Optical and Photoacoustic Properties of Laser-Ablated Silver Nanoparticles in a Carbon Dots Solution

This study used the carbon dots solution for the laser ablation technique to fabricate silver nanoparticles. The ablation time range was from 5 min to 20 min. Analytical methods, including Fourier transform infrared spectroscopy (FTIR), UV-visible spectroscopy, transmission electron microscopy, and Raman spectroscopy were used to categorize the prepared samples. The UV-visible and z-scan techniques provided optical parameters such as linear and nonlinear refractive indices in the range of 1.56759 to 1.81288 and 7.3769 × 10⁻¹⁰ cm² W⁻¹ to 9.5269 × 10⁻¹⁰ cm² W⁻¹ and the nonlinear susceptibility was measured in the range of 5.46 × 10⁻⁸ to 6.97 × 10⁻⁸ esu. The thermal effusivity of prepared samples, which were measured using the photoacoustic technique, were in the range of 0.0941 W s^1/2 cm⁻² K⁻¹ to 0.8491 W s^1/2 cm⁻² K⁻¹. The interaction of the prepared sample with fluoride was investigated using a Raman spectrometer. Consequently, the intensity of the Raman signal decreased with the increasing concentration of fluoride, and the detection limit is about 0.1 ppm.     

Constant heat flux solution for mixed convection boundary layer viscoelastic fluid

The mixed convection boundary layer of a viscoelastic fluid past a circular cylinder with constant heat flux is discussed. The boundary layer equations are an order higher than those for the Newtonian (viscous) fluid and the adherence boundary conditions are insufficient to determine the solution of these equations completely. The governing non-similar partial differential equations are transformed into dimensionless forms and then solved numerically using the Keller-box method by augmenting an extra boundary condition at infinity. Numerical results obtained in the form of velocity distributions and temperature profiles are presented for a range of values of the dimensionless viscoelastic fluid parameter. It is found that for some values of the viscoelastic parameter and some negative values of the mixed convection parameter (opposing flow) the momentum boundary layer separates from the cylinder. Heating the cylinder delays separation and can, if the cylinder is warm enough, suppress the separation completely. Similar to the case of a Newtonian fluid, cooling the cylinder brings the separation point nearer to the lower stagnation point.     

Analytical solution of convective oscillating flow at a sinusoidal pressure waveform

The flow of an oscillating motion of viscoelastic fluid in a capillary tube is modelled to determine a sinusoidal waveform effect on the heat transfer performance. Analytical technique based on finite Hankel transformation, incorporating Laplace transformation and combined with confluent hypergeometric function (Kummer’s function) is implemented in time and space with the constitutive model for the viscoelastic fluid. Explicit analytical expressions for the steady, permanent and transient solutions for both the velocity and temperature fields describing the flow at small and large times have been derived. The results are displayed graphically, and the influence of the Prandtl number Pr and transient amplitude \(B_{1}\) is discussed.     

Evolution of Vanadium Redox Flow Battery in Electrode

The vanadium redox flow battery (VRFB) is a highly regarded technology for large-scale energy storage due to its outstanding features, such as scalability, efficiency, long lifespan, and site independence. This paper provides a comprehensive analysis of its performance in carbon-based electrodes, along with a comprehensive review of the system‘s principles and mechanisms. It discusses potential applications, recent industrial involvement, and economic factors associated with VRFB technology. The study also covers the latest advancements in VRFB electrodes, including electrode surface modification and electrocatalyst materials, and highlights their effects on the VRFB system‘s performance. Additionally, the potential of two-dimensional material MXene to enhance electrode performance is evaluated, and the author concludes that MXenes offer significant advantages for use in high-power VRFB at a low cost. Finally, the paper reviews the challenges and future development of VRFB technology.     

Unsteady MHD stagnation-point flow with heat and mass transfer in a micropolar fluid in the presence of thermophoresis and suction/injection

The effect of suction or injection on unsteady MHD flow with heat and mass transfer in a micropolar fluid near the forward stagnation point flow with thermophoresis has been investigated. The problem is reduced to a system of non-dimensional partial differential equations, which are solved numerically using the implicit finite-difference scheme. Profiles for velocity, microrotation, temperature and concentration as well as the skin friction, the rate of heat and mass transfer are determined and presented graphically for physical parameters. The results show that the suction increases the skin friction, the rate of heat and mass transfer while opposite trend is observed for the case of injection. It is also found that the effect of thermophoresis is decrease the concentration boundary layer thickness.     

Application of Carrageenan extract from red seaweed (Rhodophyta) in cosmetic products: A review

Cosmetic industries have expanded globally and will continue to increase as there are consumers. Nowadays, the interest starts to incline towards cosmetics formulated using plant-based ingredients. Marine plants such as seaweed possess numerous natural polysaccharides. Carrageenan is one of the compounds that can be extracted from red seaweed (Rhodophyta). This natural polysaccharide is widely known to act as a thickener, stabilizer, and water-binding agent as well as have diverse biological activities that make it a suitable active ingredient in cosmetic products. The review paper is organized by starting with discussing the significant aspects related to carrageenan which are the source, structure, as well as general and biological properties of carrageenan that make it appropriate to be applied in cosmetics. This paper also highlighted the applications of carrageenan in cosmetics, followed by the extraction method and instrument used.     

Exact solutions for unsteady flow of second grade fluid generated by oscillating wall with transpiration

A problem of unsteady flow of a second grade fluid over flat plates with the impulsive and oscillating motion, starting from rest, and with the wall transpiration is considered. The exact solutions are derived by the Laplace transform, the perturbation techniques, and an extension of the variable separation technique together with similarity arguments. These solutions are written as the sum between the permanent solutions and the transient solutions. The variations of fluid behaviors with various physical parameters are shown graphically and analyzed. The results are validated by comparing the limiting cases of the present paper with the results of the related published articles.     

Heat transfer on peristaltic flow of fourth grade fluid in inclined asymmetric channel with partial slip

In this paper, the effects of slip and heat transfer are studied on the peristaltic transport of a magnetohydrodynamic (MHD) fourth grade fluid. The governing equations are modeled and solved under the long wavelength approximation by using a regular perturbation method. Explicit expressions of solutions for the stream function, the velocity, the pressure gradient, the temperature, and the heat transfer coefficient are presented. Pumping and trapping phenomena are analyzed for increasing the slip parameter. Further, the temperature profiles and the heat transfer coefficient are observed for various increasing parameters. It is found that these parameters considerably affect the considered flow characteristics. Comparisons with published results for the no-slip case are found in close agreement.     

Impact of polyvinylpyrrolidone and quantity of silver nitrate on silver nanoparticles sizing via solvothermal method for dye-sensitized solar cells

The multiple sizing of silver nanoparticles (AgNPs) were synthesized from the miscible compound of ethylene glycol (EG), polyvinylpyrrolidone (PVP) and silver nitrate (AgNO3) via the solvothermal method. During the synthesis, the PVP-AgNO3 was contemplated as a paramount parameter. Using the simple method of solvothermal, the sizing of AgNPs was easily controlled in accord with the augmentation of PVP-AgNO3 at secured and moderate temperature. In regards to the sizing of AgNPs, the presence of minimum agglomeration, the absorption capability and chemical structures were highlighted through a series of verification includes ultraviolet–visible (UV–Vis) spectroscopy, Fourier-transform infrared (FTIR) spectroscopy and transmission electron microscopy (TEM) analysis. The effectiveness of the synthesized AgNPs was further investigated and compared with the commercial AgNPs by incorporating the AgNPs into titanium dioxide (TiO2) semiconductor film-based dye-sensitized solar cells (DSSCs). Results signified that the spherical AgNPs with produced sizing within the range of 19.6 to 45.2 nm were greatly impacting by tunable quantities of PVP-AgNO3, which was validated in the forms of linear equations. A larger size promotes a slower nucleation rate that conduces agglomeration. In opposition to this, the smallest size of AgNPs develops a faster formation rate of Ag ions into AgNPs, inducing the deterrent of agglomeration in light of notable particle dispersion. The power conversion efficiency (PCE) contributed by the incorporation of synthesized AgNPs into TiO2 is also 41.2% higher than that of the commercial AgNPs-TiO2. This is because the synthesized AgNPs provides less agglomeration which led to a better surface plasmonic effect towards the nanoparticles.