Anisotropic Superconducting Properties of Kagome Metal CsV_3Sb_5

We systematically measure the superconducting(SC) and mixed state properties of high-quality CsV_3 Sb_5 single crystals with T_c～3.5 K.We find that the upper critical field H_(c2)(T) exhibits a large anisotropic ratio of H_(c2)~(ab)/H_(c2)~c～9 at zero temperature and fitting its temperature dependence requires a minimum two-band effective model.Moreover,the ratio of the lower critical field,H_(c1)~(ab)/H_(c1)~c,is also found to be larger than 1,which indicates that the in-plane energy dispersion is strongly renormalized near Fermi energy.Both H_(c1)(T) and SC diamagnetic signal are found to change little initially below T_c～3.5 K and then to increase abruptly upon cooling to a characteristic temperature of ～2.8 K.Furthermore,we identify a two-fold anisotropy of in-plane angular-dependent magnetoresistance in the mixed state.Interestingly,we find that,below the same characteristic T～2.8 K,the orientation of this two-fold anisotropy displays a peculiar twist by an angle of 60° characteristic of the Kagome geometry.Our results suggest an intriguing superconducting state emerging in the complex environment of Kagome lattice,which,at least,is partially driven by electron-electron correlation.     

神经网络在棱镜摄谱仪定量分析光谱中的应用

给出了采用BP神经网络拟合标准光源在棱镜摄谱仪的谱平面位置和相应波长的非线性函数,省去了和标准铁谱比对测量未知谱线波长,简化了光谱的定量分析,提高了仪器的自动化和智能化水平.     

Common (π,π) Band Folding and Surface Reconstruction in Fe As-Based Superconductors

High resolution angle-resolved photoemission spectroscopy(ARPES) measurements are carried out on CaKFe_4 As_4,KCa_2 Fe_4 As_4 F_2 and(Ba_(0.6)K_(0.4))Fe_2 As_2 superconductors.Clear evidence of band folding between the Brillouin zone center and corners with a(π,π) wave vector has been found from the measured Fermi surface and band structures in all the three kinds of superconductors.A dominant ~(1/2)×~(1/2) surface reconstruction is observed on the cleaved surface of CaKFe_4As_4 by scanning tunneling microscopy(STM) measurements.We propose that the commonly observed ~(1/2)×~(1/2) reconstruction in the FeAs-based superconductors provides a general scenario to understand the origin of the(π,π) band folding.Our observations provide new insights in understanding the electronic structure and superconductivity mechanism in iron-based superconductors.     

两种波纹板通道内的流动及换热比较

采用非稳态算法,计算了周期性正弦型和三角形两种波纹板通道内的流动和换热,比较了它们的平均阻力系数和平均努赛尔数.结果表明:在较大流量下,两种通道内的流动均出现了自维持振荡现象,但是两者相比正弦型通道波纹板的换热和压降均较大.     

燃气机热泵全年性能优化研究

本文建立了燃气机热泵(GEHP)的全年性能优化模型,定义了燃气机热泵的全年性能系数,比较了采用不同优化目标函数得到的优化结果的差别,研究了冷负荷比例变化对全年性能优化的影响,分析了燃气机热泵在不同地区应用时全年性能优化目标的确定.     

Single-Stage Extraction and Separation of Co2+ from Ni2+ Using Ionic Liquid of [C4H9NH3][Cyanex 272]

The purpose of this study was to optimize the extraction conditions for separating Co²⁺ from Ni²⁺ using N-butylamine phosphinate ionic liquid of [C₄H₉NH₃][Cyanex 272]. A Box–Behnken design of response surface methodology was used to analyze the effects of the initial pH, extraction time, and extraction temperature on the separation factor of Co²⁺ from sulfuric acid solution containing Ni²⁺. The concentrations of Co²⁺ and Ni²⁺ in an aqueous solution were determined using inductively coupled plasma-optical emission spectrometry. The optimized extraction conditions were as follows: an initial pH of 3.7, an extraction time of 55.8 min, and an extraction temperature of 330.4 K. The separation factor of Co²⁺ from Ni²⁺ under optimized extraction conditions was 66.1, which was very close to the predicted value of 67.2, and the error was 1.7%. The equation for single-stage extraction with high reliability can be used for optimizing the multi-stage extraction process of Co²⁺ from Ni²⁺. The stoichiometry of chemical reaction for ion-exchange extraction was also investigated using the slope method.     

The Relationship between Procyanidin Structure and Their Protective Effect in a Parkinson’s Disease Model

This study evaluated the effect of grape seed-derived monomer, dimeric, and trimeric procyanidins on rat pheochromocytoma cell line (PC12) cells and in a zebrafish Parkinson’s disease (PD) model. PC12 cells were cultured with grape seed-derived procyanidins or deprenyl for 24 h and then exposed to 1.5 mm 1-methyl-4-phenylpyridinium (MPP⁺) for 24 h. Zebrafish larvae (AB strain) 3 days post-fertilization were incubated with deprenyl or grape seed-derived procyanidins in 400 µM 1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine (MPTP) for 4 days. The results showed that the procyanidin dimers procyanidin B1 (B1), procyanidin B2 (B2), procyanidin B3 (B3), procyanidin B4 (B4), procyanidin B1-3-O-gallate (B1-G), procyanidin B2-3-O-gallate (B2-G), and the procyanidin trimer procyanidin C1 (C1) had a protective effect on PC12 cells, decreasing the damaged dopaminergic neurons and motor impairment in zebrafish. In PC12 cells and the zebrafish PD model, procyanidin (B1, B2, B3, B4, B1-G, B2-G, C1) treatment decreased the content of reactive oxygen species (ROS) and malondialdehyde (MDA), increased the activity of antioxidant enzymes glutathione peroxidase (GSH-Px), catalase (CAT), and superoxide dismutase (SOD), and upregulated the expression of nuclear factor-erythroid 2-related factor (Nrf2), NAD(P)H: quinone oxidoreductase 1 (NQO1), and heme oxygenase-1 (HO-1). These results suggest that in PC12 cells and the zebrafish PD model, the neuroprotective effects of the procyanidins were positively correlated with their degree of polymerization.     

Heterogeneous Catalysis of Ozone Using Iron–Manganese Silicate for Degradation of Acrylic Acid

Iron–manganese silicate (IMS) was synthesized by chemical coprecipitation and used as a catalyst for ozonating acrylic acid (AA) in semicontinuous flow mode. The Fe-O-Mn bond, Fe-Si, and Mn-Si binary oxide were formed in IMS on the basis of the results of XRD, FTIR, and XPS analysis. The removal efficiency of AA was highest in the IMS catalytic ozonation processes (98.9% in 15 min) compared with ozonation alone (62.7%), iron silicate (IS) catalytic ozonation (95.6%), and manganese silicate catalytic ozonation (94.8%). Meanwhile, the removal efficiencies of total organic carbon (TOC) were also improved in the IMS catalytic ozonation processes. The IMS showed high stability and ozone utilization. Additionally, H₂O₂ was formed in the process of IMS catalytic ozonation. Electron paramagnetic resonance (EPR) analysis and radical scavenger experiments confirmed that hydroxyl radicals (•OH) were the dominant oxidants. Cl⁻, HCO₃⁻, PO₄³⁻, Ca²⁺, and Mg²⁺ in aqueous solution could adversely affect AA degradation. In the IMS catalytic ozonation of AA, the surface hydroxyl groups and Lewis acid sites played an important role.     

精确确定光路中四分之一波片光轴方位的新方法

为了准确安装四分之一波片,介绍了一种精确确定光路中四分之一波片光轴方位的新方法,并利用米勒矩阵理论分析了影响测量结果的误差因素.测试方法所用的主要理论有米勒矩阵理论、傅里叶分析方法和最小二乘法.该方法利用最小二乘法得到了最优傅里叶系数,利用消光比测试原理实现了检偏棱镜的精确安装,利用反馈环控制系统对步进电机的步进角进行了控制.误差分析表明该方法的测量误差与四分之一波片光轴方位角本身的大小有关.实验结果表明该方法的标准不确定度为0.03.     

相干光脉冲位置调制信道容量及传信率最大化研究

分析了相干光脉冲位置调制的信道容量及传信率最大化条件.通过分析光外差接收的脉冲位置调制信号具有的概率分布特性,推导出采用最大似然检测的相干脉冲位置调制信道具有的转移概率矩阵和信道容量,证明在检测器散粒噪声极限假设下,信道容量只取决于接收脉冲能量和脉冲位置调制阶数.利用Jensen不等式化简信道容量得到其下限,该下限能够近似实际通信链路的信道容量.基于此估计出达到最高传信率时的脉冲位置调制阶数同粒子数反转的重建时间之间的关系,给出了二者在一定范围内的一般映射.数值仿真表明,在接收能量使信道误码率优于10-2时,估箅出的脉冲位置调制阶数能够使传信率接近最大值.