全文获取类型
收费全文 | 5871篇 |
免费 | 400篇 |
国内免费 | 72篇 |
专业分类
化学 | 4615篇 |
晶体学 | 39篇 |
力学 | 110篇 |
综合类 | 3篇 |
数学 | 376篇 |
物理学 | 1200篇 |
出版年
2024年 | 8篇 |
2023年 | 48篇 |
2022年 | 111篇 |
2021年 | 159篇 |
2020年 | 128篇 |
2019年 | 151篇 |
2018年 | 98篇 |
2017年 | 108篇 |
2016年 | 222篇 |
2015年 | 210篇 |
2014年 | 261篇 |
2013年 | 392篇 |
2012年 | 502篇 |
2011年 | 558篇 |
2010年 | 354篇 |
2009年 | 300篇 |
2008年 | 437篇 |
2007年 | 351篇 |
2006年 | 347篇 |
2005年 | 312篇 |
2004年 | 267篇 |
2003年 | 184篇 |
2002年 | 210篇 |
2001年 | 103篇 |
2000年 | 84篇 |
1999年 | 71篇 |
1998年 | 53篇 |
1997年 | 48篇 |
1996年 | 40篇 |
1995年 | 33篇 |
1994年 | 24篇 |
1993年 | 20篇 |
1992年 | 6篇 |
1991年 | 11篇 |
1990年 | 12篇 |
1989年 | 8篇 |
1988年 | 10篇 |
1987年 | 9篇 |
1986年 | 3篇 |
1985年 | 12篇 |
1984年 | 9篇 |
1983年 | 15篇 |
1982年 | 6篇 |
1981年 | 7篇 |
1980年 | 10篇 |
1979年 | 6篇 |
1978年 | 5篇 |
1975年 | 3篇 |
1973年 | 3篇 |
1969年 | 3篇 |
排序方式: 共有6343条查询结果,搜索用时 0 毫秒
21.
Ju Yeon Woo Eun Hee Kim Byung Kyu Kim 《Journal of polymer science. Part A, Polymer chemistry》2007,45(23):5590-5596
Doping of conductive fullerene particles to the formulation of conventional holographic polymer dispersed liquid crystal‐induced dual effects of reducing both droplet coalescence and operating voltage. Fullerene induced an induction period which otherwise does not exist, followed by a gradual increase of diffraction efficiency to a saturation value being increased with increasing fullerene content. The increased diffraction efficiency was caused by the decreased droplet coalescence which was due to the hindered migration of LC by the fullerene particles. On the other hand, doped fullerene particles augmented the conductivity of polymer phase and hence the local electrical field imposed on LC droplet, which overcome the threshold for driving and reduced operating voltage and response times. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5590–5596, 2007 相似文献
22.
Ranked-set sampling is useful when measurements are destructive or costly to obtain but ranking of the observations is relatively easy. The Wilcoxon signed rank test statistic based on the ranked-set sample is considered. We compared the asymptotic relative efficiencies of the RSS Wilcoxon signed rank test statistic with respect to the SRS Wilcoxon signed rank test statistic and the RSS sign test statistic. Throughout the ARE’s, the proposed test statistic is superior to the SRS Wilcoxon signed rank test statistic and the RSS sign test statistic. 相似文献
23.
24.
In this paper we introduce a new notion of infine nonsmooth functions and give several characterizations of infineness property. We prove alternative theorems with mixed constraints (i.e., inequality and equality constraints) being described by invex-infine nonsmooth functions. We establish a necessary and sufficient condition for a solution of a vector optimization problem involving mixed constraints to be a properly efficient solution. 相似文献
25.
Hee Seok Choi Young Han Kim Shun Myung Shin 《Journal of polymer science. Part A, Polymer chemistry》2006,44(8):2428-2439
An in‐line monitoring device using a quartz crystal resonator for thin film polymerization was proposed, and its performance has been evaluated by implementing in the UV polymerization of 2‐hydroxyethyl methacrylate with a photoinitiator of 1‐chloroanthraquinone. Because the variation of resonant resistance of the resonator is proportional to the square root of viscosity change that is closely related to the polymerization degree, the resistance can be used as a measure of the polymerization degree. The resistance measurements were compared with the outcome of instrumental analyses of polymerization degree using an FTIR spectrometer and a gel permeation chromatograph. The experimental results showed that the resistance measurements were consistent with the experimental outcome of the instrumental analyses, and this indicates the effectiveness of the proposed device. Owing to the simplicity and availability of the resonator system, its wide utilization in the monitoring of a variety of film polymerization processes, including photoresistor application, is expected. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2428–2439, 2006 相似文献
26.
Cascade Grating Structure for Increasing the Channel Number on Holographic Demultiplexer 总被引:1,自引:0,他引:1 下载免费PDF全文
Jun Won AN 《中国物理快报》2006,23(6):1459-1461
The expansion capability of the channel number in the optical demultiplexer using two cascaded photopolymer volume gratings is reported. It could be accomplished by designing of two gratings with different spectral range. As a result of the experiment, a 0.4-nm-spaced 130-channel demultiplexer with the channel uniformity of 3.5 dB, the 3 riB-bandwidth of 0.12nm, and the channel crosstalk of-20 dB is experimentally demonstrated. 相似文献
27.
28.
Transmission gratings of holographic polymer-dispersed liquid crystals (HPDLC) are prepared under controlled reaction conditions by adding various amounts of chain-transfer agent (CTA). The resulting films have a higher gel content with lower cross-link density, less dark reaction, less grating shrinkage with much smoother LC/polymer interfaces, smaller induction period, and fast saturation of diffraction efficiency, which shows a maximum of 95 % with 1 % CTA. An optimum LC content of 35 % is verified on the basis of morphology and reaction kinetics. 相似文献
29.
在很高的温度和适宜的生长条件下,分别采用熔盐籽晶法和高温引上法生长了高质量的YAP、NAB、KTP、LN、BBO、SBN等多元氧化物单晶,它们具有优良的物理化学性能,严格的化学比,固定的组成与结构以及较好的化学均匀性和电子束轰击下的稳定性。广泛地用于激光和非线性光学领域。我们选用这些晶体为原材料研制电子探针定量分析的标准样品。经过测量和标定,这些单晶标样符合中华人民共和国国家标准GB 4930-85(电子探针显微分析标准样品通用技术条件)的规定。含有稀土元素的标样如NAB和YAP能发出绿色荧光,是电子显微术中理想的阴极发光材料。 相似文献
30.
Photodissociation at 266 nm of protonated synthetic polypeptides containing a tryptophanyl residue was investigated using a homebuilt tandem time-of-flight mass spectrometer equipped with a matrix-assisted laser desorption/ionization source. Efficient photodissociation of the protonated peptides was demonstrated. Most of the intense peaks in the laser-induced tandem mass spectra were sequence ions. Furthermore, sequence ions due to cleavages at all the peptide bonds were observed; this is a feature of the technique that is particularly useful for peptide sequencing. Fragmentations at both ends of the tryptophanyl residue were especially prevalent, which can be useful for location of the tryptophanyl chromophore in a peptide. 相似文献