全文获取类型
收费全文 | 1882篇 |
免费 | 52篇 |
国内免费 | 5篇 |
专业分类
化学 | 1158篇 |
晶体学 | 34篇 |
力学 | 30篇 |
综合类 | 1篇 |
数学 | 64篇 |
物理学 | 652篇 |
出版年
2023年 | 6篇 |
2022年 | 6篇 |
2021年 | 13篇 |
2020年 | 33篇 |
2019年 | 24篇 |
2018年 | 20篇 |
2017年 | 12篇 |
2016年 | 31篇 |
2015年 | 30篇 |
2014年 | 31篇 |
2013年 | 84篇 |
2012年 | 86篇 |
2011年 | 122篇 |
2010年 | 84篇 |
2009年 | 67篇 |
2008年 | 124篇 |
2007年 | 127篇 |
2006年 | 149篇 |
2005年 | 115篇 |
2004年 | 96篇 |
2003年 | 88篇 |
2002年 | 79篇 |
2001年 | 32篇 |
2000年 | 35篇 |
1999年 | 22篇 |
1998年 | 17篇 |
1997年 | 19篇 |
1996年 | 11篇 |
1995年 | 16篇 |
1994年 | 32篇 |
1993年 | 28篇 |
1992年 | 33篇 |
1991年 | 10篇 |
1990年 | 23篇 |
1989年 | 25篇 |
1988年 | 17篇 |
1987年 | 14篇 |
1986年 | 22篇 |
1985年 | 19篇 |
1984年 | 12篇 |
1983年 | 10篇 |
1982年 | 9篇 |
1981年 | 10篇 |
1980年 | 12篇 |
1979年 | 11篇 |
1978年 | 12篇 |
1977年 | 7篇 |
1974年 | 8篇 |
1973年 | 6篇 |
1969年 | 9篇 |
排序方式: 共有1939条查询结果,搜索用时 31 毫秒
151.
152.
Takashi Aoki Yasuhiro Kombu Yasuo Ohno 《Proceedings of the American Mathematical Society》2008,136(2):387-395
A generating function for specified sums of multiple zeta values is defined and a differential equation that characterizes this function is given. As applications, some relations for multiple zeta values over the field of rational numbers are discussed.
153.
Koichi Aoki Mengjuan Li Jingyuan Chen Toyohiko Nishiumi 《Electrochemistry communications》2009,11(2):239-241
Water droplets were formed spontaneously at the interface of the 2-nitrophenyloctyl ether and aqueous phases on the oil phase side when the oil contained tetraalkylammonium chloride without surfactants. The droplets, less than some micrometers in diameter, gathered at the interface. The number density of the droplets was proportional to the concentration of tetraethylammonium chloride, and hence this salt should be responsible for the formation of the droplets as a surfactant. When positive voltage was applied to the aqueous phase against the oil, the droplets departed from the interface toward the oil bulk. The droplets should be negatively charged by chloride. The adsorption model of the salt was suggested, in which chloride is immobilized at the interface on the aqueous side electrostatically with tetraethylammonium ion on the oil side. 相似文献
154.
155.
Different initial cell concentrations of a recombinant flocculent Saccharomyces cerevisiae MA-R4 were evaluated for their effects on xylose fermentation and glucose–xylose cofermentation. A high initial cell concentration greatly increased both the substrate utilization and ethanol production rates. During xylose fermentation, the highest rates of xylose consumption (2.58 g/L h) and ethanol production (0.83 g/L h) were obtained at an initial cell concentration of 13.1 g/L. During cofermentation, the highest rates of glucose consumption (14.4 g/L h), xylose consumption (2.79 g/L h), and ethanol production (6.68 g/L h) were obtained at an initial cell concentration of 12.7 g/L. However, a high initial cell density had no positive effect on the maximum ethanol concentration and ethanol yield mainly due to the increased amount of by-products including xylitol. The ethanol yield remained almost constant (0.34 g/g) throughout xylose fermentation (initial cell concentration range, 1.81–13.1 g/L), while it was slightly lower at high initial cell concentrations (9.87 and 12.7 g/L) during cofermentation. The determination of the appropriate initial cell concentration is necessary for the improvement of substrate utilization and ethanol yield. 相似文献
156.
Eiji Hashimoto Yuichi Seshimo Keita Sasanuma Yuichiro Aoki Hitoshi Kanazawa Yuji Ike Seiji Kojima 《Journal of Thermal Analysis and Calorimetry》2010,99(1):45-50
The fragility of ethylene glycol and glucose aqueous solution systems has been investigated by temperature-modulated differential
scanning calorimetry (TMDSC). The frequency and temperature dependences of complex specific heat have been observed in the
vicinity of a glass-transition temperature T
g
. It is shown that the value of the fragility index m can be determined from the temperature dependence of the α-relaxation times observed by TMDSC. We have also studied the elastic
properties of these aqueous solutions by micro-Brillouin scattering, and determined these relaxation times of elastic properties
in the gigahertz range. 相似文献
157.
Satoshi Motodate Takuya Kobayashi Mikio Fujii Prof. Tomoyuki Mochida Dr. Taichi Kusakabe Shigeki Katoh Prof. Hiroyuki Akita Prof. Keisuke Kato 《化学:亚洲杂志》2010,5(10):2221-2230
Bis(oxazoline)‐palladium(II) catalyzed carbonylation of homopropargyl alcohols afforded acyclic methoxyacrylate 2 and 6‐membered lactone 3a , 3b , 3d , 3e , 3f , 3g , 3h , 3i , 3j , 3k in good combined yield. In the case of propargyl alcohols, 5‐membered lactones 3p , 3q , 16 were obtained in moderate yields. The one‐pot synthesis of kawa lactones 3a , 3r , 3s and formal synthesis of dihydroxycystothiazole A and dihydroxycystothiazole C are presented. To elucidate the stereochemistry of (+)‐annularin G and (?)‐annularin H, the first asymmetric syntheses of these natural products were achieved. 相似文献
158.
Kobayashi S Waki T Nakanishi I Matsumoto K Anzai K 《Chemical & pharmaceutical bulletin》2010,58(11):1442-1446
New potent antioxidants conjugating the catechol (=pyrocatechol; pyrCat) group to two N-termini of modified double-stranded tyrosine residues were synthesized and showed radical scavenging activity with 2,2-diphenyl-1-picrylhydrazyl radical (DPPH radical, DPPH˙) as a free radical model, second-order rate constants for the DPPH˙ scavenging reaction, and the results from electron spin resonance (ESR) studies. It was found that the tyrosine (Tyr) residue and pyrCat containing new antioxidants developed in the study have about 3-20 times more potent antioxidative activity than Trolox, pyrCat, and L-ascorbic acid (VC). In order to elucidate the relationship between antioxidant activity and the molecular orbital states, and to design potent antioxidants we present an interesting approach using an absolute hardness (η)-absolute electronegativity (χ) diagram based on chemical hardness. It was shown that quantum chemicals were required to develop potent antioxidants. 相似文献
159.
Adare A Afanasiev S Aidala C Ajitanand NN Akiba Y Al-Bataineh H Alexander J Angerami A Aoki K Apadula N Aphecetche L Aramaki Y Asai J Atomssa ET Averbeck R Awes TC Azmoun B Babintsev V Bai M Baksay G Baksay L Baldisseri A Barish KN Barnes PD Bassalleck B Basye AT Bathe S Batsouli S Baublis V Baumann C Bazilevsky A Belikov S Belmont R Bennett R Berdnikov A Berdnikov Y Bhom JH Bickley AA Blau DS Boissevain JG Bok JS Borel H Boyle K Brooks ML Buesching H Bumazhnov V Bunce G Butsyk S Camacho CM 《Physical review letters》2011,107(14):142301
We present measurements of J/ψ yields in d+Au collisions at sqrt[s(NN)]=200 GeV recorded by the PHENIX experiment and compare them with yields in p+p collisions at the same energy per nucleon-nucleon collision. The measurements cover a large kinematic range in J/ψ rapidity (-2.2相似文献
160.
We studied the quantum interference of electrons in the Bi (p(x), p(y)) orbital-derived j = 1/2 spin-split surface states at Bi/Ag(111)√3 × √3 surfaces of 10 monolayer thick Ag(111) films on Si(111) substrates. Surface electron standing waves were observed clearly at the energy (E) below the intersection of the two spin-split downward dispersing parabola bands (E(x)). The E dependence of the standing wave pattern reveals the dispersion as the average of the two spin-split surface bands due to the interference between |(k + Δ), ↑> and |-(k - Δ), ↑> [or (|(k - Δ), ↓>) and |-(k + Δ), ↓>] states. In contrast, it was impossible to deduce the dispersion from the standing wave pattern at E ≥ E(x) because the surface electron cannot find its backscattered state with the same spin polarization. 相似文献