Absorption spectra and the nature of complexes in the polyvinyl Alcohol-Nickel (II) chloride system

We have used electronic spectroscopy in the 160–1100 nm range to study the polyvinyl alcohol-nickel(II) chloride system. Based on the results obtained, we hypothesize formation of mixed-ligand complexes of the type [Ni(H₂O)_6-nCl_n]^2-n (n = 0, 1,..., 5) in the polyvinyl alcohol matrix. Transformation of the coordination sphere as the NiCl₂ concentration changes is apparent both in the region of the d-d transition bands (350–1100 nm) and in the region of the charge transfer bands (160–250 nm). We propose assigning the absorption bands separated by mathematical treatment to complexes of specific compositions. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 1, pp. 136–138, January–February, 2006.     

High-energy gamma-rays accompanying the spontaneous fission of 252Cf

The γ-ray spectrum of ²⁵²Cf(sf) was measured in the Darmstadt-Heidelberg Crystal Ball spectrometer, with a double ionization chamber mounted inside to detect the fission fragments. The measurement was aimed at a better understanding of an unusual component found in the high-energy region between 3 and 8 MeV, with fragment mass splits near symmetry. This component was proved to be predominantly emitted by the heavier fragment, to reach its highest intensity at a fragment mass split of 132:120, and to have an almost isotropic angular distribution. Calculations with the statistical code CASCADE could reproduce the main features.     

Interactions between kinetic and radiative processes inside moving absorbing fluids

The aim of this paper is to present several features of the couplings occurring between radiative transfer and the kinetics of a moving dielectric. After determining how the velocity field affects the apparent thermo-optical properties of matter, the energy transport problem is investigated in instationary regime and the general form of transient radiative transfer equation inside a moving medium is built. Then, the model is applied to the particular case of turbulent flows: a system of two equations for mean and fluctuating radiative energies is presented, and the resolution of this system is finally carried out.     

Vertical variability of sound fields in a coastal wedge

The results of measuring the vertical variability of sound fields are presented for a coastal wedge off the Pacific shelf of the Kamchatka peninsula. It is shown that the vertical radius of sound field correlation can reach ～30 m for frequencies within 600–800 Hz. The scatter of the specific parameters of the variability is in rather wide limits depending on the location of a vertical chain of receiving hydrophones, the hydrological conditions, the azimuth angle of the sound source, and the relief and bottom structure of the coastal wedge.     

Multi-layer structure in the strongly coupled 5D abelian Higgs model

We explore the phase diagram of the five-dimensional anisotropic Abelian Higgs model by Monte Carlo simulations. In particular, we study the transition between the confining phase and the four-dimensional layered Higgs phase. We find that, in a certain region of the lattice parameter space, this transition can be first order, and that each layer moves into the Higgs phase independently of the others (decoupling of layers). As the Higgs couplings vary, we find, using mean field techniques, that this transition may probably become second order. Received: 21 December 2001 / Published online: 12 April 2002     

Secondary anti-stokes emission from the bulk of gallium phosphide at 4.2 K

Secondary radiation (photoluminescence and Raman scattering) emitted by gallium phosphide single crystals at helium temperatures is investigated. It is established for the first time that, in the case when the secondary emission spectra are excited by a cw low-power He-Ne laser, whose linewidth lies in the transparency region of GaP, anti-Stokes photoluminescence from the bulk of the sample occurs due to interband and impurity recombination. The results obtained make it possible to carry out a qualitative and quantitative analysis of impurities which are present in the bulk of a semiconductor by recording the bulk anti-Stokes photoluminescence spectra at low temperatures.     

Raman spectra of MgB2 at high pressure and topological electronic transition

Raman spectra of MgB₂ ceramic samples were measured as a function of pressure up to 32 GPa at room temperature. The spectrum at normal conditions contains a very broad peak at ∼590 cm⁻¹ related to the E _2g phonon mode. The frequency of this mode exhibits a strong linear dependence in the pressure region from 5 to 18 GPa, whereas, beyond this region, the slope of the pressure-induced frequency shift is reduced by about a factor of two. The pressure dependence of the phonon mode up to ∼5 GPa exhibits a change in the slope, as well as a “hysteresis” effect in the frequency vs. pressure behavior. These singularities in the E _2g mode behavior under pressure support the suggestion that MgB₂ may undergo a pressure-induced topological electronic transition.     

Full-Wave Analyses for a Multi-Layered Microstrip Patch Antenna

This paper describes numerical modelling of a dual band multi-layered microstrip patch antenna operating at 35GHz on an in-house semi-insulating GaAs substrate. The simulated and measured resonant frequencies at both lower and upper resonant frequencies will be compared to check the accuracy of the different numerical modelling techniques.