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51.
Spatial parameters of the X-ray radiation produced by a high-voltage nanosecond discharge evolving in air under atmospheric
pressure in the rod (cathode)-plane electrode system with a 10-cm electrode spacing are studied experimentally. A ∼170-ns
voltage pulse with an amplitude of ∼200 kV and 10-ns rise time is applied to the cathode. The photoelectronic method is used
to study, under the same conditions, the integrated (over the gap) characteristics of the radiation, in particular, the duration
of its generation. It is found that, when the size of the X-ray source is not smaller than that of the discharge region of
diffusive luminescence, radiation from the cathode region of the gap is primarily observed (i.e., from the region where the
electric field distribution is sharply inhomogeneous). The X-ray generation is usually observed after the bridging of the
discharge gap, the X-ray pulse having a rise time of ∼3 ns, a duration of ∼10 ns, and an effective radiation energy of ∼6
keV. 相似文献
52.
The translational nonequilibrium zone in a shock wave is considered for a gas consisting of light particles and a small addition
of heavy particles. The gas is taken to be two-dimensional, and long-range forces are assumed to be absent. In the framework
of this approximation, a program for molecular dynamics simulation of the gas is developed. It is applied to calculate a particle
distribution function in the shock wave, to analyze the time evolution of the distribution function, and to study its dependence
on the gas composition. 相似文献
53.
54.
A. B. Maizel’ 《Acoustical Physics》2004,50(6):717-720
Using the theory of spheroidal wave functions, the total acoustic impedance is determined for a prolate spheroid performing transverse translational and rotational oscillatory movements. Expressions for the radiation resistance, the added mass, and the added moment of inertia are derived. It is shown that, in the lowfrequency approximation, this mass and moment of inertia reach limiting values identical to hydrodynamic ones. The components of the total acoustic impedance are calculated for spheroids of different relative thicknesses at an arbitrary frequency. 相似文献
55.
Yu. B. Bolkhovityanov S. Ts. Krivoshchapov A. I. Nikiforov B. Z. Ol’shanetskii O. P. Pchelyakov L. V. Sokolov S. A. Teys 《Physics of the Solid State》2004,46(1):64-66
Different techniques for the fabrication of structures containing ensembles of ultrasmall germanium nanoclusters distributed with a high density over the substrate surface are discussed. How to control the morphology and ordering of these ensembles is also discussed. 相似文献
56.
E. A. Ekimov E. L. Gromnitskaya D. A. Mazalov A. F. Pal’ V. V. Pichugin S. Gierlotka B. Palosz J. A. Kozubowski 《Physics of the Solid State》2004,46(4):755-757
Superhard nanodiamond-SiC ceramics are prepared by infiltrating liquid Si into porous nanodiamond compacts under pressure.
Synthesized samples are 2.2 mm thick and 3–4 mm in diameter. The effect of particle size of dynamically synthesized nanodiamond
powders on silicon infiltration and SiC phase formation is studied. It is established that silicon does not penetrate into
the pores of nanodiamond powders if the original particle size is smaller than 0.5–1.0 μm. The critical pore size for infiltration
is 100–200 nm. A study of the microstructure of the samples showed the presence of the nanometer-and submicron-scale SiC phase.
The ultrasound velocities are measured in the prepared compacts, and the elastic moduli are calculated.
__________
Translated from Fizika Tverdogo Tela, Vol. 46, No. 4, 2004, pp. 734–736.
Original Russian Text Copyright ? 2004 by Ekimov, Gromnitskaya, Mazalov, Pal’, Pichugin, Gierlotka, Palosz, Kozubowski. 相似文献
57.
Ren‐Shen Lee Jen‐Ming Yang Tz‐Feng Lin 《Journal of polymer science. Part A, Polymer chemistry》2004,42(10):2303-2312
Water‐soluble poly(ester‐carbonate) having pendent amino and carboxylic groups on the main‐chain carbon is reported for the first time. This article describes the melt ring‐opening/condensation reaction of trans‐4‐hydroxy‐N‐benzyloxycarbonyl‐L ‐proline (N‐CBz‐Hpr) with 5‐methyl‐5‐benzyloxycarbonyl‐1,3‐dioxan‐2‐one (MBC) at a wide range of molar fractions. The influence of reaction conditions such as catalyst concentration, polymerization time, and temperature on the number average molecular weight (Mn) and molecular weight distribution (Mw/Mn) of the copolymers was investigated. The polymerizations were carried out in bulk at 110 °C with 3 wt % stannous octoate as a catalyst for 16 h. The poly(ester‐carbonate)s obtained were characterized by Fourier transform infrared spectroscopy, 1H NMR, differential scanning calorimetry, and gel permeation chromatography. The copolymers synthesized exhibited moderate molecular weights (Mn = 6000–14,700 g mol?1) with reasonable molecular weight distributions (Mw/Mn = 1.11–2.23). The values of the glass‐transition temperature (Tg) of the copolymers depended on the molar fractions of cyclic carbonate. When the MBC content decreased from 76 to 12 mol %, the Tg increased from 16 to 48 °C. The relationship between the poly(N‐CBz‐Hpr‐co‐MBC) Tg and the compositions was in approximation with the Fox equation. In vitro degradation of these poly(N‐CBz‐Hpr‐co‐MBC)s was evaluated from weight‐loss measurements and the change of Mn and Mw/Mn. Debenzylation of 3 by catalytic hydrogenation led to the corresponding linear poly(ester‐carbonate), 4 , with pendent amino and carboxylic groups. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2303–2312, 2004 相似文献
58.
Qi Wang Huaxiang Yang Zhiqiang Fan Hong Xu 《Journal of polymer science. Part A, Polymer chemistry》2004,42(5):1093-1099
Ethylisobutylaluminoxane (EBAO) and its analogues were synthesized by a reaction between an triethylaluminum (Et3Al)/triisobutylaluminum (i‐Bu3Al) mixture and 4‐fluorobenzeneboronic acid, phenylboronic acid, or n‐butaneboronic acid and subsequent hydrolysis with water. They were used as cocatalysts in ethylene polymerization catalyzed by an iron complex {[(ArN?C(Me))2C5H3N]FeCl2, where Ar is 2,6‐diisopropylphenyl}. Polyethylene with a high molecular weight and a narrow molecular weight distribution was prepared with modified EBAOs, and the performance of the iron complex at high polymerization temperatures was greatly improved. The activators for the iron complex also affected the polymerization activity and the molecular weight of the resultant polyethylene. It was suggested that the stereo and electronic effects of the substitute groups of aluminoxane contributed to the improved performance of the new activators. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1093–1099, 2004 相似文献
59.
Chin‐Ping Yang Sheng‐Huei Hsiao Che‐Yu Tsai Guey‐Sheng Liou 《Journal of polymer science. Part A, Polymer chemistry》2004,42(10):2416-2431
Two series of fluorinated polyimides were prepared from 2,2′‐bis(4‐amino‐2‐trifluoromethylphenoxy)biphenyl ( 2 ) and 2,2′‐bis(4‐amino‐2‐trifluoromethylphenoxy)‐1,1′‐binaphthyl ( 4 ) with various aromatic dianhydrides via a conventional, two‐step procedure that included a ring‐opening polyaddition to give poly(amic acid)s, followed by chemical or thermal cyclodehydration. The inherent viscosities of the polyimides ranged from 0.54 to 0.73 and 0.19 to 0.36 dL/g, respectively. All the fluorinated polyimides were soluble in many polar organic solvents, such as N,N‐dimethylacetamide and N‐methylpyrrolidone, and afforded transparent and light‐colored films via solution‐casting. These polyimides showed glass‐transition temperatures in the ranges of 222–280 and 257–351 °C by DSC, softening temperatures in the range of 264–301 °C by thermomechanical analysis, and a decomposition temperature for 10% weight loss above 520 °C both in nitrogen and air atmospheres. The polyimides had low moisture absorptions of 0.23–0.58%, low dielectric constants of 2.84–3.61 at 10 kHz, and an ultraviolet–visible absorption cutoff wavelength at 351–434 nm. Copolyimides derived from the same dianhydrides with an equimolar mixture of 4,4′‐oxydianiline and diamine 2 or 4 were also prepared and characterized. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2416–2431, 2004 相似文献
60.
Sang‐Uk Kim Choonkeun Lee Saimani Sundar Wonbong Jang Seung‐Jin Yang Haksoo Han 《Journal of Polymer Science.Polymer Physics》2004,42(23):4303-4312
A series of polyimides were synthesized from 2,2‐Bis(3,4‐dicarboxyphenyl)hexafluoropropane, 2,2‐bis(3‐amino‐4‐hydroxyphenyl)‐hexafluoropropane, and 4,4′‐oxydianiline by chemical imidization. The effects of the diamine ratios on the properties of the films were evaluated through the study of their thermal, electrical, and morphological properties. All the polymers exhibited better solubility in most of the organic solvents and hence were easily processable. Polyimides with more 2,2‐bis(3‐amino‐4‐hydroxyphenyl)‐hexafluoropropane exhibited better solubility and a low refractive index, which is highly desired for microelectronic applications. The dielectric constant and birefringence were strongly dependent on the fluorine content. With an increase in the fluorine substitution, both the dielectric constant and birefringence decreased. All the polymers exhibited high thermal stability (>400 °C). The absence of crystalline melting in differential scanning calorimetry and broad wide‐angle X‐ray diffraction patterns revealed the amorphous nature of the polymers, which was due to the presence of bulky CF3 groups and hinged ether linkages of the diamine component. The residual stress values decreased with an increase in the 4,4′‐oxydianiline content, and the results were in agreement with the dielectric constant. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4303–4312, 2004 相似文献