焊接接头热影响区表面裂纹疲劳扩展速率

给出了数据处理的方法，通过对试验数据的分析，给出了裂纹扩展速率与ΔK的关系，为油田的安全生产提供了依据。     

Resistive switching polymer materials based on poly(aryl ether)s containing triphenylamine and 1,2,4‐triazole moieties

A series of poly(aryl ether)s were successfully prepared via aromatic nucleophilic substitution reaction from various bisphenols and a novel bipolar aryl difluoride monomer containing electron‐donor triphenylamine and electron‐acceptor 1,2,4‐triazole moieties. The poly(aryl ether)s exhibited excellent solubility in organic solvents such as dimethylformamide, chloroform, and tetrahydrofuran at room temperature. The poly(aryl ether)s showed high thermal stability with T_d10 higher than 500 °C and glass transition temperatures (T_g) higher than 187 °C. The thin films of the poly(aryl ether)s indicated bistable resistive switching behavior with ON/OFF current ratios as high as 10³. The switching on and switching off bias voltages of the poly(aryl ether)s were affected by the bisphenol moiety. The good resistive switching behavior of the poly(aryl ether)s made them promising candidates for future nonvolatile memory applications. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6861–6871, 2008     

关于奇性两点狄利克雷问题

本文研究奇性两点狄利克雷问题，在ｆ（ｔ，ｘ，ｙ）≤α（ｔ）ｇ（ｘ）＋β（ｔ）ｈ（ｘ）｜ｙ｜ε，０＜ε≤２情形下，得到了解的存在性定理，推广了Ｔｉｎｅｏ（１９９２）的结果．     

The synthesis and coordination properties of new macrocyclic polyethers

A new type of macrocyclic polyethers has been synthesized. It consists of an azacrown ether as mother ring, e.g. 1,7-dioxa-4,10-diaza-cyclododecane (1a) or 1,7,10,16-tetraoxa-4,13-diazacycloocatadecane (1b), and two side chains attached on the two nitrogen atoms of 1a or 1b. A number of these new crown ethers are obtained by alkylation of the two secondary amino groups of 1a or 1b with corresponding halides, BrCH₂(CH₂OCH₂)_nCH₂OR, in the presence of potassium carbonate. The crown-alkali metal complex thus obtained is hydrolyzed by acid. In order to obtain pure crown ether the reaction mixture is treated with tetramethylammonium hydroxide and followed by solvent extraction. The ability of complexing alkali cations of macrocyclic polyethers in terms of the equilibrium constant have been studied by the method of solubilities of salts in chloroform. It is shown that the size of the mother ring, the number of oxygen atoms either in the ring or in the side-chains, and the ionic radius of the alkali metal are the factors governing the stability of the metal complexes. Most of these new crown ethers possess high ability for alkali metal complexation some of them, such as N,N′- di-β-methoxyethyl-1,7-dioxa-4,10-diaza-cyclododecanc (13a), possesses higher selectivity for Na+ and K+ ions than 18-crown-6- and 4,4′(5′)-dimethylbenz-30-crown-10.     

Crystal Structure and Third-order Nonlinear Optical Property Studies on Copper(Ⅱ) Complex Containing NS Donor Ligand

Recently,thestudyofrelationshipsbetweenstructureandpropertyforseriesofcompoundhavingenhancedopticalnonlinearityhasincreaseourunderstandingofwhatmolecularleveIdesigncriteriaareimPortantformaximizingthesecondandthethird-ordernonlinearity'.lngeneral,thesestudieshavefocusedonmanipulationoftheeffectiveconjugationlengthforavarietyofn-electronbackbones,mostlyrelatedto.-PvariousorganiccomPoundscontainingdonorandacceptorgroups'.InthispaPer,wewillstudytheinteractionamongdonor-metal-donorinx-conjugation…     

A new (Hg,V)-based 1212-type cuprate (Hg,V) Sr2(Y,Ca) Cu2Oz with Tc(onset) up to 110 K

We have successfully synthesized a new (Hg, V)-based 1212-type cuprate (Hg_1?x V _x )Sr₂(Y_1?y Ca _y )Cu₂O _z . The electrical resistance measurements showed that some of the as-synthesized materials with proper Hg/V and Y/Ca ratios exhibit weak superconductivity. Oxygen-annealing significantly improved their superconducting behavior, andT _c(onset) up to 110 K was observed. The lattice parameters of (Hg,V)-1212 were found to be in the order ofa=3.8415(1) Å andc=11.8514(6) Å. Substitu ting mercury atoms by vanadium ones results in an important increase of thea parameter and an important decrease of thec parameter compared to the known Hg-based Sr-bearing compounds. The crystal structure of (Hg, V)-1212 was refined by Rietveld refinement against X-ray powder data using the tetragonal symmetry of space groupP4/mmm. The V and Cu valence states and superconductivity in this new (Hg, V)-1212 cuprate are briefly discussed.     

微型计算机在微弱光谱测试系统中的应用

本文报道了在我们研制的微弱光谱测试系统中微计算机的应用,介绍了数据采集、双机间的DMA传送数据、二维光栅扫描控制、应用微机改善信噪比、应用软件和图形显示等问题。着重讨论如何通过我们所做的研制工作,使性能较低的EG3003微计算机达到OMA系统所要求的水平。     

A Concise and Stereoselective Synthesis of the Cathasterone''''s Side Chain

A concise and stereoselective synthesis of cathasterone's side chain using methyl isopropyl ketone 3 as the fragment is described.     

GM（1，1）模型的样条插值函数的残差拟合

本文用样条函数对GM(1，1)模型的残差序列进行插值拟合，然后作用于二阶线性微分方程，并以此修正原模型，得到一种新的预测模型的数值解．     

向量集值优化超有效解的对偶问题

借助于Contingent切锥和集值映射的上图而引入的有关集值映射的Contingent切导数，对约束集值优化问题的超有效解建立了最优性Kuhn Tucker必要及充分性条件,借此建立了向量集值优化超有效解的Wolfe型和Mond Weir型对偶定理.