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801.
Xu-Tao Zeng Ziyu Chen Cong Chen Bin-Bin Liu Xian-Lei Sheng Shengyuan A. Yang 《Frontiers of Physics》2023,18(1):13308
Dirac semimetals (DSMs) are an important class of topological states of matter. Here, focusing on DSMs of band inversion type, we investigate their boundary modes from the effective model perspective. We show that in order to properly capture the boundary modes, k-cubic terms must be included in the effective model, which would drive an evolution of surface degeneracy manifold from a nodal line to a nodal point. Sizable k-cubic terms are also needed for better exposing the topological hinge modes in the spectrum. Using first-principles calculations, we demonstrate that this feature and the topological hinge modes can be clearly exhibited in β-CuI. We extend the discussion to magnetic DSMs and show that the time-reversal symmetry breaking can gap out the surface bands and hence is beneficial for the experimental detection of hinge modes. Furthermore, we show that magnetic DSMs serve as a parent state for realizing multiple other higher-order topological phases, including higher-order Weyl-point/nodal-line semimetals and higher-order topological insulators. 相似文献
802.
从三维弹性力学基本方程出发,通过假设自由边的边界位移函数,建立了正交异性层合板的状态方程,给出了对边自由,对边简支矩形板的解析解.此解满足层合板的基本方程和层间连续条件.用本文的方法比较容易处理层合板的自由边.算例表明,数值结果具有较高的精度. 相似文献
803.
以广东某水坝为研究对象,给出一种基于Fluent平台和Ansys平台进行结构动力响应分析的方法。首先采用基于YOUNGS界面重构技术的VOF模型,对流动进行数值模拟,成功捕捉了闸门开启过程中自由面的变化,比较了在三种落差情况下水坝的受力差异。计算表明,即使在上游平稳的入流条件下,水坝所受到的湍流水压力也会出现波动现象,水压力对坝体的冲击为低频作用,下游水位的升高会减缓水压力的波动,这些特点都与现场观察的相符。然后将水动力作为激励条件导入结构动力分析平台Ansys后,进一步对坝体结构进行动力分析。结构的模态分析结果与实测结果一致。因此,方法可以应用于实际。 相似文献
804.
A novel incompressible finite-difference lattice Boltzmann equation for particle-laden flow 总被引:1,自引:1,他引:1
In this paper, we propose a novel incompressible finite-difference lattice Boltzmann Equation (FDLBE). Because source terms that reflect the interaction between phases can be accurately described, the new model is suitable for simulating two-way coupling incompressible multiphase flow. The 2-D particle-laden flow over a backward-facing step is chosen as a test case to validate the present method. Favorable results are obtained and the present scheme is shown to have good prospects in practical applications. 相似文献
805.
Reversible Modulation of Surface Plasmons in Gold Nanoparticles Enabled by Surface Redox Chemistry 下载免费PDF全文
Dr. Zheng Li Dr. Jonathan J. Foley IV Dr. Sheng Peng Dr. Cheng‐Jun Sun Dr. Yang Ren Dr. Gary P. Wiederrecht Dr. Stephen K. Gray Dr. Yugang Sun 《Angewandte Chemie (International ed. in English)》2015,54(31):8948-8951
Switchable surface redox chemistry is demonstrated in gold@iron/iron oxide core–shell nanoparticles with ambient oxidation and plasmon‐mediated reduction to modulate the oxidation state of shell layers. The iron shell can be oxidized to iron oxide through ambient oxidation, leading to an enhancement and red‐shift of the gold surface plasmon resonance (SPR). This enhanced gold SPR can drive reduction of the iron oxide shell under broadband illumination to reversibly blue‐shift and significantly dampen gold SPR absorption. The observed phenomena provide a unique mechanism for controlling the plasmonic properties and surface chemistry of small metal nanoparticles. 相似文献
806.
Formation of a Syndiotactic Organic Polymer Inside a MOF by a [2+2] Photo‐Polymerization Reaction 下载免费PDF全文
Dr. In‐Hyeok Park Dr. Raghavender Medishetty Hyeong‐Hwan Lee Caroline Evania Mulijanto Hong Sheng Quah Prof. Shim Sung Lee Prof. Jagadese J. Vittal 《Angewandte Chemie (International ed. in English)》2015,54(25):7313-7317
Getting suitable crystals for single‐crystal X‐ray crystallographic analysis still remains an art. Obtaining single crystals of metal–organic frameworks (MOFs) containing organic polymers poses even greater challenges. Here we demonstrate the formation of a syndiotactic organic polymer ligand inside a MOF by quantitative [2+2] photopolymerization reaction in a single‐crystal‐to‐single‐crystal manner. The spacer ligands with trans,trans,trans‐conformation in the pillared‐layer MOF with guest water molecules in the channels, undergo pedal motion to trans,cis,trans‐conformation prior to [2+2] photo‐cycloaddition reaction and yield single crystals of MOF containing two‐dimensional coordination polymers fused with the organic polymer ligands. We also show that the organic polymer in the single crystals can be depolymerized reversibly by cleaving the cyclobutane rings upon heating. These MOFs also show interesting photoluminescent properties and sensing of small organic molecules. 相似文献
807.
Dr. Chun Zhang Zhen Wang Liangxiao Tan Tian‐Long Zhai Dr. Sheng Wang Prof. Bien Tan Prof. Yan‐Song Zheng Prof. Xiang‐Liang Yang Prof. Hui‐Bi Xu 《Angewandte Chemie (International ed. in English)》2015,54(32):9244-9248
A quadrangular prismatic tricyclooxacalixarene cage 1 based on tetraphenylethylene (TPE) was efficiently synthesized by a one‐pot SNAr condensation reaction. As a result of the porous internal structure in the solid state, cage 1 exhibited a good CO2 uptake capacity of 12.5 wt % and a high selectivity for CO2 over N2 adsorption of 80 (273 K, 1 bar) with a BET surface area of 432 m2 g?1. Formation of cage 1 led to the fluorescence of TPE being switched on in solution. The system was employed as a single‐molecule platform to study the mechanism of aggregation‐induced emission (AIE) by examining the restriction of intramolecular rotation (RIR). 相似文献
808.
Wrinkled Graphene Monoliths as Superabsorbing Building Blocks for Superhydrophobic and Superhydrophilic Surfaces 下载免费PDF全文
Li‐Bing Lv Tian‐Lu Cui Bing Zhang Hong‐Hui Wang Prof. Xin‐Hao Li Prof. Jie‐Sheng Chen 《Angewandte Chemie (International ed. in English)》2015,54(50):15165-15169
Superhydrophobic and superhydrophilic surfaces are of great interest because of a large range of applications, for example, as antifogging and self‐cleaning coatings, as antibiofouling paints for boats, in metal refining, and for water–oil separation. An aqueous ink based on three‐dimensional graphene monoliths (Gr) can be used for constructing both superhydrophobic and superhydrophilic surfaces on arbitrary substrates with different surficial structures from the meso‐ to the macroscale. The surface wettability of a Gr‐coated surface mainly depends on which additional layers (air for a superhydrophobic surface and water for a superhydrophilic surface) are adsorbed on the surface of the graphene sheets. Switching a Gr‐coated surface between being superhydrophobic and superhydrophilic can thus be easily achieved by drying and prewetting with ethanol. The Gr‐based superhydrophobic membranes or films should have great potential as efficient separators for fast and gravity‐driven oil–water separation. 相似文献
809.
Green Approach to the Fabrication of Superhydrophobic Mesh Surface for Oil/Water Separation 下载免费PDF全文
We report a simple and environment friendly method to fabricate superhydrophobic metallic mesh surfaces for oil/water separation. The obtained mesh surface exhibits superhydrophobicity and superoleophilicity after it was dried in an oven at 200 °C for 10 min. A rough silver layer is formed on the mesh surface after immersion, and the spontaneous adsorption of airborne carbon contaminants on the silver surface lower the surface free energy of the mesh. No low‐surface‐energy reagents and/or volatile organic solvents are used. In addition, we demonstrate that by using the mesh box, oils can be separated and collected from the surface of water repeatedly, and that high separation efficiencies of larger than 92 % are retained for various oils. Moreover, the superhydrophobic mesh also possesses excellent corrosion resistance and thermal stability. Hence, these superhydrophobic meshes might be good candidates for the practical separation of oil from the surface of water. 相似文献
810.
Iridium‐ and Osmium‐decorated Reduced Graphenes as Promising Catalysts for Hydrogen Evolution 下载免费PDF全文
Chee Shan Lim Prof. Zdeněk Sofer Rou Jun Toh Alex Yong Sheng Eng Jan Luxa Prof. Martin Pumera 《Chemphyschem》2015,16(9):1898-1905
Renewable energy sources are highly sought after as a result of numerous worldwide problems concerning the environment and the shortage of energy. Currently, the focus in the field is on the development of catalysts that are able to provide water splitting catalysis and energy storage for the hydrogen evolution reaction (HER). While platinum is an excellent material for HER catalysis, it is costly and rare. In this work, we investigated the electrocatalytic abilities of various graphene–metal hybrids to replace platinum for the HER. The graphene materials were doped with 4f metals, namely, iridium, osmium, platinum and rhenium, as well as 3d metals, namely, cobalt, iron and manganese. We discovered that a few hybrids, in particular iridium‐ and osmium‐doped graphenes, have the potential to become competent electrocatalysts owing to their low costs and—more importantly—to their promising electrochemical performances towards the HER. One of the more noteworthy observations of this work is the superiority of these two hybrids over MoS2, a well‐known electrocatalyst for the HER. 相似文献