Neutral pion production by weak neutral currents in neutrino and antineutrino reactions

A study is presented of single π^o production in neutrino and antineutrino interactions in Gargamelle filled with freon CF₃Br. Limits on the neutral to charged current cross-section ratios $\text{R}{}_{\mathrm{v}}\text{=σ(v}\text{N}\text{→v}\text{N}\text{′π}{}^{\mathrm{o}}\text{)/2 σ(v}\text{N}\text{→ μ}{}^{\mathrm{-}}\text{N}\text{′π}{}^{\mathrm{o}}\text{)}$ and $\text{R}{}_{\mathrm{<mtext>\nu </mtext>}}\text{= σ(}\text{ν}\text{N}\text{→}\text{ν}\text{N}\text{′π}{}^{\mathrm{o}}\text{)/2 σ(}\text{ν}\text{N}\text{→ ω}{}^{\mathrm{+}}\text{N}\text{′π}{}^{\mathrm{o}}\text{)}$ are found to be $\text{0.10 < R}{}_{\mathrm{\nu }}\text{< 0.20}\text{and}\text{0.26 < R}{}_{\mathrm{<mtext>\nu </mtext>}}\text{< 0.44}$ at 68% confidence level.     

Wavelength-dependent fragmentation in resonance-enhanced multiphoton ionization mass spectrometry

Wavelength-dependent effects in the resonance-enhanced multiphoton ionization/fragmentation mass spectra of p-chloroaniline and diphenyl ether are presented. For both molecules, the formation of low-energy fragments can be discriminated against in favor of higher-energy fragments by using ‘low’-energy radiation (290 nm region) for ionization/fragmentation. The same low-energy fragments become dominant when higher-energy radiation (266 nm) is used. This unique behavior is explained in terms of the narrow distribution of parent ion internal energies created through resonance-enhanced multiphoton ionization/fragmentation and the competing kinetic processes accessed by the parent ion as it absorbs each successive photon.     

Sequence-specific fragmentation of benzyloxycarbonyl dipeptides by resonance-enhanced multiphoton ionization

The mechanism of fragment ion formation in resonance-enhanced multiphoton ionization (REMPI) of benzyloxycarbonyl (CBZ)-derivitized dipeptides is presented. At 266 nm, the entire multiphoton process can be thought of as a two-part scheme where ionization occurs by resonant two-photon ionization followed by photodissociation of the created ions. When the energy of two photons exceeds the molecular ionization energy by a significant amount, REMPI has the advantage of producing both parent ions and low appearance energy fragments in large amounts. For CBZ dipeptides, resonant two-photon ionization at 266 nm produces parent ions as well as A type sequence ions with high abundance. On the other hand, a three-photon process (resonant two-photon ionization followed by parent ion photodissociation) forms sequence-related ions which also involve complex fragmentations of the CBZ chromophore. These results are compared to mass spectra obtained by other ionization/dissociation methods and to REMPI mass spectra of related compounds. Factors related to molecular structure elucidation based upon REMPI mass spectra are discussed. Enhanced isomer distinction is demonstrated for CBZ-leu-ala-OCH₃ and CBZ-ile-ala-OCH₃ based upon REMPI fragmentation.