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31.
N. Jiten Singh Adriana C. Olleta Anupriya Kumar Mina Park Hai-Bo Yi Indrajit Bandyopadhyay Han Myoung Lee P. Tarakeshwar Kwang S. Kim 《Theoretical chemistry accounts》2006,115(2-3):127-135
In earlier studies, the interactions of isolated ionic species with various solvents were investigated using ab initio calculations.
The ionic species investigated included cations (proton, hydronium, ammonium, and metal cations) and anions (single electron,
hydroxide, and halide anions). However in the present study, we investigate the interactions of these ionic species with the
solvent in the presence of other competing ionic species. We also elaborate on how the information obtained from these extensive
studies have been employed in designing and synthesizing various kinds of novel ionophores and receptors. 相似文献
32.
Seoung-Soo Lee Ho-In Park Chung-Hyung Joh Song-Ho Byeon 《Journal of solid state chemistry》2007,180(12):3529-3534
Three different synthetic methods, the liquid phase process in HCl solution, the solvothermal reaction, and the surfactant-assisted solvothermal reaction, were explored to selectively control the particle shape and to enhance the luminescence intensity of the PbFCl-type red-emitting oxychloride phosphors LnOCl:Eu (Ln=La and Gd). The solvothermal pressure facilitated the low-temperature crystallization of the rod-shape particles for both Ln=La and Gd. It is noted that LaOCl:Eu nanorods show highly porous particle surface and quite low photoemission intensity. In contrast, the solvothermal synthesis could highly enhance the red-emission of GdOCl:Eu with no porous surface so as to be comparable to that of commercial Y2O3:Eu phosphor. An addition of surfactant material during solvothermal reaction yielded a rhomboidal-shape phosphor particles with no porous surface for both Ln=La and Gd. Interestingly, the elimination of surface porosity by using a surfactant significantly increased the emission intensity of LaOCl:Eu. It is proposed that the application of solvothermal technique for the synthesis of the PbFCl-type oxychloride phosphors is very effective to selectively control the particle shape and consequently to enhance the photoemission intensity if we use an appropriate surfactant material. 相似文献
33.
We consider a SA-SA' critical point in the presence of a symmetry-breaking external magnetic (electric) field with a positive magnetic (dielectric) anisotropy or a dislocation layer. Via a renormalization group analysis of the model hamiltonian, we show that the upper critical dimensions below which mean-field theory breaks down is dc = 2·5. Thus the SA-SA' transition in three dimensions becomes mean-field like in the presence of a symmetry-breaking field. We estimate the reduced temperature region where we can expect to see the mean field SA-SA' critical point in the presence of a magnetic field or a dislocation layer. 相似文献
34.
Jin Kyu Park Dong Hun Lee Bok Ju Song Jae Buem Oh Hwan Kyu Kim 《Journal of polymer science. Part A, Polymer chemistry》2006,44(3):1326-1342
We have designed and synthesized novel perfluorinated polyimides with 3D controlled structure. At first, we successfully developed the new synthetic routes to diamines with pendant bulky perfluorinated aromatic units in a multi‐step synthetic procedure. Novel perfluorinated polyimides were prepared in a two‐step reaction in N‐methyl‐2‐pyrrolidinone (NMP) solution: The first step was for the synthesis of polyamic acids (PAAs) and the second reaction was for the imidization of PAA. The polymer yield was over 89% and the inherent viscosity of PAAs was in the range of 0.24–0.36 dL/g. The thin films were prepared by spin‐coating the PAA solution in NMP onto various substrates such as a Si wafer or a KBr pellet, dried at 80 °C and further cured at 230 °C. The resultant polyimides are thermally stable over 400 °C. The refractive index and birefringence of the resultant polyimides are 1.5858–1.6452 and 0.01–0.005, respectively. The refractive index of polyimide decreases with increasing the fluorine content. The copolymerization and the ether linkages into the backbone reduce the birefringence of polyimides. Surprisingly, the pendant ether linkage is not a crucial factor in reducing the polyimide birefringence. Their birefringence is comparatively very low, compared with that of previous polyimides. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1326–1342, 2006 相似文献
35.
Chae Kyu Kim Eun Seok Song Hyung Joo Kim Chiyoung Park Young Chul Kim Jai Kyeong Kim Jae Woong Yu Chulhee Kim 《Journal of polymer science. Part A, Polymer chemistry》2006,44(1):254-263
We have synthesized conjugated dendrimer with triazine peripheries, and their luminescence properties were investigated. The dendrimers consist of dendritic triazine wedges for electron transport, distyrylbenzene core as an emitting moiety, and t‐butyl peripheral groups for good processing properties. The dendrimers have LUMO values of about ?2.7 eV possibly because of the triazine moiety with high electron affinity. Photoluminescence study indicates that energy transfer occurs from the triazine wedges to the stilbene bridge, and finally to the core chromophore units due to a cascade decrease of bandgap from the peripheral wedge to core moiety. Therefore, the emission wavelength was determined by the structure of the core unit. The energy transfer efficiency of distyrylbenzene‐cored dendrimers was about 75 and 55% for Trz‐1GD‐DSB and Trz‐2GD‐DSB, respectively. A preliminary electroluminescence property also was investigated. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 254–263, 2006 相似文献
36.
In order to obtain the depth profile of a thin film, we investigated the emission characteristics of a voltage modulation glow discharge to optimize the modulation parameters (modulation voltage, offset voltage, and modulation frequency). In this study, a phase-sensitive detection method with a lock-in amplifier to the modulation technique led to a higher sensitivity and a larger signal-to-noise ratio in the emission analysis compared to the normal dc amplification method. Upon increasing the maximum voltage, the emission intensity of the Cu atomic line (CuI 239.34 nm) increased linearly at a modulation voltage of 400 V and an offset voltage of 300 V. On the other hand, the emission intensity was gradually reduced when a modulation frequency increased. It is advantageous for surface analysis that the voltage modulation technique gives a lower sputtering rate rather than the conventional dc discharge. 相似文献
37.
T.W. Lim S.H. Park D.Y. Yang H.J. Kong K.S. Lee 《Applied Physics A: Materials Science & Processing》2006,84(4):379-383
A nano-surfacing process (NSP) is proposed to directly fabricate three-dimensional (3D) concavo–convex-shaped microstructures such as micro-lens arrays using two-photon polymerization (TPP), a promising technique for fabricating arbitrary 3D highly functional micro-devices. In TPP, commonly utilized methods for fabricating complex 3D microstructures to date are based on a layer-by-layer accumulating technique employing two-dimensional sliced data derived from 3D computer-aided design data. As such, this approach requires much time and effort for precise fabrication. In this work, a novel single-layer exposure method is proposed in order to improve the fabricating efficiency for 3D concavo–convex-shaped microstructures. In the NSP, 3D microstructures are divided into 13 sub-regions horizontally with consideration of the heights. Those sub-regions are then expressed as 13 characteristic colors, after which a multi-voxel matrix (MVM) is composed with the characteristic colors. Voxels with various heights and diameters are generated to construct 3D structures using a MVM scanning method. Some 3D concavo–convex-shaped microstructures were fabricated to estimate the usefulness of the NSP, and the results show that it readily enables the fabrication of single-layered 3D microstructures. PACS 85.40.Hp; 81.16.Nd; 42.82.Cr 相似文献
38.
Kwangwon Park 《Talanta》2007,73(4):791-794
It is very challenging to decompose a plastic product for the purpose of analysis of hazardous elements contained. To circumvent such technical problem, it is imperative that an analyst employ a nondestructive analytical method free of any pretreatments. The analytical results of the concentrations of toxic metals such as Cd and Cr in polypropylene for seven samples at two different levels were obtained using the instrumental neutron activation analysis. This work was intended ultimately to establish certified reference materials (CRMs) of these metals in the polypropylene, traceable to the SI. The uncertainties associated with the analytical procedures were estimated in accordance with the ISO guideline. The results were subsequently validated by a comparison with those for CRM-680 and −681 of the Bureau Communautaire de Reference (BCR), which demonstrated acceptable agreement within their uncertainty ranges. 相似文献
39.
In this paper we prove the semialgebraic version of Palais' covering homotopy theorem, and use this to prove Bredon's covering mapping cylinder conjecture positively in the semialgebraic category. Bredon's conjecture was originally stated in the topological category, and a topological version of our semialgebraic proof of the conjecture answers the original topological conjecture for topological G-spaces over “simplicial” mapping cylinders. 相似文献