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71.
The pion-nucleon scattering amplitudes with current algebra constraints involving “remainder terms” are calculated by saturating them with the N1(1236) contribution having off-mass shell effects and compared with experiments. 相似文献
72.
Bhaba R. Sarker Wilber E. Wilhelm Gary L. Hogg 《The Journal of the Operational Research Society》1994,45(9):1024-1039
This paper studies the assignment of M unique machines to M equally spaced locations along a linear material handling track with the objective of minimizing the cost of (jobs) backtracking (i.e. moving upstream). Because of the arrangement of machines and restrictions imposed by the sequence of operations for each job, some jobs may have to backtrack to complete required processing on different machines. This problem is formulated as a quadratic assignment problem. An optimal solution to a problem with large M is computationally intractable. The backtracking distance matrix in problems involving equally-spaced machine locations in one dimension is seen to possess some unique characteristics called amoebic properties. Ten amoebic properties have been identified and exploited to devise a heuristic and a lower bound on the optimal solution. Results which describe the performance of the heuristic and the lower bound are presented. 相似文献
73.
Several symmetrical steroidal oxalate dimers were synthesised from naturally occurring 3-hydroxysteroids, namely, estrone
(1), DHEA (3), pregnenolone (5), cholesterol (7), 5D-cholestane (9), and stigmasterol (11), using oxalyl chloride. Full spectroscopic data for all the new compounds are presented.
Published in Khimiya Prirodnykh Soedinenii, No. 5, pp. 442–444, September–October, 2006. 相似文献
74.
Yashodharan KumarasamyPhilip J Cox Marcel JasparsLutfun Nahar Satyajit D Sarker 《Tetrahedron》2003,59(34):6403-6407
Preparative HPLC purification of a methanol extract of the aerial parts of Glechoma hederaceae has yielded two unique alkaloids, hederacine A (1) and hederacine B (2). The structures of these compounds were established unequivocally by UV, IR, MS and a series of 1D and 2D NMR analyses. These alkaloids were inactive against any of the 11 bacterial species at test concentrations, but showed prominent toxicity in the brine shrimp lethality assay (LC50s=3.2, 14.0 and 2.7 μg/mL, respectively, for 1, 2 and the positive control, podophyllotoxin). 相似文献
75.
76.
Jia J Sarker M Steinmetz MG Shukla R Rathore R 《The Journal of organic chemistry》2008,73(22):8867-8879
Methacrylanilides, ArN(CH3)COC(CH2LG)=CH2, with allylic leaving groups (LG(-) = BocAla, PhCO2(-), PhCH2CO2(-), PhO(-)) undergo photochemical electrocyclic ring closure to produce a zwitterionic intermediate. Further reaction of the intermediate results in expulsion of the leaving group to give an alpha-methylene lactam as the major product. In addition, a lactam product that retains the leaving group is formed via a 1,5-H shift in the intermediate. Elimination of the leaving group is generally preferred, even for LG(-) = PhO(-), although in benzene as the solvent the lactam retaining the phenolate group becomes the sole photoproduct. The electrocyclic ring closure occurs in the singlet excited-state for the para-COPh-substituted anilide derivative and is not quenched by 0.15 M piperylene or 0.01 M sodium 2-naphthalenesulfonate (2-NPS) as triplet quenchers. Comparable concentrations of 2-NPS strongly quench the transient absorption of the triplet excited state observed at 450-700 nm according to laser flash photolysis experiments. In aqueous media, quantum yields for total products are insensitive to leaving group ability, and Phi(tot)(para-CO2CH3) = 0.04-0.06 at 310 nm and Phi(tot)(para-COPh) = 0.08-0.1 at 365 nm, for which Phi(isc) = 0.15. 相似文献
77.
One- and two-photon photochemistry and photophysics of poly(arylenevinylene)s containing a biphenyl moiety. 总被引:1,自引:0,他引:1
Veronika Strehmel Ananda M Sarker M Paul M Lahti Frank E Karasz Matthias Heydenreich Hendrik Wetzel Sophie Haebel Strehmel Bernd 《Chemphyschem》2005,6(2):267-276
Photochemical and photophysical properties were investigated for poly(arylenevinylene)s containing a flexible biphenyl "hinge" unit by applying one-photon (OP) and two-photon (TP) excitation to explore excited-state properties. The poly(arylenevinylene)s were poly[(2,5-dihexyloxy-p-phenylenevinylene)-alt-(4,4'-dihexyloxy-3,3'-biphenylenevinylene)] (1), poly[(2,5-dihexyloxy-p-phenylenevinylene)-alt-(2,2'-dihexyloxy-3,3'-biphenylenevinylene)] (2), and poly[(2,5-dihexyloxy-p-phenylenevinylene)-alt-(2,2'-biphenylenevinylene)] (3). Effective emission quantum yields and related photonic properties were evaluated on a realistic per-chromophore basis using effective conjugation lengths based on the Strickler-Berg relationship. Intramolecular photocyclization was deduced to occur in the one case where the biphenyl molecular connectivity permitted the reaction, based on matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF), heteronuclear multiple-quantum coherence (HMQC)-NMR, and gel-permeation chromatography (GPC) results. The various photoprocesses could be induced by either OP or TP excitation, though the first excited singlet state is the photoactive state. The higher excitation energy of the TP excited state favors indirect population of the S, state by electronic coupling between the TP and OP excited states [lambda(max)TPE (nm): 726; delta (GM): 1=229, 2=215, 3= 109). Photochemical processes occurring from the lowest OP excited state (S1) could therefore also be indirectly induced by TP excitation. 相似文献
78.
79.
Deepening our understanding of the characteristics and behaviors of population-based search algorithms remains an important ongoing challenge in Evolutionary Computation. To date however, most studies of Evolutionary Algorithms have only been able to take place within tightly restricted experimental conditions. For instance, many analytical methods can only be applied to canonical algorithmic forms or can only evaluate evolution over simple test functions. Analysis of EA behavior under more complex conditions is needed to broaden our understanding of this population-based search process. This paper presents an approach to analyzing EA behavior that can be applied to a diverse range of algorithm designs and environmental conditions. The approach is based on evaluating an individual’s impact on population dynamics using metrics derived from genealogical graphs. From experiments conducted over a broad range of conditions, some important conclusions are drawn in this study. First, it is determined that very few individuals in an EA population have a significant influence on future population dynamics with the impact size fitting a power law distribution. The power law distribution indicates there is a non-negligible probability that single individuals will dominate the entire population, irrespective of population size. Two EA design features are however found to cause strong changes to this aspect of EA behavior: (1) the population topology and (2) the introduction of completely new individuals. If the EA population topology has a long path length or if new (i.e. historically uncoupled) individuals are continually inserted into the population, then power law deviations are observed for large impact sizes. It is concluded that such EA designs can not be dominated by a small number of individuals and hence should theoretically be capable of exhibiting higher degrees of parallel search behavior. 相似文献
80.
Three new symmetrical pregnenolone oxyminyl oxalate dimers (8–10) were synthesized from the corresponding pregnenolone oximes (3, 5, and 7) at room temperature. All dimers were characterised by spectroscopic means, notably HRFABMS and comprehensive NMR spectroscopic
data analyses.
Published in Khimiya Prirodnykh Soedinenii, No. 3, pp. 250–252, May–June, 2008. 相似文献