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151.
In this research, a simple, sensitive chemiluminescence (CL) method for the determination of humic acid (HA) in water samples was first developed based on the redox reaction between humic acid and cerium(IV) in the acidic condition. Different with the former redox CL reaction which occurred in alkaline solution, no enhancers were needed and neither precipitation nor a second contamination would occur in the present CL system. Comparing with other spectrometric methods, we find that the proposed analysis system had better applicability and accuracy. Under the optimal experiment conditions, the CL peak height was linear with the concentration of HA in the range of 0.03 to 10.0 microg mL(-1). The detection limit is 0.01 microg mL(-1) (S/N = 3), and the relative standard deviation was 2.3% for 0.5 microg mL(-1) HA solution with eleven repeated measurements. The present CL method was successfully applied to the determination of HA in tap water, spring water and river water samples with good recovery from 90.0 to 110.0%. A possible CL mechanism was proposed based on the results of UV and fluorescence spectrometry and the CL spectrum of HA. It was speculated that the semi-quinone radicals in the excited state were the emitters. 相似文献
152.
本文采用解析的方法计算了应变Si1-xGex层中p型杂质电离度与Ge组分x、温度T以及掺杂浓度N的关系.发现常温时,在同一Ge组分下,随着掺杂浓度的升高,杂质的电离度的先变小,而后又迅速上升到1.在同一掺杂浓度下,轻掺杂时,杂质的电离度随Ge组分的增加先变大,而后几乎不变;重掺杂时,杂质电离能变为0后,杂质电离度为1.低温下,轻掺杂时,载流子低温冻析效应较为明显,杂质的电离度普遍较小,当掺杂浓度大于Mott转换点时,载流子冻析效应不再明显,电离率迅速上升到1.在同一Ge组分下,随着掺杂浓度的升高,杂质的电离度先变小,后变大,而后又迅速上升到1.在同一掺杂浓度下,轻掺杂时,杂质的电离度随Ge组分的增加变大;重掺杂时,杂质电离能变为0后,杂质电离度为1. 相似文献
153.
154.
Chang-jian Zhao 《中国科学A辑(英文版)》2007,50(9):1347-1360
In this paper, we first introduce a concept of L
p
-dual Quermassintegral sum function of convex bodies and establish the polar projection Minkowski inequality and the polar
projection Aleksandrov-Fenchel inequality for L
p
-dual Quermassintegral sums. Moreover, by using Lutwak’s width-integral of index i, we establish the L
p
-Brunn-Minkowski inequality for the polar mixed projection bodies. As applications, we prove some interrelated results.
This work was partially supported by the National Natural Science Foundation of China (Grant No. 10271071), Zhejiang Provincial
Natural Science Foundation of China (Grant No. Y605065) and Foundation of the Education Department of Zhejiang Province of
China (Grant No. 20050392) 相似文献
155.
156.
The spin coating method was used to assemble polymer (Poly (2,5-dibutoxy-1,4-phenylenevinylene)) (DBO-PPV) into the pores of porous alumina which was prepared by anodization. Four peaks in the photoluminescence (PL) spectra of the composite, with contributions from the DBO-PPV and porous alumina, were found. It was also found that the light emitting from the porous alumina could excite the photoluminescence of DBO-PPV. The nanometer effect of the porous alumina can lead to a blue shift of 90 nm of the PL peaks of DBO-PPV. 相似文献
157.
Natural convections in conjugated single and double enclosures 总被引:7,自引:0,他引:7
The natural convection in single and double conjugated enclosures are numerically investigated. The single and double enclosures are formed by low conductance walls with finite thickness. The outside vertical surfaces of the conducting walls are of the third kind of boundary condition while the top and bottom outside surfaces are adiabatic. The problem studied is characterized by a dominant horizontal temperature gradient and the thermal boundary conditions at the cavity surfaces can not be specified in priori. Numerical results reveal the characteristics in such kind of enclosures and show the importance of the thermal boundary conditions on the natural convection in enclosures. It is also found that the natural convections in the conjugated double enclosures are basically the same, with a major difference in their fluid temperature levels. 相似文献
158.
Instability of Solitary Waves in Nonlinear Composite Media 总被引:1,自引:0,他引:1
Ye Zhao 《应用数学学报(英文版)》2007,23(2):311-318
In this paper,we investigate a class of Hamiltonian systems arising in nonlinear composite media.By detailed analysis and computation we obtain a decaying estimates on the semigroup and prove the orbitalinstability of two families of explicit solitary wave solutions (slow family in anisotropic case and solitary wavesin isotropic case),which theoretically verify the related guess and numerical results. 相似文献
159.
160.
采用真空熔融缓冷方法制备了单相β-Zn4Sb3以及含有过量Zn的β-Zn4Sb3块体热电材料.在300—700K的温度范围内测试了材料的电导率、Seebeck系数和热导率,研究了β-Zn4Sb3化合物中过量Zn的分布状态及其对材料热电性能的影响规律.结果表明:过量的Zn作为第二相较均匀的分布在β-Zn4Sb3的晶界上,随着Zn含量增加,材料电导率和热导率上升,Seebeck系数下降,Zn第二相的引入能有效提高材料的功率因子,Zn过量2at%的材料在700K时其ZT值达到1.10. 相似文献