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171.
De Napoli M Nardis S Paolesse R Vicente MG Lauceri R Purrello R 《Journal of the American Chemical Society》2004,126(19):5934-5935
In aqueous solution meso-tetrakis(4-phosphonatophenyl)porphyrin shows self-aggregation processes controlled by the "sergeant-soldier rule". After partial protonation of the external phosphonic groups, it is possible (i) to further protonate the inner nitrogen atoms of the molecules or (ii) to allow, over time, the system to aggregate. Therefore, the two procedure lead to a different system evolution, producing species with different chemico-physical properties. 相似文献
172.
Two-dimensional protein map of human vastus lateralis muscle 总被引:4,自引:0,他引:4
Protein samples of human vastus lateralis muscle were analyzed by two-dimensional gel electrophoresis, using immobilized pH gradients encompassing several pH regions in the first dimension and sodium dodecyl sulfate-polyacrylamide gel electrophoresis in the second dimension. More than 500 protein spots on each gel were detected by silver staining, of which 150 were excised, digested in-gel with trypsin and characterized by matrix assisted laser desorptioin/ionization-mass spectrometry and tandem electrospray mass spectrometry. Using these techniques, 124 spots including contractile proteins and metabolic enzymes were identified. This database should provide a valuable resource for the definition of the functional properties of muscle fibres and for assessment of the influence of e.g., hypoxia, ischaemia and ageing on protein level. 相似文献
173.
Direct detection of ion pairs by fluorescence enhancement 总被引:1,自引:0,他引:1
Sensor 1 signals the simultaneous presence of sodium and phosphate with an increased fluorescence signal in the manner of a photoionic AND logic gate. 相似文献
174.
Sara Maad 《Arkiv f?r Matematik》2003,41(1):105-114
We study a semilinear elliptic equation of the form
wheref is continuous, odd inu and satisfies some (subcritical) growth conditions. The domain Ω⊂RN is supposed to be an unbounded domain (N≥3). We introduce a class of domains, called strongly asymptotically contractive, and show that for such domains Ω, the equation
has infinitely many solutions. 相似文献
175.
In (Deodhar, Geom. Dedicata, 36(1) (1990), 95–119), Deodhar proposes a combinatorial framework for determining the Kazhdan-Lusztig polynomials P
x
,
w
in the case where W is any Coxeter group. We explicitly describe the combinatorics in the case where
(the symmetric group on n letters) and the permutation w is 321-hexagon-avoiding. Our formula can be expressed in terms of a simple statistic on all subexpressions of any fixed reduced expression for w. As a consequence of our results on Kazhdan-Lusztig polynomials, we show that the Poincaré polynomial of the intersection cohomology of the Schubert variety corresponding to w is (1+q)
l(w)
if and only if w is 321-hexagon-avoiding. We also give a sufficient condition for the Schubert variety X
w
to have a small resolution. We conclude with a simple method for completely determining the singular locus of X
w
when w is 321-hexagon-avoiding. The results extend easily to those Weyl groups whose Coxeter graphs have no branch points (B
C
n
, F
4, G
2). 相似文献
176.
Lablanquie P Penent F Hall RI Eland JH Bolognesi P Cooper D King GC Avaldi L Camilloni R Stranges S Coreno M Prince KC Muehleisen A &Zbreve;itnik M 《Physical review letters》2000,84(3):431-434
Fluorescence decay of the 2s2p(6)np (1)P(o) excited states of neon has been observed directly for the first time. This process has also been observed indirectly by threshold photoelectron spectroscopy and in electron/photon coincidences. The measurements have allowed this weak decay channel to be characterized and branching ratios derived. The fluorescence excitation spectrum is well described by a simple Rydberg model that highlights the interplay and competition between the decay channels of autoionization and fluorescence. 相似文献
177.
178.
179.
Sara Sobhani Zahra Pakdin Parizi Soodabeh Rezazadeh 《Journal of organometallic chemistry》2011,696(3):813-817
3-Aminopropylated silica gel, which is prepared from commercially available and cheap starting materials, is introduced as an efficient and recyclable catalyst for the phospha-Michael addition of phosphorus nucleophiles to α,β-unsaturated malonates. Short reaction times, mild reaction conditions, ease of recovery and catalyst reusability make this method a new, economic and waste-free chemical process for the synthesis of β-phosphonomalonates. 相似文献
180.
L. de Arcangelis H. J. Herrmann M. Kolb René Thomas C. Amitrano L. Peliti M. Saber G. Weisbuch Sara A. Solla F. Bagnoli A. Francescato R. Livi S. Ruffo Pablo Tamayo Michel Droz Peter Jörg Plath S. Romano Yves Pomeau Stéphane Zaleski D. Stauffer Luciano R. da Silva Alex Hansen Stéphane Roux Antonio Coniglio B. Derrida Henrik Flyvbjerg Naeem Jan Dietrich Stauffer Peter Grassberger A. Zippelius K. E. Kurten Werner Krauth Jean -Pierre Nadal Marc Mézard Per Bak Chao Tang Itzhak Webman M. L. Martins H. F. V. Resende C. Tsallis A. C. N. Magalhaes 《Journal of statistical physics》1989,55(5-6):1333-1359