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21.
S. Bhattacharya A.N. Mandal S.R. Ray Chaudhuri A. Chatterjee 《Tetrahedron letters》1984,25(28):3007-3010
An efficient ring contraction of stereoisomeric 1,2-benzo-4-bromo-3-hydroxycyclohept-1-ene and their derivatives (1a-e) to (2a-c) is reported, and a probable mechanism for this ring contraction has been suggested. 相似文献
22.
Molecular-dynamics simulation of model polymer nanocomposite rheology and comparison with experiment
The shear-rate dependence of viscosity is studied for model polymer melts containing various concentrations of spherical filler particles by molecular-dynamics simulations, and the results are compared with the experimental results for calcium-carbonate-filled polypropylene. Although there are some significant differences in scale between the simulated model polymer composite and the system used in the experiments, some important qualitative similarities in shear behavior are observed. The trends in the steady-state shear viscosities of the simulated polymer-filler system agree with those seen in the experimental results; shear viscosities, zero-shear viscosities, and the rate of shear thinning are all seen to increase with filler content in both the experimental and simulated systems. We observe a significant difference between the filler volume fraction dependence of the zero-shear viscosity of the simulated system and that of the experimental system that can be attributed to a large difference in the ratio of the filler particle radius to the radius of gyration of the polymer molecules. In the simulated system, the filler particles are so small that they only have a weak effect on the viscosity of the composite at low filler volume fraction, but in the experimental system, the viscosity of the composite increases rapidly with increasing filler volume fraction. Our results indicate that there exists a value of the ratio of the filler particle radius to the polymer radius of gyration such that the zero-shear-rate viscosity of the composite becomes approximately independent of the filler particle volume fraction. 相似文献
23.
Summary Mixed ligand complexes of the type [VOLA]ClO4 where L=5-bromosalicylaldehyde (L) or 5-nitrosalicylaldehyde (L) and A=2, 2-dipyridyl (A) or 1, 10-phenanthroline (A) have been prepared. Treatment of the mononuclear complexes, [VOLA]ClO4, withp-phenylenediamine (ppd) orm-phenylenediamine (mpd) yielded homobinuclear [VOLA-NC6H4N-LAVO](ClO4)2, complexes, which were characterised by elemental analyses, spectra, magnetic susceptibility and molar conductance measurements. 相似文献
24.
Ghosh SK Khatua PK Ghosh JK Bhattacharya SC 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,61(3):395-401
This paper has explored the quenching of fluorescence of the dye safranine T (ST) by the inorganic cations viz Cu2+, Co2+, Ni2+ and Mn2+ in micellar solutions of the surfactant dioxyethylene nonyl phenol (Igepal CO-210), pentaoxyethylene nonyl phenol (Igepal CO-520) and dodecaoxyethylene nonyl phenol (Igepal CO-720). The quenching results have been calculated in light of stern volmer equation (SV) to evaluate the extent of interaction between the fluorophore (ST) and quencher. The average concentration of the quencher ions in the micelle have been determined. The quenching efficiency of ST by inorganic ions in micellar medium is lower than that in aqueous medium. The results show that the ions get partitioned in the micellar medium. The values of the partition coefficient of the ions decrease with increase in HLB value and number of oxyethylene groups in Igepal. 相似文献
25.
In this paper we include the rearrangement correction (discussed in the preceding paper) in a coupled Hartree–Fock (CHF) calculation of atomic hyperpolarizabilities and other related properties. We have studied the effect of these corrections on properties like electric dipole hyperpolarizabilities, uniform electric field quadrupole polarizabilities and shielding factors in two-electron ions and have noticed significant changes in the computed values over the CHF results. 相似文献
26.
De Sujit Kumar Bhattacharya Kousik 《Journal of Optimization Theory and Applications》2022,192(2):598-627
Journal of Optimization Theory and Applications - This article deals with an economic production quantity (EPQ) model with deterioration under the effect of environmental pollution in fuzzy... 相似文献
27.
Summary We consider a (possibly) vector-valued function u: RN, Rn, minimizing the integral
, 2-2/(n*1)<p<2, whereD
i
u=u/x
i
or some more general functional retaining the same behaviour, we prove higher integrability for Du: D1 u,..., Dn–1 u Lp/(p-1) and Dnu L2; this result allows us to get existence of second weak derivatives: D(D1 u),...,D(Dn–1u)L2 and D(Dn u) L
p.This work has been supported by MURST and GNAFA-CNR. 相似文献
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