Determination of Total Iron in Environmental Samples by Solid Phase Extraction with Dimethyl(E)‐2‐(2‐Methoxyphenoxy)‐2‐Butenedioate

A novel solid phase extraction technique for determination of total iron in environmental water samples was developed. The method is based on sorption of Fe(III) ions on octadecyl silica membrane disk modified with a new synthetic ligand dimethyl(E)‐2‐(2‐methoxyphenoxy)‐2‐butenedioate (I). Iron(III) is quantitatively retained on the disk in the pH range of 3–7 at a flow rate of 1–7 mL min⁻¹. The Fe(III) eluted with 10 mL of 0.01 M EDTA and than was measured by flame atomic absorption spectrometry (FAAS) at 248.3 nm. The maximum capacity disk modified by 7 mg of ligand was found to be 197 ± 2 μg of iron(III). The breakthrough volume was greater than 2000 mL. The iron(III) was completely recovered (> 99%) from water with a preconcentration factor of more than 200. The limit of detection of the proposed method was 1.00 ng mL⁻¹. The various cationic and anionic interferences had no effect on the recovery of iron(III) from the binary mixtures. The proposed method was successfully applied to determination of total iron from three different water samples.     

Toxicity of nanomaterials

Nanoscience has matured significantly during the last decade as it has transitioned from bench top science to applied technology. Presently, nanomaterials are used in a wide variety of commercial products such as electronic components, sports equipment, sun creams and biomedical applications. There are few studies of the long-term consequences of nanoparticles on human health, but governmental agencies, including the United States National Institute for Occupational Safety and Health and Japan's Ministry of Health, have recently raised the question of whether seemingly innocuous materials such as carbon-based nanotubes should be treated with the same caution afforded known carcinogens such as asbestos. Since nanomaterials are increasing a part of everyday consumer products, manufacturing processes, and medical products, it is imperative that both workers and end-users be protected from inhalation of potentially toxic NPs. It also suggests that NPs may need to be sequestered into products so that the NPs are not released into the atmosphere during the product's life or during recycling. Further, non-inhalation routes of NP absorption, including dermal and medical injectables, must be studied in order to understand possible toxic effects. Fewer studies to date have addressed whether the body can eventually eliminate nanomaterials to prevent particle build-up in tissues or organs. This critical review discusses the biophysicochemical properties of various nanomaterials with emphasis on currently available toxicology data and methodologies for evaluating nanoparticle toxicity (286 references).     

Development of ultrasound-assisted emulsification solidified floating organic drop microextraction for determination of trace amounts of iron and copper in water, food and rock samples

A simple and efficient liquid-phase microextraction technique was developed using ultrasound-assisted emulsification solidified floating organic drop microextraction combined with flame atomic absorption spectrometry, for the extraction and determination of trace amounts of iron and copper in real samples. 2-Mercaptopyridine n-oxide was used as chelating agent and 1-dodecanol was selected as extraction solvent. The factors influencing the complex formation and extraction were optimized. Under optimum conditions, an enrichment factor of ~13 was obtained for both iron and copper from only 6.7 mL of aqueous phase. The analytical curves were linear between 40–800 and 20–1,200 μg L^?1 for iron and copper respectively. Based on three SD of the blank, the detection limits were 8.6 and 4.1 μg L^?1 for iron and copper respectively. The relative SDs for ten replicate measurements of 500 μg L^?1 of metal ions were 2.9 and 1.2 for iron and copper respectively. The proposed method was successfully applied for determination of iron and copper in environmental waters and some food samples including chess, rice, honey and powdered milk. Finally, method validation was made using rock certified reference material. A student’s t test indicated that there was no significant difference between experimental results and certified values.     

Vibro-acoustic response of an elliptical plate-cavity coupled system to external shock loads

A general fully coupled three-dimensional vibro-acoustic model is developed to investigate the forced non-stationary acousto-structural response of a thin elastic plate of elliptical planform which is backed by a reverberant, rigid, and finite (closed) elliptic cylindrical acoustic enclosure, while under the action of general external transverse loads of arbitrary temporal and spatial variations. The Laplace transform with respect to the time coordinate is invoked, and the classical method of separation of variables in elliptic coordinates is used to obtain the transformed solutions as a linear combination of even and odd modes in terms of products of radial and angular Mathieu functions. A linear system of coupled algebraic equations is ultimately obtained, which is truncated and then solved numerically by implementing Durbin’s numerical Laplace transform inversion scheme. Detailed numerical simulations are conducted for the temporal histories of plate center-point displacement and on-axis cavity acoustic pressure for air-coupled elliptic aluminum plates of selected aspect ratios when subjected to external loadings of practical interest (i.e., an impulsive point load, a uniformly distributed pulse load, and a blast load). Also, acoustic radiation into the backing enclosure is examined by using appropriate 2D images of the internal sound field for selected cavity depths and plate eccentricities. The presented results confirm that the acousto-elastic characteristics of the coupled plate-cavity system are significantly influenced by the plate aspect ratio, cavity depth and the transverse loading configuration. Validity of the work is established through the computations made by using a commercial finite element package.     

Instability and pattern formation in reaction-diffusion systems: a higher order analysis

We analyze the condition for instability and pattern formation in reaction-diffusion systems beyond the usual linear regime. The approach is based on taking into account perturbations of higher orders. Our analysis reveals that nonlinearity present in the system can be instrumental in determining the stability of a system, even to the extent of destabilizing one in a linearly stable parameter regime. The analysis is also successful to account for the observed effect of additive noise in modifying the instability threshold of a system. The analytical study is corroborated by numerical simulation in a standard reaction-diffusion system.     

Prediction of fracture in grain boundaries of nano-coatings using cohesive zone elements

A cohesive zone element technique (CZ) is applied to study grain boundary fracture in nano coating layers (see [1]). This goes along with the investigations of the delamination and fracture behavior of the coatings and the substrate interface. The main motivation is to investigate antiadhesive and wear resistant properties of coatings made of ceramics produced by the High Power Pulsed Magnetron Sputtering (HPPMS) technique [2]. Different physical conditions in HPPMS result into different grain morphologies with different mechanical properties. Therefore prediction of fracture and damage in such systems can lead to the optimum choice of process parameters in order to gain the best fracture resistance properties for the coatings. To illustrate the applicability of the model, several simulations with different mechanical and structural properties are performed. The developed CZ element model is capable of modeling the separation, the contact and also the irreversible reloading conditions in different directions [3]. The model is further developed to be applicable for geometrically complex interfaces including different bonding behaviors, with a high robustness. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Generalized Interface Models With Damage in Gradient Plasticity

Gradient plasticity can account for experimentally observed size effects. Here, a previously developed gradient plasticity model is extended to account for interface delamination processes. The crystal plasticity model is based on the gradient of an equivalent plastic strain measure. A modification of the related boundary conditions allows for the formulation of a generalized cohezive zone model which can take into account the effect of interface delamination on the gradient plasticity solution. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)