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71.
Depigmenting activity and low cytotoxicity of alkoxy benzoates or alkoxy cinnamte in cultured melanocytes 总被引:2,自引:0,他引:2
To obtain effective and safe topical depigmenting agents, we synthesized hydroxybenzoates, alkoxybenzoates, and 3,4,5-trimethoxycinnamate containing a thymol moiety and screened then for high-level inhibitory activity against melanin synthesis in cultured melanocytes. Eight compounds were tested for their depigmenting effect and cytotoxicity using a murine melanocyte cell line. We found that 3,4,5-trialkoxybenzoates and 3,4,5-trimethoxycinnamate, synthesized by conjugating 3,4,5-trialkoxybenzoic acids and 3,4,5-trimethoxycinnmic acid with thymol, showed a potent depigmenting effect and low cytotoxicity. Compound 4h, 5-methyl-2-(methylethyl)phenyl (2E)-3-(3,4,5-trimethoxyphenyl)prop-2-enoate, showed the most potent depigmenting effect (IC50=10 microM) with low cytotoxicity (IC50=200 microM). 相似文献
72.
Yoshihisa Kurasawa Ho Sik Kim Keiko Yonekura Atsushi Takada Yoshihisa Okamoto 《Journal of heterocyclic chemistry》1989,26(3):857-859
3-(Pyrazolylhydrazonomethyl)-2-oxo-1, 2-dihydroquinoxalines were synthesized, and their tautomer ratios between hydrazone imine and diazenyl enamine forms were specified by pmr spectral data. 相似文献
73.
Mathematical Notes - The Boros–Moll polynomials $$P_m(a)$$ arise in the evaluation of a quartic integral. In the past few years, there has been some remarkable research on the properties of... 相似文献
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Jong-Shi Pang 《Mathematical Programming》1993,58(1-3):149-160
This paper is concerned with two well-known families of iterative methods for solving the linear and nonlinear complementarity problems. For the linear complementarity problem, we consider the class of matrix splitting methods and establish, under a finiteness assumption on the number of solutions, a necessary and sufficient condition for the convergence of the sequence of iterates produced. A rate of convergence result for this class of methods is also derived under a stability assumption on the limit solution. For the nonlinear complementarity problem, we establish the convergence of the Newton method under the assumption of a pseudo-regular solution which generalizes Robinson's concept of a strongly regular solution. In both instances, the convergence proofs rely on a common sensitivity result of the linear complementarity problem under perturbation.This work was based on research supported by the National Science Foundation under grant ECS-8717968. 相似文献
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The reactions of α-trifluoromethylated α-arylacetates 1 with 3 equiv of hydrazine, methylhydrazine or benzylhydrazine in 1,4-dioxane at reflux for 24 h afforded the corresponding 5-fluoropyrazolin-3-one derivatives 3a-m in high yields. Similarly, treatment of 1 with 3 equiv of PhNLiNH2 in THF at −78 °C, followed by warming to room temperature, resulted in the formation of 3n-s in high yields. 相似文献
79.
Styrene was polymerized in the presence of benzoyl peroxide (BPO) and 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) to yield polystyrene-TEMPO (PS-TEMPO) macroinitiator. The PS-TEMPO macroinitiator with different molecular weight was reacted with 4-vinyl pyridine (4-VP) to synthesize polystyrene-block-poly(4-vinyl pyridine) (PS-b-PVP), which was then quaternized with n-octyl iodide. Antibacterial activity of the quaternized copolymers was assessed against a gram negative bacterium (Pseudomonas aeruginosa) and a gram positive one (Staphylococcus aureus) by using the shake flask test method, and the results were compared with those of poly(styrene-random-4-vinyl pyridine) (P(ST-r--VP)). The quaternized copolymers inhibited greatly the growth of the bacteria, and PS-b-PVP was more active than P(ST-r-VP), which was ascribed to the fact that the content of quaternized 4-VP units on the surface of the particles of the former copolymer was higher than that corresponding to the latter one. 相似文献
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