Enhanced Raman scattering provided by fullerene nanoclusters

Two new nonlinear optic effects are observed in crystalline solutions of fullerenes in toluene and carbon tetrachloride. Both are provided by a self-clustering of the solute molecules and are referred to fullerene-enhanced Raman scattering and solvent-enhanced luminescence. The effects are induced by the excitation of charge-transfer states of the fullerene nanoclusters, which makes the latter act as amplifiers of local electric fields. The text was submitted by the authors in English.     

Computational chemistry of the silicon nitride surface. 1. Water,ammonia, and water-ammonia complex

This paper deals with computational modeling of structure and properties of the silicon nitride surface zone using combined computational and real experiments. The computational experiment implies quantum chemical calculations of structure and vibrational spectra of polyatomic clusters. The real experiment suggests measurement and analysis of vibrational spectra. For quantum chemical calculations, semiempirical methods (MNDO and AM1) were chosen. In most calculations, the MNDO/H method was preferred because of the presence of many H-bonds in the surface zone. For verification of calculations, we calculated the structures and vibrational spectra of water and ammonia molecules and the water-ammonia complex and compared the results with experimental and ab initio (extended basis) data; MNDO/H proved to be an optimal method giving reliable results. Russian Peoples' Friendship University. Translated fromZhurnal Strukturnoi Khimii, Vol. 36, No. 1, pp. 58–69, January–February, 1995. Translated by L. Smolina     

Soliton-magnon scattering in a two-dimensional isotropic magnetic material

We use the generalized σ-model to analytically study the solution of the problem of magnon scattering in two-dimensional isotropic ferromagnets and antiferromagnets in the presence of a Belavin-Polyakov soliton. We obtain the exact analytical solution to this problem for the partial mode with the azimuthal quantum number m=1. The scattering amplitude for other values of m (i.e., values not equal to unity) are studied analytically in the long-and short-wavelength approximations and also numerically for an arbitrary value of the wave number. We establish the general laws governing the soliton-magnon interaction. For a magnetic material of finite dimensions we calculate the frequencies of the magnon modes. We also use the data on local modes to derive the equations of motion of the soliton. Finally, we calculate the low-temperature (long-wavelength) asymptotic behavior of the magnon density of states due to the soliton-magnon interaction. Zh. éksp. Teor. Fiz. 116, 1091–1114 (September 1999)     

The electronic states of naphthalene molecules adsorbed on a zeolite

Physical principles are considered for this method of examining interactions. Changes in absorption and fluorescence spectra are examined in relation to Van der Waals, electrostatic, and exchange interactions. Major spectral criteria are presented for the types of interaction and are illustrated by reference to naphthalene adsorbed on zeolites. Spectra at 77 K show that the adsorbed molecules are in two different states: in one they are bound by Van der Waals forces, while in the other a charge-transfer complex is formed. Examination at intervals after preparation shows that the adsorbed naphthalene is gradually oxidized.     

Thin ferromagnetic nanodisk in transverse magnetic field

The magnetization of a ferromagnetic nanodisk is studied using micromagnetic modeling. It is demonstrated that, under an external magnetic field applied perpendicular to the disk surface, magnetic phase transitions can occur between uniform states, between uniform and vortex states, and between vortex states with different directions of polarization. A simple variation model is proposed describing the observed magnetic states quantitatively.     

Continuous symmetry of C60 fullerene and its derivatives

Conventionally, the I(h) symmetry of fullerene C(60) is accepted, which is supported by numerous calculations. However, this conclusion results from the consideration of the molecule electron system, of its odd electrons in particular, in a closed-shell approximation without taking the electron spin into account. Passing to the open-shell approximation has led to both the energy and the symmetry lowering up to C(i). Seemingly contradicting to a high-symmetry pattern of experimental recording, particularly concerning the molecule electronic spectra, the finding is considered in this Article from the continuous symmetry viewpoint. Exploiting continuous symmetry measure and continuous symmetry level approaches, it was shown that formal C(i) symmetry of the molecule is by 99.99% I(h). A similar continuous symmetry analysis of the fullerene monoderivatives gives a reasonable explanation of a large variety of their optical spectra patterns within the framework of the same C(1) formal symmetry exhibiting a strong stability of the C(60) skeleton. TOC color pictures present chemical portrait of C(60) in terms of atomic chemical susceptibility (Sheka, E. Fullerenes: Nanochemistry, Nanomagnetism, Nanomedicine, Nanophotonics; CRC Press: Taylor and Francis Group, Boca Raton, 2011).     

Spectroscopy of Molecular Crystals A Bibliography for 1984

The 1984 Bibliography continues the series of annual issues of Bibliographies Spectroscopy of Molecular Crystals. The full list of these issues from 1957–1968 may be found in Molecular Crystals and Liquid Crystals, 6, 175(1969). The issues for 1969, 1970, 1971, 1972, 1973, 1974, 1975, 1976, 1977, 1978, 1979, 1980, 1981, 1982 and 1983 are published ibid. 14, 329(1971), 17,55(1972), 19,331(1973), 26,87(1974), 30,239(1975), 33,261(1976), 39,259(1977), 46,25(1978), 54, 60(1979), 61,251(1980), 73, 105(1981), 91, 197(1983), 104, 1(1984), and 135, 129(1986).     

Sequence of Phase Transitions in Solid Mbba

Combined neutron diffraction and Raman scattering measurements were carried out on a series of different phases of the same MBBA sample. The change in the diffraction patterns and in the optical spectra are used to indicate the transitions between the different phases investigated in the whole temperature range of interest. Besides the isotropic and nematic liquid crystalline phases, 7 different solid structures were found and a schematic phase diagram was constructed to show the thermal procedur for producing these phases.