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291.
V. I. Burkov E. P. Peredereĭ E. V. Fedotov B. V. Mill’ Yu. V. Pisarevskiĭ 《Crystallography Reports》2008,53(5):843-846
The absorption and circular dichroism spectra of langasite family crystals are studied. Wide bands in the range of 285–500 nm that are related to the structure lattice defects are found. For all the crystals, these bands are in approximately the same spectral region, have identical structures, and can be attributed to one type of defects formed by cation vacancies and excess oxygen atoms in the optically active positions. 相似文献
292.
293.
294.
Titanium tetrachloride promoted reaction of silyl ketene acetals with epoxides, followed by acidic work-up, affords butanolides in moderate/good yields. With epihalohydrins the reaction is regioselective and occurs at the less substituted end of the epoxide; the γ-haloalkyl-γ-butanolides thus obtained can be further transformed into various products. 相似文献
295.
The problem of homoaromaticity in mono-, di- and polyfluorinated- homotropylium cations is addressed by the B3LYP/6-311++G** DFT method. The energetic, structural and magnetic criteria are used for this purpose. They convincingly show that the ground state equilibrium species are aromatic, or in other words that the homoaromaticity is preserved by the (poly)fluorination. In contrast, a considerable decrease in the aromatic stabilization is observed in the transition structures (TS). According to the NICS(0) index, they vary form strongly antiaromatic, via weakly and non-aromatic to slightly aromatic transition states. However, the hierarchy of the aromaticity in fluorinated homotropylium ions predicted by NICS(0) is completely unrelated to that obtained by using the energy criterion assuming a kinetic definition of aromaticity. On the other hand the latter is closely related to geometric parameters of the equilibrium and transition structures. 相似文献
296.
Ryohei Hanayama Kenichi Hibino Shin’ichi Warisawa Mamoru Mitsuishi 《Optical Review》2004,11(5):337-343
Wavelength scanned interferometry allows the simultaneous measurement of top surface shape and optical thickness variation of a transparent object consisting of several parallel surfaces. Interference signals from these surfaces can be separated in frequency space, and their phases are detected by discrete Fourier analysis. However, these signal frequencies are shifted from the detection frequency by the refractive index dispersion of the object and a nonlinearity of the wavelength scanning. The Fourier analysis is sensitive to the detuning of the signal frequency and suffers from the multiple-beam interference noise. Conventional error-compensating algorithms cannot be applied to an object consisting of more than three reflecting surfaces. We derive a new 2N-1 sample error-compensating algorithm, which allows the phase detection of any order of harmonic frequency among the interference signals. The new algorithm suppresses the effect of signal frequency detuning as well as the multiple-beam interference noise and can be applied to the measurement of complex objects consisting of more than three reflecting surfaces. 相似文献
297.
Electric and spatial characteristics of a pulse-periodic microsecond barrier discharge are investigated in different geometries—triangular
prism, plate, and corrugated electrode—that are in contact with a dielectric plate and form a dihedral angle with it. It is
established that, in the space of the dihedral angle, the regions of discharge represent alternating cylindrical layers with
the axes lying on the contact line. The first conducting layer is formed at some distance from the contact edge of the electrode.
The number of layers and their localization are determined by the angle formed between an electrode and the dielectric plate.
A physical model explaining the main features of the structure formation is proposed. 相似文献
298.
A mathematical model is constructed of a nonautonomous dynamic system containing a nonlinear capacitance and possessing a
four-dimensional phase space. A numerical investigation is performed of branching processes and phenomena accompanying variations
in the frequency and amplitude of an external force. The existence of complex dynamic processes that are a combination of
a nonlinear force resonance and a parametric resonance is demonstrated. It is found that both a strange chaotic and a strange
nonchaotic attractor exist in the phase space. It is shown that, in the case of a single-frequency external force, the latter
attractor exhibits the property of roughness. The results of numerical calculations are confirmed by the results of laboratory
experiments. 相似文献
299.
300.
The electrodynamic properties of the interface between two periodic dielectric superlattices are studied. It is shown that
the interface may serve as a guide for an electromagnetic wave whose field decays exponentially on both sides of the plane
of the interface. The field and power flux distributions, as well as the frequency dependence of the field penetration depth,
are studied. 相似文献