Influence of reactor design on the electrochemical oxidation and disinfection of wastewaters using boron-doped diamond electrodes

Electrochemical oxidation is the most popular electrochemical advanced oxidation process within the scientific community owing to its simplicity and high effectiveness to treat different wastewaters. Electrode material and reactor design are important factors that influence the removal efficiency of pollutants. This work presents an overview of recent applications of electrochemical oxidation process for contaminant mineralization and water disinfection using electrochemical reactors, in batch and continuous mode of operation, fitted with boron-doped diamond electrodes. In addition, recent advances in the use of flow-through reactors (continuous single-pass and recirculation) are presented. Geometrical aspects, operating conditions, and energy consumption are provided and discussed.     

Synthesis of a 10-membered ring with eleutheside functionality by Nozaki-Hiyama-Kishi coupling

The synthesis of a medium-sized unit of 15-seco-eleutheside analogue 3 has been achieved by the NiCl₂/CrCl₂-mediated intramolecular coupling of iodoaldehyde 8 with excellent yields. An important issue in our reported route to 3 involved a pyranose/furanose rearrangement, which opened the tetrahydrofuran ring on to the target.     

The effect of conditioning of fused-silica capillaries on their electrophoretic performance

In CE practice, conditioning of the capillary tube with strong base, acid, or both in sequence, has been recognized as essential to obtain reasonable precision in electroosmotic mobility (EOM), and consequently, in the migration times of analytes. This report focuses on the comparative study of three different approaches for capillary conditioning: etching with HF, etching with NaOH, and leaching with HCl after NaOH treatment. EOM-based measurements, including the hysteresis effect that characterizes the dependence of EOM with pH, were used to evaluate the conditioned silica surface. Additionally, indirect inspection of the conditioned surface was carried out by examining the electrophoretic profile of the cationic probe Ru(bpy)(3) (2+), known to strongly interact with the ionized silica surface while displaying no significant acid-base activity. It was shown that, once conditioned and prior to any CE measurement, extensive rinse of the capillary with the running electrolyte at high flow rate was essential to attain relatively rapid re-equilibration of the tube with the fluid. Insufficient rinse with the running electrolyte would result in negatively biased EOM measurements and significant drift in migration times. It was also established that relatively high flow rates of 1 M NaOH conditioning solution (4-5 column volumes per minute) was required to attain capillaries with reproducible electrophoretic performance within a reasonable conditioning time (typically, 1 h). In addition to relatively more extensive rehydroxylation of the silica surface, evidenced by the highest EOM values obtained, the sequential use of NaOH-etching and HCl-leaching provided better precision than HF-etching or NaOH-etching alone.     

The G-invariant spectrum and non-orbifold singularities

We consider the G-invariant spectrum of the Laplacian on an orbit space M/G where M is a compact Riemannian manifold and G acts by isometries. We generalize the Sunada–Pesce–Sutton technique to the G-invariant setting to produce pairs of isospectral non-isometric orbit spaces. One of these spaces is isometric to an orbifold with constant sectional curvature whereas the other admits non-orbifold singularities and therefore has unbounded sectional curvature. We conclude that constant sectional curvature and the presence of non-orbifold singularities are inaudible to the G-invariant spectrum.     

Chiral η6‐Arene/N‐Tosylethylenediamine–Ruthenium(II) Complexes: Solution Behavior and Catalytic Activity for Asymmetric Hydrogenation

Aromatic ketones are enantioseletively hydrogenated in alcohols containing [RuX{(S,S)‐Tsdpen}(η⁶‐p‐cymene)] (Tsdpen=TsNCH(C₆H₅)CH(C₆H₅)NH₂; X=TfO, Cl) as precatalysts. The corresponding Ru hydride (X=H) acts as a reducing species. The solution structures and complete spectral assignment of these complexes have been determined using 2D NMR (¹H‐¹H DQF‐COSY, ¹H‐¹³C HMQC, ¹H‐¹⁵N HSQC, and ¹H‐¹⁹F HOESY). Depending on the nature of the solvents and conditions, the precatalysts exist as a covalently bound complex, tight ion pair of [Ru⁺(Tsdpen)(cymene)] and X^?, solvent‐separated ion pair, or discrete free ions. Solvent effects on the NH₂ chemical shifts of the Ru complexes and the hydrodynamic radius and volume of the Ru⁺ and TfO^? ions elucidate the process of precatalyst activation for hydrogenation. Most notably, the Ru triflate possessing a high ionizability, substantiated by cyclic voltammetry, exists in alcoholic solvents largely as a solvent‐separated ion pair and/or free ions. Accordingly, its diffusion‐derived data in CD₃OD reflect the independent motion of [Ru⁺(Tsdpen)(cymene)] and TfO^?. In CDCl₃, the complex largely retains the covalent structure showing similar diffusion data for the cation and anion. The Ru triflate and chloride show similar but distinct solution behavior in various solvents. Conductivity measurements and catalytic behavior demonstrate that both complexes ionize in CH₃OH to generate a common [Ru⁺(Tsdpen)(cymene)] and X^?, although the extent is significantly greater for X=TfO^?. The activation of [RuX(Tsdpen)(cymene)] during catalytic hydrogenation in alcoholic solvent occurs by simple ionization to generate [Ru⁺(Tsdpen)(cymene)]. The catalytic activity is thus significantly influenced by the reaction conditions.     

Electrochemical treatment of slaughterhouse and dairy wastewater: Toward making a sustainable process

The industrial processing of meat and dairy production uses large amounts of fresh water, therefore, generates a significant volume of wastewaters. The treatment of these effluents has been performed using different technologies from biological to electrochemical advanced oxidation processes. Under the circular economy concept, the lack of available freshwater resources has increased the interest in reusing wastewater from slaughterhouses, and even in the recovering of by-products.This article reviews the application of electrochemical treatments to slaughterhouse and dairy wastewaters. In addition, an overview of added-value products and energy recovery from these industrial wastewaters is also presented with future perspectives.     

The hypergeneralized Heun equation in quantum field theory in curved space-times

We show for the first time the role played by the hypergeneralized Heun equation (HHE) in the context of quantum field theory in curved space-times. More precisely, we find suitable transformations relating the separated radial and angular parts of a massive Dirac equation in the Kerr-Newman-deSitter metric to a HHE.     

Pion production as a probe of the nuclear matter equation of state

It is shown that thermal and chemical equilibrium are approached during the high density stage in central nucleus-nucleus collisions and that the yield of produced pions is determined at that time. A chemical model with Rankine-Hugoniot compression is used to extract a nuclear matter equation of state from the observed pion yield assuming a partition of the internal energy per nucleon into thermal and compressional energy fractions, with only the former part contributing to particle production.