了一个3层神经网络结构,将所采集的各光谱数据进行归一化反射率预处理后作为神经网络的输入,建立了BP神经网络模型,分别选取对应的各个部位的40例作为训练样本集,用剩下的10例未知的样本进行预测,各部位测试的结果其相对偏差均在0.2以下,分类正确率为100%,达到满意的预测精度。结果表明提出的BP神经网络用于光谱舌诊进行无创检测识别不同病证提供了重要的参考价值。