全文获取类型
收费全文 | 1927篇 |
免费 | 181篇 |
国内免费 | 249篇 |
专业分类
化学 | 1291篇 |
晶体学 | 17篇 |
力学 | 166篇 |
综合类 | 36篇 |
数学 | 244篇 |
物理学 | 603篇 |
出版年
2024年 | 3篇 |
2023年 | 19篇 |
2022年 | 40篇 |
2021年 | 52篇 |
2020年 | 64篇 |
2019年 | 54篇 |
2018年 | 55篇 |
2017年 | 45篇 |
2016年 | 65篇 |
2015年 | 73篇 |
2014年 | 93篇 |
2013年 | 121篇 |
2012年 | 126篇 |
2011年 | 147篇 |
2010年 | 129篇 |
2009年 | 88篇 |
2008年 | 106篇 |
2007年 | 133篇 |
2006年 | 121篇 |
2005年 | 97篇 |
2004年 | 73篇 |
2003年 | 67篇 |
2002年 | 73篇 |
2001年 | 62篇 |
2000年 | 39篇 |
1999年 | 37篇 |
1998年 | 42篇 |
1997年 | 50篇 |
1996年 | 48篇 |
1995年 | 34篇 |
1994年 | 38篇 |
1993年 | 25篇 |
1992年 | 30篇 |
1991年 | 30篇 |
1990年 | 24篇 |
1989年 | 11篇 |
1988年 | 16篇 |
1987年 | 6篇 |
1986年 | 5篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1978年 | 1篇 |
1975年 | 1篇 |
1973年 | 3篇 |
1971年 | 1篇 |
排序方式: 共有2357条查询结果,搜索用时 109 毫秒
21.
22.
A new nondestructive testing (NDT) technique, which is based on Electronic Speckle Pattern Interferometry (ESPI) and digital image processing with quasi phase shift and gradient technique, is presented. A simple phase reduction algorithm is developed, which replaced an accurate phase shifter. Compared with other phase shift techniques, this method is insensitive to environmental vibration and air disturbance, has visible procedures and results allows the object to move slowly during the inspection procedure, does not need phase unwrapping, and has a quick image processing speed. As an application, this NDT technique is used to detect defects in composite materials and the resulting deformation phase gradient image shows a better visual effect than normal ESPI. 相似文献
23.
应用一种新颖的无损伤测量技术-连续波电光检测法(CWEOP)对GaAs/GaAlAs单异质结发光管列阵电场分布进行了扫描测量。实验结果反映了器件内电流注入的方向和载流子扩展情况;通过比较各单元电场分布,反映器件发光均匀性。文中详细介绍了测量原理、实验装置和实验结果及讨论,最后用计算机对电场分布作了模拟计算并与实验结果进行了对照。 相似文献
24.
25.
Hong She Wang Jun E. Zeng 《中国化学快报》2007,18(12):1447-1450
Synthesis of symmetrical diaryl sulfoxides from arenes and thionyl chloride in the presence of a catalytic amount of iodine at room temperature under solvent-free conditions is described.Mild reaction conditions,easy workup,high yield,and easily available catalyst are important features of this method. 相似文献
26.
27.
This paper describes a highly enantioselective epoxidation of alpha,beta-unsaturated esters using the fructose-derived ketone 2 as catalyst and Oxone as oxidant. High ee's have been obtained for a number of trans and trisubstituted substrates (82-98% ee). The results described show that it is feasible for dioxiranes to effectively epoxidize electron-deficient olefins with high ee's. 相似文献
28.
29.
Bitao Su Ke Wang Jie Bai Hongmei Mu Yongchun Tong Shixiong Min Shixiong She Ziqiang Lei 《Frontiers of Chemistry in China》2007,2(4):364-368
Fe3+-doped TiO2 composite nanoparticles with different doping amounts were successfully synthesized using sol-gel method and characterized
by X-ray diffraction (XRD), transmission electron microscopy (TEM) and ultravioletvisible spectroscopy (UV-Vis) diffuse reflectance
spectra (DRS). The photocatalytic degradation of methylene blue was used as a model reaction to evaluate the photocatalytic
activity of Fe3+/TiO2 nanoparticles under visible light irradiation. The influence of doping amount of Fe3+ (ω: 0.00%–3.00%) on photocatalytic activities of TiO2 was investigated. Results show that the size of Fe3+/TiO2 particles decreases with the increase of the amount of Fe3+ and their absorption spectra are broaden and absorption intensities are also increased. Doping Fe3+ can control the conversion of TiO2 from anatase to rutile. The doping amount of Fe3+ remarkably affects the activity of the catalyst, and the optimum efficiency occurs at about the doping amount of 0.3%. The
appropriate doping of Fe3+ can markedly increase the catalytic activity of TiO2 under visible light irradiation.
__________
Translated from Journal of Northwest Normal University (Natural Science), 2006, 42(6): 55–56 [译自: 西北师范大学学报(自然科学版)] 相似文献
30.
The hydrothermal reaction of NaVO(3).H(2)O, barbituric acid, NH(2)NH(2).2HCl, H(3)PO(4), and H(2)O gave a novel heteropolyoxovanadate Na(6)[(P(V)O(4))V(V)(6)V(IV)(12)O(39)](2).H(3)PO(4).31H(2)O (1) and an unexpected phase Na(2)[C(12)H(6)N(6)O(9)].7H(2)O (2). The basic building blocks in 1 are the six-capped sphere-shaped heteropoly anion [(P(V)O(4))V(V)(6)V(IV)(12)O(39)](3-) with framework similar to that of the reported polyoxovanadates possessing [V(18)O(42)] clusters encapsulating VO(4) or other ions. These heterpoly anionic units are linked via V[bond]O[bond]V bridges into an interesting 3D straight-channel structure. The structure of 2 consists of novel organic anions ([C(12)H(6)N(6)O(9)](2-), 5,5-bis(2',4',6'-trioxopyrimidyl)barbital, representing the first oxidized barbituric acid trimer) linked via sodium ions into 1D hollow tubes with diameter of 4.49 x 6.86 A and further connected into a three-dimensional framework via hydrogen bonds. 相似文献