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951.
Khorshidi Parisa Shirazi Reza Haji Seyed Mohammad Miralinaghi Mahsasadat Moniri Elham Saadi Sommayeh 《Research on Chemical Intermediates》2020,46(7):3607-3627
Research on Chemical Intermediates - The aim of the present study was to develop a novel adsorbent through decorating the surface of graphene oxide (GO) nanosheets with nickel ferrite (NiFe2O4)... 相似文献
952.
Hamideh Jalali Seyed Javad Hosseini Safa Ali-Asgari Jafar Izadi Nia 《Journal of heterocyclic chemistry》2020,57(1):419-427
The highly trans-stereoselective reaction of ammonium salt ( AS 2 ) toward (E)-N-benzylidene-4-methylbenzenesulfonamide ( IM 4 ) in the presence of Na2CO3 leading to an aziridine derivative, trans -Az 6 , was theoretically studied using Molecular Electron Density Theory (MEDT) at the B3LYP/6-31G(d) computational level to probe energy transformation, selectivities, and molecular mechanism. The reaction starts by a nucleophilic substitution reaction between 1,4-diazabicyclo [2.2.2]octane ( DABCO ) and phenacyl bromide ( PB ) to form AS 2 which undergoes a proton abstraction by Na2CO3 to produce Ammonium Ylide ( AY 3) . Subsequently, nucleophilic addition of AY 3 to the double bond in IM 4 leads to form a betaine-like intermediate, namely, IN-Ta which named IN-Ta . Finally, trans -Az 6 is produced as a result of the nucleophilic attack of the negatively charged nitrogen atom on the carbon atom bearing DABCO in IN-Ta . Analysis of the relative Gibbs free energies shows that the ring closure step is the rate-determining step (RDS). By an investigation of the conceptual density functional theory, CDFT reactivity indices AY 3 and IM 4 are classified as a strong nucleophilic molecular system and as a strong electrophilic molecular system, respectively, which implies that the addition step of AY 3 to IM 4 has a high polar character. An analysis of the calculated electrophilic and nucleophilic Parr functions at the reactive sites of reagents clarifies the regioselectivity observed experimentally within the C1–C2 bond creation process. 相似文献
953.
Mediterranean Journal of Mathematics - This work is concerned with the existence and uniqueness of positive solutions to a nonlinear boundary value problem with fractional q-derivative:... 相似文献
954.
Seyed Abolfazl Hosseini‐Yazdi Ali Akbar Khandar Hashem Azizi Amir Reza Aref 《无机化学与普通化学杂志》2008,634(11):1943-1949
The 18‐membered mixed‐donor macrocycle 6,7,8,9,10,11,12,13,20,21‐decahydro‐5H, 19H‐dibenzo[b,m][1,15,5,8,11]dioxatriazacyclooctadecin‐20‐ol ( L ), which contains N3O3 donor set, was synthesized. Also two nickel(II) complexes of L have been synthesized and characterized by X‐ray crystallography, FT‐IR, UV‐Vis absorption spectroscopy and elemental analysis. The structure of complexes shows an unexpected anion dependence. Reaction of Ni(ClO4)2·6H2O with L afforded [Ni L ](ClO4)2·CH2Cl2 complex in which L uses all donor atoms and acts as a hexadentate ligand so forming a mononuclear nickel(II) complex in distorted octahedral geometry. Contrasting with this, when NiCl2·6H20 is used, the product complex [{Ni L Cl}2(μ‐Cl)2] is dimeric and consists of two Ni L Cl units bridged by two chloride ions. The coordination geometry of each nickel atom is a distorted octahedral. In this complex L is exo‐coordinated via only three nitrogen atoms to a nickel ion, which is bound to two cis bridging chloride and one non‐bridging chloride too. Also complexing properties of L towards Ni(ClO4)2·6H2O and NiCl2·6H20 have been determined by UV‐Vis titration in methanol. The computer treatment of the data confirmed the 1:1 metal to ligand stoichiometry for two complexes in solution and gave reliable values for corresponding stability constants (logK = 3.00 ± 0.02 with Ni(ClO4)2·6H2O and logK = 3.29 ± 0.06 with NiCl2·6H20). 相似文献
955.
L Lysineisanessentialaminoacidusedasafeedadditiveinanybalancedpoultrydiets ,anditisproducedbyamicrobial processthatutilizesaCorynebacterium glutamicumstrain .CommonlyL lysineisrecoveredfromculturebrothusingcationicexchange[1- 3] .Thebatchandfixed bedad so… 相似文献
956.
Mehdi Ghandi Seyed Jamal Tabatabaei Rezaei Ahmad Yari Abuzar Taheri 《Tetrahedron letters》2008,49(41):5899-5901
Numerous derivatives of spiropyrrolidines and spiropyrrolizines containing cyano groups were successfully synthesized via condensation of sarcosine and proline Schiff bases of several aromatic aldehydes with the Knöevenagel adduct of 9-fluorenone-malononitrile prepared through a modified procedure. Assignment of the molecular structure was carried out by single crystal X-ray diffraction, as well as by HMBC and ROSEY spectroscopy. 相似文献
957.
Ebrahim Hashemi 《Journal of Pure and Applied Algebra》2007,211(2):374-382
For a monoid M, we introduce M-quasi-Armendariz rings which are a generalization of quasi-Armendariz rings, and investigate their properties. The M-quasi-Armendariz condition is a Morita invariant property. The class of M-quasi-Armendariz rings is closed under some kinds of upper triangular matrix rings. Every semiprime ring is M-quasi-Armendariz for any unique product monoid and any strictly totally ordered monoid M. Moreover, we study the relationship between the quasi-Baer property of a ring R and those of the monoid ring R[M]. Every quasi-Baer ring is M-quasi-Armendariz for any unique product monoid and any strictly totally ordered monoid M. 相似文献
958.
Ezat Hamidi-Asl Jahan Bakhsh Raoof Reza Ojani Seyed Mahdi Golabi Mohammad Saeid Hejazi 《Journal of the Iranian Chemical Society》2013,10(6):1075-1083
In this paper, we report a new PNA biosensor for electrochemical detection of point mutation or single nucleotide polymorphism (SNP) in p53 gene corresponding oligonucleotide based on PNA/ds-DNA triplex formation following hybridization of PNA probe with double-stranded DNA (ds-DNA) sample without denaturing the ds-DNA into single-stranded DNA (ss-DNA). As p53 gene is mutated in many human tumors, this research is useful for cancer therapy and genomic study. In this approach, methylene blue (MB) is used for electrochemical signal generation and the interaction between MB and oligonucleotides is studied by differential pulse voltammety (DPV). Probe-modified electrode is prepared by self-assembled monolayer (SAM) formation of thiolated PNA molecules on the surface of Au electrode. A significant increase in the reduction signal of MB following hybridization of the probe with the complementary double-stranded oligonucleotide (ds-oligonucleotide) confirms the function of the biosensor. The selectivity of the PNA sensor is investigated by non-complementary ds-oligonucleotides and the results support the ability of the sensor to detect single-base mismatch directly on ds-oligonucleotide. The influence of probe and ds-DNA concentrations on the effective discrimination against complementary sequence and point mutation is studied and the concentration of 10?6 M is selected as appropriate concentration. Diagnostic performance of the biosensor is described and the detection limit is found to be 4.15 × 10?12 M. 相似文献
959.
Seyed Ebrahim Hashemi Mahmood Payehghadr Zarrin Es'haghi Hadi Kargar 《International journal of environmental analytical chemistry》2013,93(12):1148-1163
ABSTRACTIn this approach, a new carbon paste electrode modified with N,N′-bis(5-bromo-2-hydroxybenzylidene)-2,2-dimethylpropane-1,3-diamine Schiff base ligand (L) was synthesised for selective and effective determination of Hg2+ ions in aqueous environmental samples using cyclic and square wave anodic stripping voltammetric methods. First, the selective detection of mercury ion was confirmed by evaluating the stability constants of metal complexes formed between the Schiff base ligand (L) and some desired cations by conductometric measurements. Afterwards, by preparing an effective carbon paste electrode modified with L, the experimental and instrumental parameters affecting the performance of modified electrode were investigated. Square wave anodic stripping voltammograms were obtained after applying an accumulation potential ?0.5 V and accumulation time 150 s in Britton–Robinson buffer solution at pH 2.0. The optimal square wave parameters found are pulse amplitude 75 mV, frequency 50 Hz and step potential 6 mV. The procedure exhibited linear range from 0.4 to 120 μg L?1 Hg2+ with a limit of detection of 0.042 μg L?1. The proposed electrode was proved to be highly selective in the presence of various cations and anions and was successfully used for determination of mercury in tobacco and several water samples. 相似文献
960.
Ahmad Shaabani Ebrahim Soleimani 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):2475-2482
The protonation of a highly reactive 1,4-dipole generated in the reaction between pyridine or isoquinoline and dialkyl acetylenedicarboxylates by the acidic C-H group of (ethoxycarbonylmethyl) triphenylphosphonium bromide leads to a vinyl pyridinium cation derivatives, which undergo a carbon-centered Michael type addition with the conjugate base of the CH-acid to produce highly functionalized stable 1,4-diionic nitrogen betaines. 相似文献