Surface Modification of Silica Gels as Carrier for AminoacylaseImmobilization

IrnmobilisedaIninoacylaseisanotablecatalystforthekineticresolutionofN-acetyl-D,L-aIninoacidsandquitealotofresearchworkhasbeeninvolvedonaminoacylase~bilisationswithitscarriers.lTheauthorshaverePortedthattheaIninosilicagelspreparedbyanlinProvedmethodwereeffechveforchymotryPsininunobilisahon,'l'butitwasnotproperforaIninoacylasetriobilisahon.InordertodevelopasahsfactorysurfacesmictUreofsilicagelsforaIninoacylasetriobilisation,tWokindsofreactivegrouPs,theN,N-diethylaIninogrouPandthehydroxygr…     

Sharp photonic Crystal Defect Modes and Their Response to Ultrashort Optical Pulses

Single photonic crystal defects based on an air-bridge structure were fabricated. We obtained sharp defect modes with quality factors higher than 600 and observed their response to ultrashort optical pulses by utilizing two-photon absorption.     

PERIODIC REACTION AND TURBULENCE OF CHEMICAL BRUSSELATOR

In this paper,we discuss the reaction model of tri-molecules and the exi- stence of periodic reaction under certain original density conditions of two ob- jects without diffusion phenomena.We prove that the periodic reaction exhibit some chemical phenomena that violate the second law of thermo-mechanics. Finally,we research similar properties and phenomena concerning Belousov- Zhabotinsky reaction model.     

Structural Study of Inclusion Complex of Andrographolide with β-Cyclodextrin Prepared under Microwave Irradiation

Andrographolide (Andro) (Figure 1) is a diterpene lactone isolated from Andrographis paniculate Nees1. It has showed several biological activities including analgesic, antipyretic and anti-inflammatory effects2. However, its poor water solubility and unstability towards oxygen restrained its application. In pharmaceutics, b-CD is used to increase solubility and stability3. We have prepared the inclusion compound of Andro/b-CD (Figure 2) under microwave irradiation4. It has been found…     

Homogeneous catalytic asymmetric dihydroxylation of olefins induced by an efficient and recoverable polymer‐bound ligand QN–AQN–OPEG‐OMe

A novel polymer‐bound alkaloid ligand QN–AQN–OPEG‐OMe, which was characterized by an anthraquinone core at the 9‐O position of quinine, was synthesized conveniently. It delivered up to 99% ees in the homogeneous catalytic asymmetric dihydroxylation of seven olefins, comparable to that reported for the homogeneous catalyst with free ligand (DHQ)₂AQN. This ligand was recovered almost quantitatively by a simple filtration and reused for five cycles without obvious decreased enantioselectivities and catalytic activities. Copyright © 2005 John Wiley & Sons, Ltd.     

三元对称形式的Schur分拆与不等式的可读证明

本文给出了一类三元对称形式(即对称齐次多项式)的一种分拆法,即将此类多项式表示成一类特定形式的正半定对称形式的线性组合,介绍分拆算法．并由此而给出了三元对称形式半正定的一个充分条件．     

厚二氧化硅光波导薄膜制备及其特性分析

以硅烷和氧化二氮作为反应气体，采用等离子体增强化学气相沉积(PECVD)技术，不使用掺杂，在单晶硅衬底上制备了用于平面光波导的二氧化硅薄膜。研究了薄膜折射率和淀积速率与工艺参量之间的关系，通过棱镜耦合仪、傅里叶变换红外光谱、原子力显微镜等测试手段，分析了薄膜的结构和光学特性。结果表明，实验能快速生长厚二氧化硅薄膜，薄膜表面平整，颗粒度均匀，同时薄膜具有折射率精确可控和红外透射性能好的特点，非常适合制作光波导器件。     

Nanosized gold clusters formation in selected areas of soda-lime silicate glass

Nanosized gold clusters were developed in a gold-doped soda-lime silicate glass after X-ray irradiation followed by annealing, which provided an alternative way of forming metallic nanoclusters in glass to ion implantation. The formation of gold nanoclusters can be controlled by irradiation time or annealing time.