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91.
Pascu SI Naumann C Kaiser G Bond AD Sanders JK Jarrosson T 《Dalton transactions (Cambridge, England : 2003)》2007,(35):3874-3884
Kinetic stability studies of a series of pseudorotaxanes formed from electron-rich crown ethers (hosts and ) and naphthalene diimide (guest ) in the presence of alkali salt templates MX (where M(+) = Li(+) and Na(+), and X(-) = Cl(-), Br(-), I(-), NO(3)(-) and CF(3)SO(3)(-)) were performed by (1)H NMR. The switching between the (bound) host and its linkage isomer host (free) was monitored in solution in the presence and absence of alkali salts, to establish the relative thermodynamic stabilities in the series. We also report here six new crystal structures, for pseudorotaxanes of type: [.], [M(2)..](2+) and [M(2)..](2+). Their solution-phase structures are in good agreement with the solid-state structures determined by X-ray crystallography. 相似文献
92.
93.
94.
T. Sanders 《Journal d'Analyse Mathématique》2007,101(1):123-162
The paper has two main parts. To begin with, suppose that G is a compact abelian group. Chang’s Theorem can be viewed as a structural refinement of Bessel’s inequality for functions
ƒ ∈ L
2(G). We prove an analogous result for functions ƒ ∈ A(G), where A(G) is the space
endowed with the norm
, and generalize this to the approximate Fourier transform on Bohr sets.
As an application of the first part of the paper, we improve a recent result of Green and Konyagin. Suppose that p is a prime number and A ⊂ ℤ/pℤ has density bounded away from 0 and 1 by an absolute constant. Green and Konyagin have shown that ‖χ
A
‖
A(ℤ/pℤ) ≫ ɛ (log p)1/3−ɛ; we improve this to ‖χ
A
‖
A(ℤ/pℤ) ≫ ɛ (log p)1/2−ɛ. To put this in context, it is easy to see that if A is an arithmetic progression, then ‖χ
A
‖
A(ℤ/pℤ) ≪ log p. 相似文献
95.
This article uses the discharging method to obtain the best possible results that a 3‐connected graph embeddable on a surface of Euler characteristic χ ≤ −46 has a spanning tree of maximum degree at most and a closed, spanning walk meetting each vertex at most times. Each of these results is shown to be best possible. © 2001 John Wiley & Sons, Inc. J Graph Theory 36: 67–74, 2001 相似文献
96.
Chi Ching Mak Nick Bampos Jeremy K. M. Sanders 《Angewandte Chemie (International ed. in English)》1998,37(21):3020-3023
Rigid and flexible linkers are combined in the new dendrimer shown schematically in the picture, which contains nine metalloporphyrin units (Porph). The construction is such that the four “arms” of the dendrimer can fold in a cooperative and predetermined manner in response to added 1,4-diazabicyclo[2.2.2]octane (DABCO). 相似文献
97.
98.
99.
100.
Mao J Mukherjee S Zhang Y Cao R Sanders JM Song Y Zhang Y Meints GA Gao YG Mukkamala D Hudock MP Oldfield E 《Journal of the American Chemical Society》2006,128(45):14485-14497
Bisphosphonates are a class of molecules in widespread use in treating bone resorption diseases and are also of interest as immunomodulators and anti-infectives. They function by inhibiting the enzyme farnesyl diphosphate synthase (FPPS), but the details of how these molecules bind are not fully understood. Here, we report the results of a solid-state (13)C, (15)N, and (31)P magic-angle sample spinning (MAS) NMR and quantum chemical investigation of several bisphosphonates, both as pure compounds and when bound to FPPS, to provide information about side-chain and phosphonate backbone protonation states when bound to the enzyme. We then used computational docking methods (with the charges assigned by NMR) to predict how several bisphosphonates bind to FPPS. Finally, we used X-ray crystallography to determine the structures of two potent bisphosphonate inhibitors, finding good agreement with the computational results, opening up the possibility of using the combination of NMR, quantum chemistry and molecular docking to facilitate the design of other, novel prenytransferase inhibitors. 相似文献