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51.
Kawasaki N Araki M Nakamura T Tanada S 《Journal of colloid and interface science》2001,238(1):215-218
The solubilities of 4-nonylphenol in five kinds of hydroxypropyl-cyclodextrin (HP-CDs) solutions were investigated in order to evaluate them for soil remediation. The relative aqueous-phase concentration of 4-nonylphenol linearly increased with the increasing HP-CD concentration. The addition of HP-beta-CD (degree of substitution, D.S.=0.6) produced the largest change because the inner core of HP-beta-CD is the most hydrophobic. The solubility of 4-nonylphenol in the HP-CD solutions depended upon the cavity diameter and the degree of HP-CD substitution. Both ozone and activated carbon treatments have been using for removing organic compounds and foul odor compounds from tap water. As the inclusion complexes moved into the groundwater, the ozone degradation of the inclusion complexes was estimated. The 4-nonylphenol-HP-CD inclusion complexes were easily degraded by ozone. The degree of degradation increased with the increasing ozonization time. Weakly acidic compounds were produced from the 4-nonylphenol-HP-CD inclusion complexes by ozonization. HP-CDs could be used for the removal of 4-nonylphenol from soil. Copyright 2001 Academic Press. 相似文献
52.
Nucleophilic reactions of various enol silyl ethers with carbocation species generated from propargyl silyl ethers by the action of a Lewis acid have been developed. The present method is highly useful for the introduction of allenic or enyne functionalities into the alpha-position of substituted ketones. [reaction--see text] 相似文献
53.
Yasushi Joh Toshio Yoshihara Yahide Kotake Yoshikatsu Imai Seiki Kurihara 《Journal of polymer science. Part A, Polymer chemistry》1967,5(10):2503-2522
Some classes of organometallic catalysts what induce stereospecific polymerization of methacrylonitrile have been found. They include organolithium aluminum compounds of the type LiAlR4, Li[R3AlOAlR2], and Li[R3AlN(R)AlR2], organosodium aluminum compounds of the type NaAlR4, organolithium zinc compounds of the type LiZnR3 and Li2ZnR4, organomagnesium aluminum compounds of the type RMg[AlR4] and Mg[AlR4]2, and organomagnesium compounds containing an Mg? N bond, such as and their related compounds. One of the features of the polymerization with these catalysts was that the crystalline polymers were formed at moderately high temperatures. Total conversion, solubility index, and molecular weight of the polymer increased with increasing polymerization temperature, as observed in the case of polymerization with diethylmagnesium catalyst. Catalysts with an Mg? N bond were found to be highly effective for the stereospecific polymerization. The acetone-insoluble fractions of the polymers gave x-ray diagrams identical to the crystalline polymer produced with diethylmagnesium. This indicates that the acetone-insoluble crystalline polymers produced with these catalysts have an isotactic structure. The viscosity–molecular weight relationship for crystalline polymer was conveniently determined in Cl2CHCOOH at 30°C.; [η] = 2.27 × 10?4 M0.754. 相似文献
54.
New method for the synthesis of secondary carboxamides of type, R2NHCOR1, which utilizes 2-methyl-2-oxazoline as a carboxamide building block and various halides, R2X, has been developed. 相似文献
55.
Take-aki Mitsudo Yukiatsu Komiya Hideki Boku Yoshihisa Watanabe 《Reaction Kinetics and Catalysis Letters》1985,27(2):399-402
In the Fischer-Tropsch synthesis, potassium tetracarbonylhydridoferrate, KHFe (CO)4, supported on HY-zeolite or silica gel exhibited high selectivity to light olefins without following the Schulz-Flory distribution.
, KHFe(CO)4, HY —, — .相似文献
56.
57.
58.
Masaaki Nabika Seiki Kiuchi Tatsuya Miyatake Kiyoshi Fujisawa 《Journal of polymer science. Part A, Polymer chemistry》2009,47(21):5720-5727
Manganese(II) complex catalysts with hydrotris(pyrazolyl)borate ligands have been examined on their catalytic performance in ethylene polymerization and ethylene/1‐hexene copolymerization. The activities of [Mn(L6)(Cl)(NCMe)] ( 1 ) and [Mn(L10)(Cl)] ( 2 ) activated by Al(i‐Bu)3/[Ph3C][B(C6F5)4] for ethylene polymerization go up to 326 and 11 kg mol (cat?1) h?1, respectively, (L6? = hydrotris(3‐phenyl‐5‐methyl‐1‐pyrazolyl)borate anion, L10? = hydrotris(3‐adamantyl‐5‐isopropyl‐1‐pyrazolyl)borate anion). In particular, for ethylene/1‐hexene copolymerization, complex 1 gives high‐molecular‐weight poly(ethylene‐co‐1‐hexene)s with the highest Mw of 439,000 in manganese olefin polymerization catalyst systems. Moreover, the 1‐hexene incorporation by complex 1 seems more efficient than that by [Mn(L3)(Cl)] ( 4 ) (L3? = hydrotris(3‐tertiary butyl‐5‐isopropyl‐1‐pyrazolyl)borate anion). In this work, we demonstrated that the coordination geometry and coordination number are also important factors for ethylene polymerization reaction as well as steric hindrances and ligand frameworks in our manganese(II) catalysts. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5720–5727, 2009 相似文献
59.
It was recently demonstrated that the anisotropic phonon heat transport behavior is a good probe of the stripe formation in La(2-x)Sr(x)CuO(4) (LSCO) [Phys. Rev. B 67, 104503 (2003)]]. Using this probe, we examined an electron-doped cuprate Pr(1.3-x)La(0.7)Ce(x)CuO(4) (PLCCO) and found that essentially the same features as those in LSCO are observed. Moreover, the in-plane resistivity rho(ab) of lightly doped PLCCO shows metallic behavior (drho(ab)/dT>0) in the Néel ordered state with a mobility comparable to that in LSCO. It is discussed that these peculiar properties in common with LSCO signify the existence of stripes in electron-doped cuprates. 相似文献
60.
Lee JH Tanemura T Kikuchi K Nagashima T Hasegawa T Ohara S Sugimoto N 《Optics letters》2005,30(13):1698-1700
We introduce a new figure of merit (FOM) including the input pump power limit associated with stimulated Brillouin scattering (SBS) for evaluation of the Kerr nonlinearity efficiency of optical fibers. The new FOM is expressed as gammaL(eff)P(SBS) (gamma is a nonlinearity parameter, L(eff) is effective length, and P(SBS) is the SBS threshold), while the conventional FOM is given by gammaL(eff). Using the new FOM, we perform an efficiency comparison among four types of state-of-the-art nonlinear optical fiber: a Bi2O3-based nonlinear fiber, a silica-based holey fiber, a highly nonlinear dispersion-shifted fiber, and a conventional dispersion-shifted fiber. The Bi2O3-based nonlinear fiber is found to have the best Kerr nonlinearity efficiency owing to the superior nonlinear property of the Bi2O3 glass compared with that of the silica. 相似文献