A New Cyclic Bisdesmoside from Tubers of Bolbostemma paniculatum

The structure of tubeimoside V (1), a new cyclic bisdesmoside, isolated from tubers of Bolbostemma paniculatum (Tu Bei Mu), was established by means of 2D NMR spectral and chemical methods. Compound 1 has inter-saccharide chain bridging by a dicrotalic acid to form aunique macrocyclic structure.     

四卤化碳: 强碱反应体系顺磁共振研究

单电子转移反应是物理有机化学中十分活跃的研究领域之一,现已发现许多有机反应中都存在着单电子转移过程。探讨不同的单电子转移反应体系,了解其中电子给、受体之间的相互作用,不仅对深入了解反应机理有理论     

空气-氩气冷却ICP-AES测定环烷酸镍中的镍、铁、镁和钙

本文介绍采用空气-氩气冷却ICP直接测定了以甲基异丁基酮稀释的环烷酸镍溶液中部分金属的含量。并研究了方法的工作条件、检出限和乙醇的影响。本法快速简便,结果令人满意。     

用氟离子电极对土壤中铝作直接电位法测定

本文提出用氟离子电极对土壤中铝作直接电位法测定。大大减少了以往的用终点电位滴定法测定土壤中铝含量的实验步骤与时间,并较大地提高了测定的准确度。方法是取一定量的土壤试液加入到pH为5,离子强度为1.0的缓冲溶液中,再加入一定量的F~-离子标液,让F~-与Al_(3 )络合稳定后,用氟离子电极测出溶液中的游离态F~-浓度,从而计算出Al~(3 )的总浓度。     

Experimental investigation on thermal conductivity and viscosity of aluminum nitride nanofluid

Aluminum nitride nanoparticles (AlNs) have been found to be a good additive for enhancing the thermal conductivity of traditional heat exchange fluids.At a volume fraction of 0.1,the thermal conductivity enhancement ratios are 38.71% and 40.2%,respectively,for ethylene glycol and propylene glycol as the base fluids.Temperature does not have much influence on the enhanced thermal conductivity ratios of the nanofluids,though a volume fraction of 5.0% appears to signify a critical concentration for rheology:fo...     

反射倒向随机微分方程的逆比较问题(Ⅰ)

在Briand,Coquet,Hu,Memin,Peng[1],Coquet,Hu,Memin,Peng[2],Chen[3],Jiang [8]等中,研究了倒向随机微分方程的逆比较定理,就是通过比较倒向随机微分方程的解来比较倒向随机微分方程的生成元问题．在文[9]中Li和Tang首次研究了反射倒向随机微分方程的逆比较问题．本文考虑在更一般的条件下,反射倒向随机微分方程的生成元的逆比较问题．     

一种守恒型间断跟踪法在一维单守恒律方程上的程序实现

茅在近几年发展了一种守恒型的间断跟踪法（见[6],[7]），该跟踪法是以解的守恒性质作为跟踪的机制而不是传统的跟踪法利用Rankine-Hugoniot条件。本文的目的是对该算法在一维单守恒律的情况进行程序实现，做成一个对任意初值问题都适应的强健的算法，可处理任意的间断相互作用。在文章的第三节给出了一个数值算例，并与用ENO格式（见[8]所算得的结果进行比较。     

Preparation and Modification of Heterogeneous Vanadium-Titanium-Based Catalysts

Russian Journal of General Chemistry - Vanadium-titanium-based catalysts are among the most widely used industrial catalysts. This article reviews the progress in research of preparation methods...     

Synthesis of mono-substituted derivatives of 6-aminoquinoline

Several 6-aminoquinoline derivatives,which could be used in drug design,have been synthesized.The reaction conditions were comparatively studied,and the p-chloroaniline was used as optimum oxidant in Skraup-Doebner-Von Miller reaction.The nitro group was reduced effectively by SnCl₂ with no halo-removed occurred.     

Synthesis of α-fluoro-β-amino acids via the Reformatsky reaction of chiral N-tert-butylsulfinylimines with ethyl bromofluoroacetate

Treatment of chiral N-tert-butyl sulfinylimines with ethyl bromofluoroacetate in the presence of activated Zn dust in THF afforded the α-fluoro- β-amino acid derivatives in good yields(70-86%) and moderate diastereoselectivity(66:34-92:8).