Chemically induced enhancement of the opto-electronic response of Halobacterium purple membrane monolayer

Acetylation of purple membranes (PM) significantly enhances the surface photovoltage that they exhibit, if adsorbed as a monolayer on a solid surface; we suggest that this increase is due to the improved orientation of the PM on the surface.     

Two-stage queueing network models for quality control and testing

We study sojourn times in a two-node open queueing network with a processor sharing node and a delay node, with Poisson arrivals at the PS node. Motivated by quality control and blood testing applications, we consider a feedback mechanism in which customers may either leave the system after service at the PS node or move to the delay node; from the delay node, they always return to the PS node for new quality controls or blood tests. We propose various approximations for the distribution of the total sojourn time in the network; each of these approximations yields the exact mean sojourn time, and very accurate results for the variance. The best of the three approximations is used to tackle an optimization problem that is mainly inspired by a blood testing application.     

Directly Bound Deuterons Increase X-Nuclei Hyperpolarization using Dynamic Nuclear Polarization

Deuterated ¹³C sites in sugars (D-glucose and 2-deoxy-D-glucose) showed 6.3-to-17.5-fold higher solid-state dynamic nuclear polarization (DNP) levels than their respective protonated sites at 3.35T. This effect was found to be unrelated to the protonation of the bath. Deuterated ¹⁵N in sites bound to exchangeable protons ([¹⁵N₂]urea) showed a 1.3-fold higher polarization than their respective protonated sites at the same magnetic field. This relatively smaller effect was attributed to incomplete deuteration of the ¹⁵N sites due to the solvent mixture. For a ¹⁵N site that is not bound to protons or deuterons ([¹⁵N]nitrate), deuteration of the bath did not affect the polarization level. These findings suggest a phenomenon related to DNP of X-nuclei directly bound to deuteron(s) as opposed to proton(s). It appears that direct binding to deuterons increases the solid-state DNP polarization level of X-nuclei which are otherwise bound to protons.