Photoelectron spectroscopy of solids using gas-phase spectrometers

By using continuous deposition of metal surfaces or a continuous scrape technique the ultraviolet photoelectron spectra of clean polycrystalline Zn, Cd, Sn and Pb have been obtained using spectrometers originally designed for gas-phase work. Spectra are calibrated with respect to an internal gas-phase standard. A study of the oxidation of lead is presented to illustrate the applicability of these techniques to adsorption studies. A second oxide in addition to the established orthorhombic form of PbO is observed for low O₂ doses.     

A projection model and a rational policy for the supply and demand of human resources from an educational institution

A projection model based on the concept of fertility and mortality of a closed population was constructed as an analytical tool to investigate the supply of graduates (human resources) in an academic discipline from an educational institution. Student generation, drop-out rate, and transfer rate are defined to construct a projection matrix. This matrix, along with trends of survival and transfer rates, projects the class distribution (first year class size, size of each successive class, and the size of the graduating class) at any future year. With a knowledge of population growth rate and therefore the projected need, this model serves as an aid to the administration to discern the relations among the decision factors and to formulate a rational policy of supplying human resources to meet future need. The model is simple, makes use of available statistical data, and can easily be programmed on a desk computer.     

An Approach to Linear Scalable DH-PHEMT Model for Millimeterwave Application

This paper describes a scalable small-signal equivalent circuit for 0.25 m gatelength Double Heterojunction delta-doped PHEMTs. The scaling rules for all elements except the pad capacitances and bondwire inductances have been determined. Good agreement is obtained between simulation results and measured results for 2 times 20 m , 2 times 40 m, 2 times 60 m, 2 times 100 m gate width (number of gate fingers times unit gate width) DH PHEMT.     

Frequency resolution and amplitude accuracy of the coherent optical spectrum analyzer with a swept local oscillator

We present a model for coherent optical spectrum analysis that relates the key parameters of frequency resolution, power uncertainty, and sweep speed. The theoretical model is compared with experimental results obtained from spectral measurements of an external-cavity laser.     

Dipole orientational order at liquid/vapor surfaces

We present ellipsometric observations of the orientational order alpha(2) of highly polar molecules at the noncritical liquid/vapor surface of critical polar+nonpolar mixtures. The dipoles, which are repelled from the interface via interactions with their image dipoles, are preferentially oriented with their axes parallel to the surface and possess an orientational order which is well described by alpha(2) approximately -t(2beta)D+(z/xi), where t=[T-T(c)]/T(c) is the reduced temperature, beta=0.328 is a critical exponent, and D+ is a universal function of the dimensionless depth z/xi with surface correlation length xi.     

Propagation of nonparaxial beams with a modified Arnoldi method

We have developed a modified Arnoldi method that includes a complex square-root approximation, which excels at modeling the propagation of highly diverging beams in various media. Simulations of one transverse dimensional beam with an ultranarrow width and of cylindrical Gaussian beams with various divergence angles reveal the strength of this nonparaxial-beam propagation method.     

Electrochemical fluorescence switching properties of conjugated polymers composed of triphenylamine,fluorene, and cyclic urea moieties

The study of the electrochemical fluorescence switching properties of the conjugated copolymers containing fluorene, triphenylamine, and 1,3‐diphenylimidazolidin‐2‐one moieties is reported. The polymers show high fluorescence quantum yields, excellent thermal stability, and good solubility in polar organic solvents. While the polymer emits blue light under UV irradiation, the fluorescence intensity is quenched upon electrochemical oxidation. The fluorescent behavior can be reversibly switched between nonfluorescent (oxidized) state and strong fluorescence (neutral) state with a high contrast ratio (I_f/I_f0) of 16.3. The role of the electrochemical oxidation of the triphenylamine moieties is to generate the corresponding radical cations that lead to fluorescence quenching in the solid matrix. © 2012 Wiley Periodicals, Inc. J. Polym. Sci. Part A: Polym Chem, 2012