Hydrogen behavior in Pd0.75Ag0.25H x studied by PAC and PAS

Hydrogen behavior in Pd_0.75Ag_0.25H _x has been investigated by both perturbed angular correlation (PAC) and positron annihilation lifetime spectroscopy (PAS) techniques. The PAC measurements with the ¹¹¹Ag/¹¹¹Cd probe nuclei were conducted at room temperature as a function of the hydrogen concentration x up to 0.35. At x = 0 the probe nuclei experienced no quadrupole perturbation, while a distinct perturbation was observed after hydrogen charging. The quadrupole interaction frequency ω ₁ and its distribution width σ ₁ and relative fraction f₁ all decrease with increasing hydrogen concentration, indicating size growth and concentration reduction of the hydrogen induced vacancy clusters. The measured frequency distribution width σ ₁ reveals hydrogen diffusion. The PAS measurements were also performed at room temperature. The obtained lifetimes and their variation with hydrogen concentration strongly support the PAC results. The experimental results can be explained by the appearance of the β-phase in the Pd_0.75Ag_0.25H _x samples. The α-phase is the major phase in the Pd_0.75Ag_0.25H _x samples. Charging of the hydrogen leads to the formation of the β-phase and the fraction of the β-phase increases with increasing hydrogen concentration. The present PAC and PAS results show that as the fraction of the β-phase increases, hydrogen induced vacancy clusters are formed and become larger and larger, while the cluster density reduces due to the combination of the vacancy clusters into larger size vacancy clusters.     

高效液相色谱-电喷雾串联质谱法测定饲料中的N-氨基甲酰-L-谷氨酸

建立了高效液相色谱-电喷雾串联质谱(HPLC-ESI-MS/MS)测定饲料中N-氨基甲酰-L-谷氨酸(NCG)含量的方法。饲料样品经甲醇提取、混合型强阴离子交换反相固相萃取(PXA)柱净化、HPLC分离后,采用ESI-MS/MS在正离子多反应监测(MRM)模式下进行检测,以碎片离子m/z 148.0和m/z 84.0进行定性,以碎片离子m/z 130.0进行定量。NCG的检出限(S/N >3)为24 μg/kg,定量限(S/N >10)为80 μg/kg,在20~1000 μg/L的质量浓度范围内峰面积与含量的线性关系良好,相关系数为0.9999。对饲料中NCG在80、200、500 mg/kg等3个添加水平下的回收率进行了测定,分别为104.0%、103.5%、95.3%,相对标准偏差分别为7.5%、6.3%、5.8%。结果表明,该方法操作简单,净化效果好,快速,灵敏度和准确度高,符合对饲料样品中NCG检测分析的要求。     

Multiobjective programming problems with (G,C,ρ)-convexity

In this paper, we deal with multiobjective programming problems involving functions which are not necessarily differential. A new concept of generalized convexity, which is called (G,C,??)-convexity, is introduced. We establish not only sufficient but also necessary optimality conditions for multiobjective programming problems from a viewpoint of the new generalized convexity. When the sufficient conditions are utilized, the corresponding duality theorems are derived for general Mond-Weir type dual program.     

On-line Time Differential Perturbed Angular Correlation with Light Probe Nucleus 19F

An on-line time differential perturbed angular correlation technique has been developed with the light probe nucleus ¹⁹F. The first on-line TDPAC measurement was carried out to determine the field gradient in Cd and quadrupole moment of ¹⁹F (0.197 MeV: I ^π = 5/2⁺, T_1/2 = 89 ns). This revised version was published online in September 2006 with corrections to the Cover Date.     

Structural characterization of alachlor complexes with transition metal ions by electrospray ionization tandem mass spectrometry

Electrospray ionization mass (ESI-MS) spectrometry was used to investigate the nature of metal complexes of alachlor and their dissociations on activation. Ions of the first row transition metal series were employed to react with alachlor and the products were subjected to collision-induced dissociation (CID) for further structural characterization. The formation of diverse complex ions including doubly charged metal/alachlor complexes; [3L + M]²⁺ and [4L + M]²⁺ (L: alachlor and M: transition metal ions) were observed depending on the experimental conditions including the tube lens offset voltage (TLOV) and relative concentrations of alachlor and transition metal ions. It is clear that complexation with transition metal ions alters the reactive site of alachlor, promoting the loss of chlorine over the loss of CH₃OH that is the major reaction pathway in uncomplexed system. Direct elimination of chlorine from alachlor molecule was confirmed by the use of MnBr₂ instead of MnCl₂. These evidences clearly illustrate the catalytic activities of the metal ions through insertion mechanism. The function of transition metal ions in complexation was emphasized comparing the fragmentation patterns with those of protonated molecule. A change in the oxidation state of copper from + 2 to + 1 during the dissociation of metal complex was observed in company with elimination of radicals which is specific for the copper complex ions.     

Study of dependence of quasi-particle alignment on proton and neutron numbers in A = 80 region through g-factor measurements

Dependence of quasi-particle alignment on proton and neutron numbers has been studied in A?=?80 mass region through g-factor measurements by using TMF-IMPAD. The experimental results show that for the nuclides ⁸⁴Zr, ⁸⁵Zr and ⁸⁶Zr with Z?=?40 the proton alignment is followed by the neutron alignment in ⁸⁴Zr and ⁸⁵Zr, while the neutron alignment is followed by the proton alignment in ⁸⁶Zr, and for the nuclides ⁸²Sr, ⁸³Y, ⁸⁴Zr and ⁸⁵Nb with N?=?44 the proton aligns only in ⁸²Sr, the proton alignment occurs first that is followed by the neutron alignment in ⁸³Y and ⁸⁴Zr and the neutron alignment is followed by the proton alignment in ⁸⁵Nb. Proton and/or neutron alignments lead to different patterns of the g-factor variation with spin.     

可见光电视摄像机整机MTF测量装置及方法

调制传递函数（MTF）是评价电视摄像机成像质量的重要参数。介绍了一种用于可见光电视摄像机整机MTF测量装置及方法。设计了三积分球目标发生器系统,通过电动衰减器实现了目标和背景亮度的独立可控,其出口不均匀性为4.1%。采用基于倾斜狭缝法的亚像元自动插值与匹配算法以及线扩散函数（LSF）的最小二乘拟合分析法,实现了倾斜角度的自动计算以及MTF的精确测量,测量装置的重复性为0.007。通过与国外先进仪器的比对实验,表明建立的电视摄像机整机性能测量装置可以有效解决电视摄像机整机成像质量性能评价问题。     

敞开式大跨空间桁架结构风荷载分布特性研究

敞开式空间结构的桁架由于直接受气流作用,其流场空间分布复杂,风荷载确定困难,且风洞试验受模型缩尺比限制难于获取桁架结构上的气动力．借助数值风洞技术,利用高性能计算平台,本文数值求解了敞开式桁架结构的空间流场及风荷载分布．敞开式空间桁架结构整体风荷载表现为水平向为主,竖向不显著的特点,该点与封闭式桁架结构整体通常表现出竖向较强吸力作用明显不同．敞开式空间桁架结构整体风荷载对风向角表现并不敏感,其原因在于敞开式空间桁架的流场多处分离且相互干扰严重,其整体特征紊流不易在某个风向角下特别占优．     

g-Factors of magnetic–rotational states in 85Zr

The properties of the double iron and tungsten carbide prepared by mechanical alloying technique (MA) from elemental powders are reported. The samples were milled for 1, 3, 5, 10, 15, 20, 25 and 30 h. The alloy progress for each milling time was evaluated by X-ray diffraction (XRD) and ⁵⁷Fe Mössbauer spectrometry. Once the alloy was consolidated two sorts of paramagnetic sites and a magnetic distribution were detected according to the Mössbauer fitting. The majority doublet could correspond to Fe₆W₆C ternary carbide as X-ray diffraction suggests, and the other could be Fe₃W₃C. The hyper fine parameters are reported. Vickers microhardness measurements of 30 h milled sample was conducted at room temperature with a load of 0.245 N for 20 s.