Electrochemical reduction of 1,1-dihalo-2,2-disubstituted cyclopropanes

The electrochemical reduction of 1,1-dihalo-2-R-2-methylcyclopropanes was studied by polarography and preparative electrolysis. A mixture of stereoisomeric monoboro- and monochlorocyclopropanes was obtained with preparative yield of 60–70% in preparative electroreduction in methanol against a background of 0.1 M LiClO₄. In the case of bromine derivatives of cyclopropanes (except when R = CN) an effect was found on the part of the current density on the ratio of cis and trans isomers, which was interpreted as a change, in dependence on current density, of the contributions of the reactions of reduction of the starting compounds (S_N2 mechanism) and ionic pairs (S_N1 mechanism). The effect of the solvent (CHCl₃, DMF, DMSO, MeOH) and background salt (LiClO₄, Et₄NBr) on the ratio of stereoisomers is in agreement with this interpretation.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center, Russian Academy of Sciences, Kazan. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 9, pp. 2023–2032, September, 1992.     

Rate of rational approximation and asymptotic monogeneity of functions at points of the finite porosity of a compact set

We study the rate of rational approximation and asymptotic monogeneity of functions at points of the finite porosity of a compact set.Translated from Sovremennaya Matematika i Ee Prilozheniya (Contemporary Mathematics and Its Applications), Vol. 9, Suzdal Conference-3, 2003.     

Effect of Gd-Mn exchange on phase transitions in GdMn<Subscript>2</Subscript>O<Subscript>5</Subscript> induced by a strong magnetic field

Complex studies of the magnetic, magnetoelectric, and magnetoelastic properties of GdMn₂O₅ single crystals in strong pulsed magnetic fields are carried out in order to obtain additional indirect information on the character of the rare-earth and manganese spin ordering. It is shown that magnetic ordering of Gd³⁺ spins affects the manganese sublattice spin orientation and initiates new magnetic phase transitions. The observed magnetoelectric properties of the GdMn₂O₅ system are interpreted in terms of the theory of phase transitions.     

Absolute negative conductivity and zero-resistance states in two-dimensional electron systems: A plausible scenario

We present a model that provides a plausible explanation of the effect of zero-resistance and zero-conductance states in two-dimensional electron systems subjected to a magnetic field and irradiated with microwaves observed in a number of experiments and of the effect’s main features. The model is based on the concept of absolute negative conductivity associated with photon-assisted scattering of electrons on impurities. It is shown that the main features of the effect can be attributed to the interplay of different electron scattering mechanisms.     

Maxwell’s equations in the Majorana representation in a locally isotropic chiral medium

Maxwell’s equations in the Majorana representation are generalized to the case of a chiral medium. A relation between the dynamic variables and the parameters of a chiral medium is found. An expression for the current density 4-vector is obtained for the medium under consideration.     

Dynamics of fluorescence of solid solutions of quantum dots and the organic dye DODCI: Experiment and numerical simulation

The fluorescence of solid solutions of CdSe/ZnS quantum dots and the organic dye DODCI is investigated. It is shown that nonradiative transfer of electronic excitation energy to dye molecules, which with some probability lose their acceptor properties as a result of photoisomerization or photodegradation, is responsible for a significant increase in the fluorescence intensity of a donor. The degree of polarization of the donor fluorescence attains values exceeding 0.5, which is due to the difference in the fluorescence quantum yields of donors with different orientations of the oscillator with respect to the electric vector of an excitation light wave. A numerical simulation of the experimentally observed dependences is performed.