全文获取类型
收费全文 | 296篇 |
免费 | 3篇 |
专业分类
化学 | 264篇 |
数学 | 2篇 |
物理学 | 33篇 |
出版年
2021年 | 4篇 |
2020年 | 4篇 |
2019年 | 5篇 |
2018年 | 2篇 |
2017年 | 2篇 |
2016年 | 9篇 |
2015年 | 6篇 |
2014年 | 6篇 |
2013年 | 8篇 |
2012年 | 8篇 |
2011年 | 16篇 |
2010年 | 9篇 |
2009年 | 4篇 |
2008年 | 11篇 |
2007年 | 11篇 |
2006年 | 10篇 |
2005年 | 11篇 |
2004年 | 11篇 |
2003年 | 9篇 |
2002年 | 8篇 |
1999年 | 5篇 |
1997年 | 2篇 |
1996年 | 5篇 |
1995年 | 2篇 |
1994年 | 5篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 5篇 |
1990年 | 7篇 |
1989年 | 4篇 |
1988年 | 10篇 |
1987年 | 6篇 |
1986年 | 9篇 |
1985年 | 5篇 |
1984年 | 10篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 5篇 |
1980年 | 10篇 |
1979年 | 8篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 9篇 |
1975年 | 2篇 |
1974年 | 4篇 |
1973年 | 3篇 |
1971年 | 2篇 |
1969年 | 1篇 |
1966年 | 1篇 |
1964年 | 1篇 |
排序方式: 共有299条查询结果,搜索用时 218 毫秒
21.
Lucas Stiegler Ribeiro Layse do Prado Cordoba Tiago André Denck Colman Cristina Soltovsti de Oliveira Marina Morena Pereira Andrade Egon Schnitzler 《Journal of Thermal Analysis and Calorimetry》2014,117(2):935-942
When starch is incorporated into puddings, desserts, and other foods containing sugar as the main ingredient, it will have an effect on the gelatinisation temperature and pasting properties. Many studies have been undertaken to investigate the effect of several sugars in foods and starches, as well as their physicochemical and functional properties. These studies have verified the significant influence on these properties, which are dependent on the nature of sugar and of starch. In this study, pinhão starch was extracted in the laboratory and was added, stirring for 60 min, to solutions at 1 % of each of the following sugars: fructose, glucose, sucrose, and 0.5 % fructose and 0.5 % glucose. After this time, the slurry was filtered, washed, dried at 40 °C and kept in a desiccator over anhydrous calcium chloride until constant mass. The effects of each sugar on the surface of the pinhão starch granules were observed using the non-contact method of atomic force microscopy, whereby it was possible to verify a decrease in the average diameter and an increase in the average roughness. X-ray diffractometry made it possible to evaluate the degree of relative crystallinity, which was proportional to the roughness and inversely proportional to the gelatinisation enthalpy (ΔH), which was studied by differential scanning calorimetry. 相似文献
22.
A simple spray pyrolysis setup is used to grow multi-walled carbon nanotubes (MWCNTs), from a ferrocene solution in benzene
as precursor. The effects of process variables such as growth temperature, position of the aerosol generator and position
in the reactor where the sample was formed were investigated. These variables have a strong influence on the graphitization
degree, homogeneity, diameter and alignment of the nanotubes, as observed by TEM, SEM, XRD and Raman spectroscopy. Vertically
aligned MWCNT arrays with high density were obtained in large areas (10 × 10 mm2), with high yield (2.1 mg cm−2) and at a growth rate at 1.43 μm min−1, by a suitable choice of the experimental conditions. 相似文献
23.
Clemente-Juan JM Coronado E Gaita-Ariño A Giménez-Saiz C Chaboussant G Güdel HU Burriel R Mutka H 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(24):5701-5708
The ground-state properties of a Co3II moiety encapsulated in a polyoxometalate anion were investigated by combining measurements of specific heat, magnetic susceptibility, and low-temperature magnetization with a detailed inelastic neutron scattering (INS) study on a fully deuterated polycrystalline sample of Na12[Co3W(D2O)2(ZnW9O34)2].40D2O (Co3). The ferromagnetic Co3O14 cluster core consists of three octahedrally oxo-coordinated CoII ions. According to the single-ion anisotropy and spin-orbit coupling of the octahedral CoII ions, the appropriate exchange Hamiltonian to describe the ground-state properties of the Co3 spin cluster is anisotropic and is expressed as H = -2 sigma a = x,y,z (Ja12 S1a S2a + Ja23 S2a S3a), where Ja are the components of the exchange interactions between the CoII ions. To reproduce the INS data, different orientations of the two anisotropic J tensors must be considered, and the following conditions had to be introduced: Jx12 = Jy23, Jy12 = Jx23, Jz12 = Jz23. This result was correlated with the molecular symmetry of the complex. The following set of parameters was obtained: Jx12 = Jy23 = 1.37, Jy12 = Jx23 = 0.218, and Jz12 = Jz23 = 1.24 meV. This set also reproduces in a satisfactory manner the specific heat, susceptibility, and magnetization properties of Co3. 相似文献
24.
25.
26.
27.
Hachenberg J Streng C Süske E Vauth S Mayr SG Krebs HU Samwer K 《Physical review letters》2004,92(24):246102
The crossover in kinetic roughening of thin films from a particle-character-dominated regime to continuous growth behavior has been observed in this work. This has been accomplished by atomic force microscopy investigations of pulsed laser deposited amorphous organic films with thicknesses ranging from several nanometers to more than 4 microm. The early-stage random-deposition-like processes end once a closed layer is formed, which grows without saturation on the characteristic length scales. In addition, the influence of oblique film deposition has been examined and interpreted. 相似文献
28.
Berlinguette CP Dragulescu-Andrasi A Sieber A Galán-Mascarós JR Güdel HU Achim C Dunbar KR 《Journal of the American Chemical Society》2004,126(20):6222-6223
A charge-transfer-induced spin transition (CTIST) is observed in the discrete cyanide-bridged complex, {[Co(tmphen)2]3[Fe(CN)6]2}. Single-crystal X-ray diffraction, 57Fe M?ssbauer spectroscopy, and magnetic susceptibility were used collectively to describe the oxidation states of the Co and Fe ions in this cluster as a function of temperature. This pentanuclear complex represents the first example of a CTIST at the discrete molecular level. 相似文献
29.
30.