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81.
Williams RM Kelly JF Hartman JS Sharpe SW Taubman MS Hall JL Capasso F Gmachl C Sivco DL Baillargeon JN Cho AY 《Optics letters》1999,24(24):1844-1846
Frequency stabilization of mid-IR quantum cascade (QC) lasers to the kilohertz level has been accomplished by use of electronic servo techniques. With this active feedback, an 8.5-microm QC distributed-feedback laser is locked to the side of a rovibrational resonance of nitrous oxide (N(2) O) at 1176.61cm (-1) . A stabilized frequency-noise spectral density of 42Hz/ radicalHz has been measured at 100 kHz; the calculated laser linewidth is 12 kHz. 相似文献
82.
Blake TA Glendening ED Sams RL Sharpe SW Xantheas SS 《The journal of physical chemistry. A》2007,111(44):11328-11341
We present experimental infrared spectra and theoretical electronic structure results for the geometry, anharmonic vibrational frequencies, and accurate estimates of the magnitude and the origin of the ring-puckering barrier in C4F8. High-resolution (0.0015 cm-1) spectra of the nu12 and nu13 parallel bands of perfluorocyclobutane (c-C4F8) were recorded for the first time by expanding a 10% c-C4F8 in helium mixture in a supersonic jet. Both bands are observed to be rotationally resolved in a jet with a rotational temperature of 15 K. The nu12 mode has b2 symmetry under D2d that correlates to a2u symmetry under D4h and consequently has +/- <-- +/- ring-puckering selection rules. A rigid rotor fit of the nu12 band yields the origin at 1292.56031(2) cm-1 with B' = 0.0354137(3) cm-1 and B' ' = 0.0354363(3) cm-1. The nu13 mode is of b2 symmetry under D2d that correlates to b2g under D4h, and in this case, the ring-puckering selection rules are +/- <-- -/+ . Rotational transitions from the ground and first excited torsional states will be separated by the torsional splitting in the ground and excited vibrational states, and indeed, we observe a splitting of each transition into strong and weak intensity components with a separation of approximately 0.0018 cm-1. The strong and weak sets of transitions were fit separately again using a rigid rotor model to give nu13(strong) = 1240.34858(4) cm-1, B' = 0.0354192(7) cm-1, and B' ' = 0.0354355(7) cm-1 and nu13(weak) = 1240.34674(5) cm-1, B' = 0.0354188(9) cm-1, and B' ' = 0.0354360(7) cm-1. High-level electronic structure calculations at the MP2 and CCSD(T) levels of theory with the family of correlation consistent basis sets of quadruple-zeta quality, developed by Dunning and co-workers, yield best estimates for the vibrationally averaged structural parameters r(C-C) = 1.568 A, r(C-F)alpha = 1.340 A, r(C-F)beta = 1.329 A, alpha(F-C-F) = 110.3 degrees , thetaz(C-C-C) = 89.1 degrees , and delta(C-C-C-C) = 14.6 degrees and rotational constants of A = B = 0.03543 cm-1 and C = 0.02898 cm-1, the latter within 0.00002 cm-1 from the experimentally determined values. Anharmonic vibrational frequencies computed using higher energy derivatives at the MP2 level of theory are all within <27 cm-1 (in most cases <5 cm-1) from the experimentally measured fundamentals. Our best estimate for the ring-puckering barrier at the CCSD(T)/CBS (complete basis set) limit is 132 cm-1. Analysis of the C4F8 electron density suggests that the puckering barrier arises principally from the sigmaCC-->sigmaCF hyperconjugative interactions that are more strongly stabilizing in the puckered than in the planar form. These interactions are, however, somewhat weaker in C4F8 than in C4H8, a fact that is consistent with the smaller barrier in the former (132 cm-1) with respect to the latter (498 cm-1). 相似文献
83.
84.
The solvation of a variety of ions by the dipolar aprotic solvents acetonitrile, sulfolane, and dimethylsulfoxide was studied through the influence of salts on the proton magnetic resonance chemical shifts of the solvents. In the case of acetonitrile the results were supplemented with infrared measurements, which showed that in general anions affect only the C–H and cations both the C–C and particularly the CN stretching frequencies of acetonitrile. The results are discussed in conjunction with transport and other data already in the literature. Current views on the structure of these solvents are summarized.From the Ph.D. thesis of this author, University of Pittsburgh, 1972. 相似文献
85.
G. J. Sharpe 《Combustion Theory and Modelling》2013,17(4):717-738
The linear stability of freely propagating, adiabatic, planar premixed flames is investigated in the context of a simple chain-branching chemistry model consisting of a chain-branching reaction step and a completion reaction step. The role of chain-branching is governed by a crossover temperature. Hydrodynamic effects, induced by thermal expansion, are taken into account and the results compared and contrasted with those from a previous purely thermal-diffusive constant density linear stability study. It is shown that when thermal expansion is properly accounted for, a region of stable flames predicted by the constant density model disappears, and instead the flame is unstable to a long-wavelength cellular instability. For a pulsating mode, however, thermal expansion is shown to have only a weak effect on the critical fuel Lewis number required for instability. These effects of thermal expansion on the two-step chain-branching flame are shown to be qualitatively similar to those on the standard one-step reaction model. Indeed, as found by constant density studies, in the limit that the chain-branching crossover temperature tends to the adiabatic flame temperature, the two-step model can be described to leading order by the one-step model with a suitably defined effective activation energy. 相似文献
86.
I. Kleiner N. Moazzen-Ahmadi T.A. Blake S.W. Sharpe J.T. Hougen 《Journal of Molecular Spectroscopy》2008,252(2):214-229
The lowest small-amplitude vibration in acetaldehyde (CH3CHO) is the in-plane aldehyde scissors mode ν10 at 509 cm−1. This mode lies about 175 cm−1 above the top of the barrier to internal rotation of the methyl group and is relatively well separated from other small-amplitude vibrational states (the next fundamental occurring more than 250 cm−1 higher). It thus provides an excellent example of an isolated small-amplitude fundamental (bright state) embedded in a bath of dark states. Since the bath states at these energies are not too dense, and since they arise purely from states of the large-amplitude torsional vibration of the methyl rotor, a detailed spectroscopic analysis of interactions between the bright state and the bath states should be possible. This paper represents the first step toward that goal. We have assigned several thousand transitions in the ν10 band (J ? 28, K ? 12), and have carried out a simultaneous fit of 2400 of these transitions (J ? 15, K ? 9) with over 8100 transitions to the torsional bath state levels. Three vibration-torsion interactions, which give rise to rather global level shifts of the order of 1 cm−1 in the ν10 levels, have been identified and quantitatively fit. A number of vibration-torsion-rotation interactions, which give rise to localized (avoided-crossing) shifts in ν10 have also been determined. The present analysis indicates the need for reliable spectroscopic information on more of the torsional bath states in the immediate vicinity of the ν10 levels. Possible ways of obtaining such information in future studies are considered. 相似文献
87.
Heterogeneous recombination of O + CO → CO2 over a solid CO2 surface at 77 K was investigated. A modified discharge flow setup was used to generate low O atom concentrations by the reaction N + NO → N2 + O(3P). The O atom concentrations were measured upstream and downstream of the solid CO2 substrate using resonance fluorescence by monitoring the unresolved 130.3 nm triplet transition 3S1 ? 3P2,1,0 at the two fixed points. CO2 formed was determined by measuring the β activity from C14O2 produced from CO containing C14O as a reactant gas. The CO2 formation was found to be first order in CO and independent of O atom concentration over the entire range of 4.3 × 1012 to 1.9 × 1014 cm?3 and 1.2 × 1011 to 5.6 × 1012 cm?3 for CO and O respectively. The first order recombination coefficient, λCO was found to be 1.4 (±.38) × 10?5. 相似文献
88.
89.
Merriam AJ Sharpe SJ Shverdin M Manuszak D Yin GY Harris SE 《Physical review letters》2000,84(23):5308-5311
We demonstrate efficient, pulsed, gas-phase, nonlinear frequency conversion in a quadruply resonant, double- Lambda system and, simultaneously, verify theoretical predictions of Rabi-frequency matching unique to absorbing nonlinear media. This system is used to up-convert ultraviolet light at 233 nm to the vacuum ultraviolet at 186 nm in atomic Pb vapor with small-signal conversion efficiencies exceeding 30% and with modest atomic density-length (NL) products (scale 10(14) cm(-2)) and optical power densities (10-100 kW/cm(2)). 相似文献
90.
The validity of the split-Hopkinson-pressurebar technique for measuring dynamic strain and stress is examined by comparing the average strain computed by use of that technique with the strain at the midpoint of the sample. The midpoint strain is measured by use of the inter-ferometric-strain-gage method. It is found that the midpoint surface strain and the average strain agree quite well after a strain of approximately 1 percent. It is concluded that the pressure-bar technique is valid for large strains. 相似文献