全文获取类型
收费全文 | 766篇 |
免费 | 23篇 |
国内免费 | 6篇 |
专业分类
化学 | 430篇 |
晶体学 | 2篇 |
力学 | 19篇 |
数学 | 86篇 |
物理学 | 258篇 |
出版年
2023年 | 10篇 |
2022年 | 15篇 |
2021年 | 7篇 |
2020年 | 10篇 |
2019年 | 11篇 |
2018年 | 12篇 |
2017年 | 9篇 |
2016年 | 27篇 |
2015年 | 16篇 |
2014年 | 25篇 |
2013年 | 39篇 |
2012年 | 58篇 |
2011年 | 44篇 |
2010年 | 30篇 |
2009年 | 24篇 |
2008年 | 47篇 |
2007年 | 40篇 |
2006年 | 30篇 |
2005年 | 32篇 |
2004年 | 16篇 |
2003年 | 16篇 |
2002年 | 17篇 |
2001年 | 7篇 |
2000年 | 18篇 |
1999年 | 12篇 |
1998年 | 9篇 |
1997年 | 11篇 |
1996年 | 12篇 |
1995年 | 12篇 |
1994年 | 11篇 |
1993年 | 10篇 |
1992年 | 8篇 |
1991年 | 9篇 |
1989年 | 5篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1986年 | 15篇 |
1985年 | 9篇 |
1984年 | 12篇 |
1983年 | 8篇 |
1982年 | 7篇 |
1981年 | 12篇 |
1980年 | 12篇 |
1978年 | 6篇 |
1977年 | 7篇 |
1976年 | 6篇 |
1975年 | 4篇 |
1974年 | 3篇 |
1971年 | 4篇 |
1970年 | 3篇 |
排序方式: 共有795条查询结果,搜索用时 31 毫秒
51.
A p‐Hydroxyphenacyl–Benzothiazole–Chlorambucil Conjugate as a Real‐Time‐Monitoring Drug‐Delivery System Assisted by Excited‐State Intramolecular Proton Transfer 下载免费PDF全文
Shrabani Barman Sourav K. Mukhopadhyay Sandipan Biswas Surajit Nandi Moumita Gangopadhyay Satyahari Dey Anakuthil Anoop N. D. Pradeep Singh 《Angewandte Chemie (International ed. in English)》2016,55(13):4194-4198
Among the well‐known phototriggers, the p‐hydroxyphenacyl (pHP) group has consistently enabled the very fast, efficient, and high‐conversion release of active molecules. Despite this unique behavior, the pHP group has been ignored as a delivery agent, particularly in the area of theranostics, because of two major limitations: Its excitation wavelength is below 400 nm, and it is nonfluorescent. We have overcome these limitations by incorporating a 2‐(2′‐hydroxyphenyl)benzothiazole (HBT) appendage capable of rapid excited‐state intramolecular proton transfer (ESIPT). The ESIPT effect also provided two unique advantages: It assisted the deprotonation of the pHP group for faster release, and it was accompanied by a distinct fluorescence color change upon photorelease. In vitro studies showed that the p‐hydroxyphenacyl–benzothiazole–chlorambucil conjugate presents excellent properties, such as real‐time monitoring, photoregulated drug delivery, and biocompatibility. 相似文献
52.
AC Conduction and Time–Temperature Superposition Scaling in a Reduced Graphene Oxide–Zinc Sulfide Nanocomposite 下载免费PDF全文
Koushik Chakraborty Poulomi Das Sankalpita Chakrabarty Dr. Tanusri Pal Dr. Surajit Ghosh 《Chemphyschem》2016,17(10):1518-1523
We report, herein, the results of an in depth study and concomitant analysis of the AC conduction [σ′(ω): f=20 Hz to 2 MHz] mechanism in a reduced graphene oxide–zinc sulfide (RGO–ZnS) composite. The magnitude of the real part of the complex impedance decreases with increase in both frequency and temperature, whereas the imaginary part shows an asymptotic maximum that shifts to higher frequencies with increasing temperature. On the other hand, the conductivity isotherm reveals a frequency‐independent conductivity at lower frequencies subsequent to a dispersive conductivity at higher frequencies, which follows a power law [σ′(ω)∝ωs] within a temperature range of 297 to 393 K. Temperature‐independent frequency exponent ′s′ indicates the occurrence of phonon‐assisted simple quantum tunnelling of electrons between the defects present in RGO. Finally, this sample follows the “time–temperature superposition principle”, as confirmed from the universal scaling of conductivity isotherms. These outcomes not only pave the way for increasing our elemental understanding of the transport mechanism in the RGO system, but will also motivate the investigation of the transport mechanism in other order–disorder systems. 相似文献
53.
Synthesis of five-, six-, seven-, eight-, and nine-membered cyclic α-hydrazino acids from a common starting material ‘diethylmalonate’ with 26, 16, 34, 13.5, and 13.33% overall yields is described. Sequential allylation or homoallylation and electrophilic amination followed by cyclization gave the desired rings. The methyl esters of eight- and nine-membered rings were synthesized by RCM and the corresponding free acids were generated after hydrolysis in the presence of 1 M BBr3 solution in DCM. 相似文献
54.
55.
A Kerr metric describing a rotating black hole is obtained on the three brane in a five-dimensional Randall-Sundrum brane
world by considering a rotating five-dimensional black string in the bulk. We examine the causal structure of this space-time
through the geodesic equations. 相似文献
56.
Anindya Datta Amitava Raychaudhuri Sreerup Raychaudhuri Surajit Chakrabarti 《Zeitschrift fur Physik C Particles and Fields》1996,72(3):449-460
Many extensions of the Standard Model includeSU(2) L ×U(1) Y singlet higgs bosons,h 0, and also vector-like fermions which couple to it. The production and detection possibilities of such singlet neutral scalars at hadron colliders are considered for different scenarios of vectorlike fermions. We find that for some values of masses and couplings, detection at the CERN large hadron collider (LHC) appears to be a distinct possibility, while at the Fermilab Tevatron upgrade theh 0 might be observed only in very favourable circumstances. 相似文献
57.
Raj K. Sehgal Sisir K. Sengupta R. Karl Dieter 《Journal of heterocyclic chemistry》1985,22(3):665-667
A single step synthesis of 2-deaminoactinomycin D ( 3a ) and 2-deamino-2-nitroactinomycin D ( 2a ) arising from actinomycin D ( 1a, AMD ) is reported. Structural confirmation was made by nmr, ir and chemical conversion to known materials. 相似文献
58.
Kalyan Kali Sengupta Biswanath Basu Shipra Sengupta Sanghamitra Nandi 《Polyhedron》1983,2(10):983-986
Hypophosphite ion is oxidised by Au(III) in aqueous hydrochloric acid to give phosphorus acid and Au(I). The kinetics of the reaction has been studied spectrophotometrically in the UV region at different temperatures. The oxidation of hypophosphorous acid is first order with respect to both Au(III) and substrate. Hydrogen ion has no effect on the rate in acid media (0.15–1.0)M. The energy and entropy of activations are 128 ± 3.0kJ mol?1 and 135.8 ± 6.5 JK?1 mol?1 respectively. The results are interpreted in terms of the probable formation of intermediate Au(lI). 相似文献
59.
The trivalent ruthenium, rhodium and iridium complexes of dipicolinic acid and its mixed ligand complexes with several nitrogen, oxygen donor molecules, of types: Na[M(dipic)2]·2H2O and [M(dipic)(N-O)]·nH2O (where M = Ru(III), Rh(III) or Ir(III); dipicH2 = dipicolinic acid; NOH represents different nitrogen, oxygen donor molecules, viz., picolinic acid, nicotinic acid, isonicotinic acid, glycine, aminophenol, o- or p-aminobenzoic acid), have been synthesized and characterised on the basis of elemental analyses, electrical conductance, magnetic susceptibility measurements and spectral (electronic and infrared) data. The parent dipicolinic acid complexes are found to have a six-coordinate pseudooctahedral structure, whereas for mixed ligand complexes, a polymeric six-coordinate structure has been assigned. Various ligand field and nephelauxetic parameters have also been evaluated. 相似文献
60.
The object of the present paper is to investigate the radial motion of a solid spherical body, assumed to be homogeneous, isotropic and elastic, in presence of a magnetic field in the azimuthal direction. The body is assumed to be in a state of initial stress which is hydrostatic in nature. This theory of radial motion of a solid spherical body in a magnetic field has been utilised to find the small radial motion of a solid Earth assumed to be homogeneous isotropic elastic sphere in presence of a magnetic field in the azimuthal direction. Considering the effect of gravity and the initial stress produced by slow process of creep due to extra masses over the surface of the Earth, the fundamental equations of motion are derived which are non-linear in character and are solved. The times of a desired radial displacement are calculated in presence of a magnetic field only and in presence of the same magnetic field, initial stress and gravitational field, which are compared and exhibited numerically. 相似文献