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111.
112.
Generalized flow equations developed for two-phase flow through porous media contain a second term that enables proper account to be taken of capillary coupling between the two flowing phases. In this study, a partition concept, together with a novel capillary pressure equation for countercurrent flow, have been introduced into Kalaydjian’s generalized flow equations to construct modified flow equations which enable a better understanding of the role of capillary coupling in horizontal, two-phase flow. With the help of these equations it is demonstrated that the reduced flux observed in countercurrent flow, as compared to cocurrent flow, can be explained by the reduction in the driving force per unit volume which comes about because of capillary coupling. Also, it is shown experimentally that, because fluids flow through a void space reduced in magnitude due to the presence of immobile irreducible and residual saturations, the capillary coupling parameter should be defined in terms of a reduced porosity, rather than in terms of porosity. Moreover, it is shown statistically that the countercurrent relative permeability curve is proportional to the cocurrent relative permeability curve, the constant of proportionality being the capillary coupling parameter. Finally it is suggested that one can eliminate the need to determine experimentally countercurrent relative permeability curves by making use of an equation constructed for predicting the magnitude of the capillary coupling parameter. 相似文献
113.
Dynamic spontaneous imbibition (DSI) plays an important role in oil reservoir characterization. Conventional equations used to characterize DSI consider neither interfacial coupling effects (ICE) nor variable inlet saturation (S*) for DSI. Yazzan et?al. (Transp Porous Media 87(1):309?C333, 2011a; 86(3):705?C717, 2011b) developed a set of equations, and a numerical solution scheme, to take into account ICE and variable S* for DSI. Based on these, a graphical user interface (GUI) simulator was built. A sensitivity analysis has been conducted to study the effect of the fluid and rock properties on DSI. The results reveal that including a variable S* has no significant impact; however, neglecting ICE results in an overestimation of the imbibition flow rate. Moreover, it is shown that the capillary and relative permeability curves determine the type of frontal advance, and that the imbibition recovery is proportional to the square root of time. 相似文献
114.
Parimal Trivedi D. N. Bhavsar Sunil Chaki R. G. Patel 《Molecular Crystals and Liquid Crystals》2014,592(1):183-198
Charge transfer (CT) complexes of aniline blue (AB) were prepared with standard organic acceptors such as TCNQ, TCNE, DDQ, and chloranil and studied with UV-VIS-NIR spectra showing σ→π* and π→π* transitions along with free-carrier absorption due to scattering of light particles which has been found involving phonon–photon, electron–photon, and electron–electron scattering. Infrared spectra contain half power beta density due to hopping conduction and an asymmetric band corresponding to A(k) = A0k exp(?bk) as absorption associated with diffraction of IR light from the crystalline particles. 相似文献
115.
Sumanta Bhattacharya Sandip K Nayak Subrata Chattopadhyay Manas Banerjee Asok K Mukherjee 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2002,58(2):289-298
[70]fullerene has been shown to form 1:1 EDA complex with anthracene, naphthalene, phenanthrene, pyrene and acenaphthene in CCl4 medium. Charge transfer (CT) bands have been detected in all the cases. Isosbestic points have been observed in the cases of phenanthrene and acenaphthene complexes. Ionisation potentials of the donors and CT transition energies have been found to correlate in accordance with Mulliken equation and from this correlation the electron affinity of C70 has been found to be 2.59 eV. Enthalpies and entropies of formation of the complexes have been estimated from the formation constants of the complexes determined spectrophotometrically at three different temperatures. 相似文献
116.
A. Dhal R. K. Sinha D. Negi T. Trivedi M. K. Raju D. Choudhury G. Mohanto S. Kumar J. Gehlot R. Kumar S. Nath S. S. Ghugre R. P. Singh J. J. Das S. Muralithar N. Madhavan J. B. Gupta A. K. Sinha A. K. Jain I. M. Govil R. K. Bhowmik S. C. Pancholi L. Chaturvedi 《The European Physical Journal A - Hadrons and Nuclei》2012,48(3):1-10
The odd mass nucleus 137Pm has been studied to high spins through the 109Ag(32S, 2p2n)137Pm reaction at an incident beam energy of 150 MeV. The de-exciting ??-rays were detected using an array of 18 Compton suppressed clover detectors. The level scheme of 137Pm has been extended up to $J^\pi = \tfrac{{43}} {2}^ -$ and excitation energy of E x ? 6 MeV with the observation of 42 new gamma transitions. The linear polarization (IPDCO) measurements for the ??-ray transitions have been done for the first time. The spin and parity assignments for most of the reported levels have been made using these results and the coincidence angular anisotropy (RDCO) measurements. The nuclear shape evolution is discussed in the light of Total Routhian Surface (TRS) and Cranked Shell Model (CSM) calculations. 相似文献
117.
Simone Giombi Shiraz Minwalla Shiroman Prakash Sandip P. Trivedi Spenta R. Wadia Xi Yin 《The European Physical Journal C - Particles and Fields》2012,72(8):1-65
We study three-dimensional conformal field theories described by U(N) Chern?CSimons theory at level k coupled to massless fermions in the fundamental representation. By solving a Schwinger?CDyson equation in light-cone gauge, we compute the exact planar free energy of the theory at finite temperature on ?2 as a function of the ??t?Hooft coupling ??=N/k. Employing a dimensional reduction regularization scheme, we find that the free energy vanishes at |??|=1; the conformal theory does not exist for |??|>1. We analyze the operator spectrum via the anomalous conservation relation for higher spin currents, and in particular show that the higher spin currents do not develop anomalous dimensions at leading order in 1/N. We present an integral equation whose solution in principle determines all correlators of these currents at leading order in 1/N and present explicit perturbative results for all three-point functions up to two loops. We also discuss a light-cone Hamiltonian formulation of this theory where a W ?? algebra arises. The maximally supersymmetric version of our theory is ABJ model with one gauge group taken to be U(1), demonstrating that a pure higher spin gauge theory arises as a limit of string theory. 相似文献
118.
A novel, ultrafast, mild and scalable amide bond formation strategy in methanol using simple thioacids and amines is described. The mechanism suggests that the coupling reactions are initially mediated by CuSO(4)·5H(2)O and subsequently catalyzed by in situ generated copper sulfide. The pure peptides were isolated in satisfactory yields in less than 5 minutes. 相似文献
119.
Amal Halder Sandip K. Nayak Subrata Chattopadhyay Sumanta Bhattacharya 《Journal of solution chemistry》2012,41(2):223-240
The present article reports the host-guest complexation of a calix[4]arene derivative, namely 4-iso-propyl-calix[4]arene (1), with fullerenes (both C60 and C70) in toluene and benzonitrile solutions. It is observed that the charge-transfer (CT) absorption bands are located in the
ground state for the C60 and C70 complexes of 1. By utilizing the CT absorption bands, various important physicochemical parameters like the oscillator strength, resonance
energy, transition dipole moment, electronic coupling element and solvent reorganization energies have been estimated for
the C60-1 and C70-1 complexes. The CT transition energy is very helpful for determining the vertical ionization potential of 1 in solution. Jobs method of continuous variation was used to establish 1:1 stoichiometry for the fullerene complexes of 1. The most fascinating feature of the present study is that 1 binds C70 preferentially compared to C60 as obtained from binding constant (K) data. The effect of solvent on the complexation of fullerenes (C60 and C70) with 1 is clearly observed from the trend in the K values: in toluene and whereas in benzonitrile, and . Molecular mechanics force field (MMMF) calculations reveal fascinating features regarding the binding pattern of fullerenes
towards 1 in vacuo in terms of enthalpy of formation. MMMF calculations establish that during C70-1 complexation, C70 is directed in an end-on manner rather than the traditional side-on pattern. 相似文献
120.
Chetan K. Modi Parthiv M. Trivedi Sanjeev K. Gupta Prafulla K. Jha 《Journal of inclusion phenomena and macrocyclic chemistry》2012,74(1-4):117-127
A series of zeolite-Y encapsulated hybrid catalysts, [M(STCH)·xH2O]-Y have been prepared by encapsulating Schiff base complexes [where M?=?Mn(II), Fe(II), Co(II), Ni(II); (x?=?3) and Cu(II); (x?=?1); H2STCH?=?salicylaldehyde thiophene-2-carboxylic hydrazone] in zeolite-Y matrix by flexible ligand method. These hybrid materials have been characterized by various physico-chemical techniques such as ICP-OES, elemental analyses, (FT-IR and electronic) spectral studies, BET, scanning electron micrographs, thermal analysis and X-ray powder diffraction patterns. X-ray powder diffraction analysis reveals that the structural integrity of the mother zeolite in the hybrid material remained intact upon immobilization of the complex. Density functional theory is employed to calculate the relaxed structure, bond angle, bond distance, dihedral angle, difference of highest occupied molecular orbital and lowest unoccupied molecular orbital energies gap and electronic density of states of ligand and their neat transition metal complexes. The hybrid materials are active catalysts for the hydroxylation of phenol using hydrogen peroxide (30% H2O2) as an oxidant in order to selectively synthesize catechol or hydroquinone, amongst them [Cu(STCH)·H2O]-Y shown the highest % of selectivity towards catechol (81.3%). 相似文献