Estimating rate constants in a convection-diffusion system with a boundary reaction

While performing biomolecular interaction analysis (BIA), scientistsoften use surface plasmon resonance (SPR) to measure rate constantsof the associated reactions. A mathematical model of a BIAcore^TM,a common SPR device, consists of a convection-diffusion equationin a channel with a reacting surface at the channel ceiling.Asymptotic and singular perturbation techniques are used toanalyse the concentration of the reacting species in two cases:when the reaction occurs much more slowly than diffusion, andwhen the reaction occurs on the same time-scale as diffusion.Linear and nonlinear integral equations result from the analysis;explicit and asymptotic solutions are constructed for physicallyrealizable cases. These expressions provide a direct way toestimate the rate constants from raw data.     

基于纯方位的浅海距离特征量解算分析

目标辐射噪声的LOFAR图中的干涉条纹包含了目标的运动参数和环境信息。当LOFAR图中的干涉条纹模糊或缺失时,其中的目标距离信息将无法提取。对于匀速直线运动的声源目标,仅利用方位信息,通过构造距离特征量和目标方位的关系模型,给出了一种浅海估计距离特征量的补充方法。浅海数值仿真和实验验证表明了该方法的可行性和有效性。     

蒙药新-Ⅱ中微量硒的测定

采用硒 -硫氰酸钾 -罗丹明 B-明胶 - OP体系分光光度法测定蒙药新 - 中微量硒。其含量为 6 .6—7.3μg· g-1 ,回收率为 94 %— 95 %。     

光声喇曼光谱的理论分析

对光声喇曼光谱(PARS)作了系统的理论分析,分别导出固体和液体介质中的光声喇曼光谱的信号表达式,并进行了数值估算。 关键词：     

Solvent and concentration effects on the properties of electrospun poly(ethylene terephthalate) nanofiber mats

This study describes the preparation and characterization of nanofibrous mats obtained by electrospinning poly(ethylene terephthalate) (PET) solutions in trifluoroacetic acid/dichloromethane (TFA/DCM). Special attention was paid to the effect of polymer concentration and solvent properties on the morphology, structure, and mechanical and thermal properties of the electrospun nonwovens. The results show that the spinnable concentration of PET solution in TFA/DCM solvents is above 10 wt %. Mats have nanofibrous morphology with fibers having an average diameter in the range of 200–700 nm (depending on polymer concentration and solvent composition) and an interconnected pore structure. Higher solution concentration favors the formation of uniform fibers without beads and with higher diameter. Morphology and fiber assembly changed with the solvent properties. Solvent mixtures rich in TFA, i.e., those with higher dielectric constant and lower surface tension, originated fibers with small diameter. However, due to the lower volatility, those solvent mixtures also produced more branched and crosslinking fibers, with less morphologic uniformity. Mechanical properties (Young's modulus, ultimate strength, and elongation at break) and thermal properties (glass transition, crystallization, and melting) have been studied for the PET electrospun nanomats and compared with those of the original polymer. Solvent effect on fiber crystallinity was not significant, but a complex effect was observed on the mechanical properties of the electrospun mats, as a consequence of the different structural organization of the fibers within the mat network. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 460–471, 2008     

龙爪芦荟和库拉索芦荟中微量锗的测定与红外光谱区别

采用吸光光度法对龙爪芦荟和库拉索芦荟中的微量锗进行了测定,并探讨了两种芦荟的红外光谱的区别。结果表明,龙爪芦荟中含锗量在26.1～28.6μg·g-1,回收率为91.6%～97 5%。库拉索芦荟中含锗量在16.8～20.0μg·g-1,回收率为87.1%～94.5%。两种芦荟的FT IR光谱图在2100cm-1处有明显差异,由此可区别两种芦荟。     

QuEChERS-液相色谱-串联质谱法测定植物性食品中30种氨基甲酸酯类农药残留

基于欧洲标准化委员会标准方法(EN 15662)对食品基质的分类,选择6种代表性植物性食品作为基质,系统优化了QuEChERS样品前处理方法;在此基础上,建立了30种氨基甲酸酯类农药的液相色谱-串联质谱分析方法。实验结果表明,除涕灭威砜的线性范围为2~100 μg/kg,其他29种氨基甲酸酯类农药的线性范围均为1~100 μg/kg;6种样品基质在3个添加水平(5、20、100 μg/kg)下的回收率为56.13%~127.6%,相对标准偏差为0.47%~16%;以信噪比(S/N)≥10计,30种农药的定量限(LOQ)为0.041~1.9 μg/kg。本文方法灵敏、有效,适用于植物性食品基质中30种氨基甲酸酯类农药残留的测定。     

On Mixed Pressure-Velocity Regularity Criteria to the Navier-stokes Equations in Lorentz Spaces,Part Ⅱ:The Non-slip Boundary Value Problem

This paper is a continuation of the authors recent work [Beir?o da Veiga, H.and Yang, J., On mixed pressure-velocity regularity criteria to the Navier-Stokes equations in Lorentz spaces, Chin. Ann. Math., 42(1), 2021, 1–16], in which mixed pressure-velocity criteria in Lorentz spaces for Leray-Hopf weak solutions of the three-dimensional NavierStokes equations, in the whole space R~3 and in the periodic torus T~3, are established. The purpose of the present work is to extend the result of mentio...     

Onset of superfluidity far from equilibrium: dynamical effects on the correlation length

Nonlinear heat conduction has recently been measured near the superfluid transition in pure ⁴He at very low heat flux Q. Since both dynamic effects and gravity limit the divergence of the superfluid correlation length near the transition at low-Q, these measurements must be repeated in the microgravity environment in order to observe the dynamic effects in isolation. Comparison of the microgravity data to similar data obtained on Earth will provide experimental insight into the effect of gravity on this nonlinear conduction region at low heat flux where theoretical predictions are lacking. While some measurement advantages exist in the microgravity laboratory, it is the study of the direct effect of gravity on the nonlinear conduction measurements that motivate the microgravity need.     

浅海环境中矢量水听器角度谱特性

为探明远场舰船噪声和近场平台噪声声能流相互作用的机制对矢量水听器角度谱特性的影响,基于简正波矢量场理论,构建舰船平台噪声声场模型,获得与海上实验结果相符的声能流角度谱特性,声能流方向均随频率变化。对远场舰船噪声声能流和近场平台噪声声能流相互作用进行仿真,两者声能流强度的此消彼长使角度谱出现4种条纹,与海上实验获得的角度谱特性一致,导致目标方位估计出现误差,且不同频带上的结果不一致。说明两个声能流相互作用时,影响合成能流角度谱特性的主要因素是两者的声压级之差,为浅海中同时存在多个声源时的目标方位估计提供参考。