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排序方式: 共有153条查询结果,搜索用时 31 毫秒
21.
Amarendra Patra Alok K. Mitra Saroj Ghosh Amitava Ghosh A. K. Barua 《Magnetic resonance in chemistry : MRC》1981,15(4):399-400
Carbon-13 NMR signal assignment of a number of polyoxygenated triterpenes of the olean-12-ene and urs-12-ene series, carried out by considering the changes in chemical shift produced by the change of oxygenation pattern(s), and using methyl oleanolate as a model, are reported. 相似文献
22.
Saroj Kumar 《应用光谱学评论》2013,48(3):187-200
AbstractThis brief review focuses on the information that can be obtained for biomolecules, especially proteins, by using the technique infrared-induced difference spectroscopy. 相似文献
23.
JPC – Journal of Planar Chromatography – Modern TLC - The Inula genus has been used for the cure of pulmonary, heart diseases and also acts as a rejuvenator, immunomodulator in... 相似文献
24.
Saroj Kumar Pradhan Raghbir Chand Gupta Rajesh Kumar Goel 《Natural product research》2018,32(20):2476-2482
Siegesbeckia orientalis L. is an annual herb widely distributed throughout the world and has many medicinal properties. In Chinese traditional system, it is popularly known as Xi-Xian and used for its anti-inflammatory properties. In the present study, two cytotypes (diploid and tetraploid) have been investigated for their secondary metabolites. The different plant parts have been explored in terms of total phenolics, total flavonoids, DPPH radical scavenging acitivity and total antioxidant capacity. Out of different plant parts, leaves have the maximum amount of secondary metabolites and antioxidant potential. HPTLC technique has been applied to quantify six marker compounds in the two cytotypes. Tetraploid cytotype has been compared with diploid cytotype, which shows that tetraploid has the maximum amount of studied secondary metabolites with high antioxidant potential. 相似文献
25.
We report on the successful application of the recently introduced atmospheric pressure laser ionization (APLI) method as a novel tool for the analysis of crude oil and its components. Using Fourier transform ion cyclotron resonance mass spectrometry, unambiguous determination of key compounds in this complex matrix with unprecedented sensitivity is presented. 相似文献
26.
Dr. Anoop Kumar Kushwaha Sushri Soumya Jena Dr. Mihir Ranjan Sahoo Dr. Debashish Das Prof. Saroj Kumar Nayak 《Chemphyschem》2023,24(18):e202300032
High-voltage alkali metal-ion batteries (AMIBs) require a non-hazardous, low-cost, and highly stable electrolyte with a large operating potential and rapid ion conductivity. Here, we have reported a halogen-free high-voltage electrolyte based on SiB11(BO)12−. Because of the weak π-orbital interaction of −BO as well as the mixed covalent and ionic interaction between SiB11-cage and −BO ligand, SiB11(BO)12− has colossal stability. SiB11(BO)12− possesses extremely high vertical detachment energy (9.95 eV), anodic voltage limit (∼10.05 V), and electrochemical stability window (∼9.95 V). Furthermore, SiB11(BO)12− is thermodynamically stable at high temperatures, and its large size allows for faster cation movement. The alkali salts MSiB11(BO)12 (M=Li, Na, and K) are easily dissociated into ionic components. Electrolytes based on SiB11(BO)12− greatly outperform commercial electrolytes. In short, SiB11(BO)12−-based compound is demonstrated to be a high-voltage electrolyte for AMIBs. 相似文献
27.
Crude oil analysis has long been an inspiration for the development of analytical techniques. Especially mass spectrometry
has flourished as a result of the challenge these extremely complex problems offer. Here an overview of different analytical
methods is presented that shows different ways to analyze volatile and nonvolatile crude oil components. Focus has been placed
on the use of mass spectrometry and especially the new developments that have been introduced using the emerging technique
of Fourier transform ion cyclotron resonance mass spectrometry. These studies are examples of how far the development of analytical
methods has come for the task of studying such complex problems. 相似文献
28.
Kuno Schwrzer Saroj K. Rout Derya Bessinger Fabio Lima Cara E. Brocklehurst Konstantin Karaghiosoff Thomas Bein Paul Knochel 《Chemical science》2021,12(39):12993
We report the selective functionalization of the 1H-imidazo[1,2-b]pyrazole scaffold using a Br/Mg-exchange, as well as regioselective magnesiations and zincations with TMP-bases (TMP = 2,2,6,6-tetramethylpiperidyl), followed by trapping reactions with various electrophiles. In addition, we report a fragmentation of the pyrazole ring, giving access to push–pull dyes with a proaromatic (1,3-dihydro-2H-imidazol-2-ylidene)malononitrile core. These functionalization methods were used in the synthesis of an isostere of the indolyl drug pruvanserin. Comparative assays between the original drug and the isostere showed that a substitution of the indole ring with a 1H-imidazo[1,2-b]pyrazole results in a significantly improved solubility in aqueous media.A methodology for the selective functionalization of the 1H-imidazo[1,2-b]pyrazole scaffold has been developed and used in the synthesis of novel push–pull dyes and a non-classical isostere of the indolyl drug pruvanserin. 相似文献
29.
Wantana Klysubun Pinit Kidkhunthod Pongjakr Tarawarakarn Panidtha Sombunchoo Chanapa Kongmark Sukit Limpijumnong Saroj Rujirawat Rattikorn Yimnirun Gamolwan Tumcharern Kajornsak Faungnawakij 《Journal of synchrotron radiation》2017,24(3):707-716
The SUT‐NANOTEC‐SLRI beamline was constructed in 2012 as the flagship of the SUT‐NANOTEC‐SLRI Joint Research Facility for Synchrotron Utilization, co‐established by Suranaree University of Technology (SUT), National Nanotechnology Center (NANOTEC) and Synchrotron Light Research Institute (SLRI). It is an intermediate‐energy X‐ray absorption spectroscopy (XAS) beamline at SLRI. The beamline delivers an unfocused monochromatic X‐ray beam of tunable photon energy (1.25–10 keV). The maximum normal incident beam size is 13 mm (width) × 1 mm (height) with a photon flux of 3 × 108 to 2 × 1010 photons s?1 (100 mA)?1 varying across photon energies. Details of the beamline and XAS instrumentation are described. To demonstrate the beamline performance, K‐edge XANES spectra of MgO, Al2O3, S8, FeS, FeSO4, Cu, Cu2O and CuO, and EXAFS spectra of Cu and CuO are presented. 相似文献
30.
Vishnu Shanker Saroj L. Samal Gopal K. Pradhan Chandrabhas Narayana Ashok K. Ganguli 《Solid State Sciences》2009,11(2):562-569
Nanocrystalline NaNbO3 and NaTaO3 have been synthesized by the reverse micellar technique for the first time. The particle size of NaNbO3 was found to be 18 nm while that of NaTaO3 was found to be 40 nm (much smaller size than most of the earlier reports on NaTaO3). Rietveld refinement of X-ray diffraction data and Raman spectroscopy confirm that the nanoparticles of NaNbO3 and NaTaO3 have orthorhombically distorted structures with Pmc21 and Pbnm space groups, respectively. The dielectric constant at 25 °C of NaNbO3 and NaTaO3 was found to be 209 and 147 at 1 kHz, respectively. The antiferroelectric transition in NaNbO3 shifts to lower temperature (325 °C) in the nanocrystalline solid. 相似文献