Reaction of Anthranilamide with Phosphorus Pentasulfide: Formation of 2-Mercapto-(1H)-1,3,2λ5-benzodiazaphosphorine-2,4-dithione

The reaction of anthranilamide with phosphorus pentasulfide in boiling pyridine leads to the benzodiazaphosphorine-pyridine salt 2 . The structure is established by elemental analysis, ¹H- ¹³C- ¹⁵N- ³¹P-NMR, and mass spectral data.     

Basic Characteristics of Synchrotron Radiation

Many advances have been made in chemical structure research over the past three decades using synchrotron radiation. Synchrotron radiation has a number of unique properties. They include high brightness, high collimation, broad energy spectrum, variable polarization, coherent power, and subnanosecond pulse width. The third-generation storage rings with wiggler and undulator sources and lower electron beam dimensions are delivering over 10¹² times higher brightness than laboratory-based sources. The future of synchrotron sources looks very promising with the development of energy recovery linac sources and free-electron laser sources. These will permit dynamic studies of chemical structure with subpicosecond time resolution. Commensurate with the development of X-ray sources, major progress has occurred in optical schemes to meet the challenging needs of chemical structure research. High-resolution monochromatization and submicron focusing of X rays present new avenues for the future.     

Extraction of uranium(VI) by tri iso-amyl phosphate (TiAP) in ionic liquids

Batch extraction of uranium(VI) from uranyl nitrate solutions using TiAP in ionic liquids ([BMIM]PF₆ and [HMIM]PF₆) is studied. Effects of acidity, TiAP concentration in ionic liquid and temperature on distribution coefficient are studied. Results show that distribution coefficient increases with an increase in acidity and reduces with an increase in the alkyl chain length of the cation of the ionic liquid. Extraction of uranium(VI) by TiAP-[HMIM]PF₆ system is found to involve two molecules of the extractant per metal ion and extraction is found to change from being exothermic to endothermic as the percentage of the extractant is increased.     

Dewetting of glassy polymer films

Dynamics and morphology of hole growth in a film of power hardening viscoplastic solid [ yield stress approximately (strain-rate)(n)] is investigated. At short times the growth is exponential and depends on the initial hole size. At long times, for n>1 / 3, the growth is again exponential but with a different exponent. However, for n<1 / 3 the hole growth slows and the hole radius approaches an asymptotic value at long times. The rim shape is highly asymmetric, the height of which has a power law dependence on the hole radius (exponent close to unity for 0.25相似文献   

Electric-quadrupole interaction at 181Ta in f.c.t. ZrHi1.97

Time-differential perturbed γ-ray angular correlation experiments have been carried out on ¹⁸¹Ta impurities in ?-phase zirconium hydride over the temperature range from 20 to 588 K. A static, slightly asymmetric electric quadripole interaction is found at all temperatures. The static nature of the pattern indicates the absence of significant hydrogen diffusion at these temperatures on the time scale of the experiment (0.1 μsec). The temperature dependence of the static quadrupole frequency is given by the relation v_q(t) = 130[1 ? (1.9 × 10^?5)T^1.5] MHz.     

169Tm Mössbaüer spectroscopy and crystal field calculations in TmNi3 and TmCo3 intermetallics

The values of the magnetic moments and the electric field gradient in TmNi₃ and TmCo₃ are obtained from ¹⁶⁹Tm Mössbauer spectroscopy. These values are compared to those from crystal field model based on point charge calculations for these intermetallics.     

Meniscus instability in a thin elastic film

A new kind of meniscus instability leading to the formation of stationary fingers with a well-defined spacing has been observed in experiments with elastomeric films confined between a plane rigid glass and a thin curved glass plate. The wavelength of the instability increases linearly with the thickness of the confined film, but it is remarkably insensitive to the compliance and the energetics of the system. However, lateral amplitude (length) of the fingers depends on the compliance of the system and on the radius of curvature of the glass plate. A simple linear stability analysis is used to explain the underlying physics and the key observed features of the instability.     

The cyclodimerisation of 3-methyl-2-butenenitrile

3-Methyl-2-butenenitrile (1) cyclodimerised on treatment with lithium diisopropylamide in dimethoxyethane at temperatures between ?78°C and 0°C to 3-amino-4-cyano-1,5,5-trimethyl-1,3-cyclohexadiene (2) the structure of which was established by acid hydrolysis to the known 4-cyano-1,5,5-trimethyl-1-cyclohexene-3-one (3).     

Phase structures of a hydrated anionic phospholipid composition containing cationic dendrimers and pegylated lipids

The effect of 4th generation poly(amidoamine) dendrimer (4G PAMAM) present in an anionic phospholipid composition, consisting of hydrogenated soyphosphatidylcholine (HSPC), cholesterol (CH), dicetyl phosphate (DCP), and poly(ethylene glycol) (Mw approximately 2000) derivatized phosphatidylethanolamine (PEG2000-PE), on the hydration and liquid crystalline structure formation was investigated. The optical and polarized light microscopies of the liposomal dispersion obtained from the hydrated lipid composition show two types of birefringent structures (mesophases): plastic, wormlike microstructures and conventional, over-elongated lamellae. Differential scanning calorimetry (DSC) shows an increase in the liquid crystalline phase transition (Tg) of the lipid composition from 60 to 94 degrees C with increasing 4G PAMAM concentrations from 0 to 0.011 mM, respectively. The Tg values of the two microstructures were 68 and 84 degrees C, respectively, indicating that the plastic microstructures were 4G PAMAM/DCP-complexes-rich (alpha mesophases) and the conventional and elongated lamellae were dendrimer-doped HSPC/CH-rich microstructures (beta mesophases). Optical microscopy shows that the alpha mesophases convert into various other types of vesicular structures such as giant unilamellar vesicles and biliquid foams, upon heating above the phase transition temperature of the lipid composition (approximately 60-65 degrees C). The microstructure transformation is a result of an osmotic influx of water and the detergent action of PEG2000-PE present in the lipid composition. The transmission electron microscopy (TEM) images of the liposomal dispersion show particles embedding circular transparent domains that exactly correlate to the theoretical 4G PAMAM/DCP complex sizes, thus, providing evidence of 4G PAMAM interspersed within the two mesophases. Small-angle X-ray scattering (SAXS) measurements indicate that the alpha mesophases are a dendrimer-interlinked, symmetrically undulated lamellar phase and the beta mesophases are dendrimer-doped, occasionally kinked lamellae. An increase in dendrimer concentration in the lipid composition was found to decrease interlamellar spacing. On the basis of optical microscopy, DSC, TEM, and SAXS data, a model of dendrimer-doped mesophase structure and lamellae fusion is proposed. This investigation provides new self-assembled materials for drug/gene delivery and supplements the understanding of mechanisms involved in various biological processes such as membrane fusion, transmembrane permeation, and endocytosis.     

Ultrafast Electron Transfer Kinetics of Graphene Grown by Chemical Vapor Deposition

High electrochemical reactivity is required for various energy and sensing applications of graphene grown by chemical vapor deposition (CVD). Herein, we report that heterogeneous electron transfer can be remarkably fast at CVD‐grown graphene electrodes that are fabricated without using the conventional poly(methyl methacrylate) (PMMA) for graphene transfer from a growth substrate. We use nanogap voltammetry based on scanning electrochemical microscopy to obtain very high standard rate constants k⁰≥25 cm s^?1 for ferrocenemethanol oxidation at polystyrene‐supported graphene. The rate constants are at least 2–3 orders of magnitude higher than those at PMMA‐transferred graphene, which demonstrates an anomalously weak dependence of electron‐transfer rates on the potential. Slow kinetics at PMMA‐transferred graphene is attributed to the presence of residual PMMA. This unprecedentedly high reactivity of PMMA‐free CVD‐grown graphene electrodes is fundamentally and practically important.