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691.
We describe a miniaturized instrument capable of performing 2-DE. Our miniaturized device is able to perform IEF and polyacrylamide slab gel electrophoresis (PASGE) in the same unit. It consists of a compartment for a first-dimensional IEF gel, which is connected to a second-dimensional PASGE gel. The focused samples are automatically transferred from the IEF gel to the PASGE gel by electromigration. Our preliminary experiments show that the device is able to focus and separate a mixture of proteins in approximately 1 h, excluding the time required for the staining procedure. On average, the gel-to-gel retardation factor (Rf) variation was 6.2% (+/-0.9%) and pI variation was 2.5% (+/-0.6%). Separated protein spots were excised from stained gels, digested with trypsin, and further identified by MS, thus enabling direct proteomic analysis of the separated proteins.  相似文献   
692.
Sami Bidier  Wolfgang Ehlers 《PAMM》2014,14(1):575-576
The individual motion of grains in granular material has a strong influence on the macroscopic material behaviour, which is in particular the case for the phenomena of strain localisation in shear zones and justifies the need for techniques that incorporate a micro-macro transition. In this contribution, granular media are investigated in three steps. Firstly, a microscopic particle-based modelling is set up, where individual grains are considered as rigid uncrushable particles while their motion is obtained through Newton's equations of state. The inter-particle contact forces are thereby determined via constitutive contact-force formulations, which have to account for the envisaged material behaviour. The second step is the homogenisation of the obtained particle's displacements and contact forces through a particle-centre-based strategy towards continuum quantities. Therefore, Representative Elementary Volumes (REV) are introduced on the mesoscale and the specific construction of the REV boundary leads to the understanding of granular media as a micropolar continuum. Finally, in order to verify the homogenisation strategy, a continuum based micropolar model is applied to model localisation phenomena and a comparative study of the results is carried out in a qualitative way. (© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
693.
We generalize the BM-local time fractional symmetric αα-stable motion introduced in Cohen and Samorodnitsky (2006) by replacing the local time with a general continuous additive functional (CAF). We show that the resulting process is again symmetric αα-stable with stationary increments. Depending on the CAF, the process is either self-similar or lies in the domain of attraction of the BM-local time fractional symmetric αα-stable motion. We also show that the process arises as a weak limit of a discrete “random rewards scheme” similar to the one described by Cohen and Samorodnitsky.  相似文献   
694.
The effects of non-magnetic Ti4+ substitution on the structural, electrical and magnetic properties of La0.67Ba0.33Mn1?x Ti x O3 (0≤x≤0.1) are investigated and compared to those existing in La0.67Ba0.33Mn1?x Cr x O3 (magnetic Cr3+). The structural refinement by the Rietveld method revealed that Ti-doped samples crystallize in the cubic lattice with space group $\mathrm{Pm}\bar{3}\mathrm{m}$ , while samples with Cr crystallize in the hexagonal setting of the rhombohedral $\mathrm{R}\bar{3}\mathrm{C}$ space group for identical contents of dopant. The most relevant structural features are an increase of the lattice parameters, of the cell volume and of the inter-ionic distances with increasing Ti doping level. Both series of samples show a decrease of the paramagnetic–ferromagnetic transition temperature when the amount of chromium or titanium increases. Transport measurements show that when increasing the metal doping, the resistivity increases whereas the metallic behavior of the parent compound La0.67Ba0.33MnO3 is destroyed. For a substitution higher than 5 at.% of Ti and 10 at.% of Cr, the samples exhibit a semiconducting behavior in the whole range of temperature, for which the electronic transport can be explained by variable range hopping and/or small polaron hopping models.  相似文献   
695.
The electrical properties and the mechanism of conduction of the simultaneously substituted La0.7−xYxBa0.3Mn1−xFexO3 perovskite (0≤x≤0.30) have been studied. The insertion of Y3+ and Fe3+ ions in the parent compound La0.7Ba0.3MnO3 leads to an increase of the resistivity. The undoped sample (x=0) shows a metallic behavior, which can be fitted by the relation ρ(T)=ρ0+ρ2T2+ρ4.5T4.5, indicating the importance of electron-magnon scattering effects in this material. All the other samples (x≥0.10) are semiconductors throughout the studied temperature range (80-290 K). Several models have been used to fit their temperature-dependent resistivity: thermal activation, adiabatic nearest-neighbor hopping of small polarons (Holstein theory) and variable range hopping (VRH) models. The fits show that the electronic transport in semiconducting La0.7−xYxBa0.3Mn1−xFexO3 is well described and dominated by the VRH mechanism, for which the hopping distance (a) grows with increasing Fe3+ doping, thus increasing the average hopping energy W.  相似文献   
696.
Bacterial biofilms constitute an extremely resistant form of bacterial colonization with dire health and economical implications. Towards achieving polymeric composites capable of resisting bacterial adhesion and biofilm formation, we prepared five 2,6-pyridinedicarboxylate-based polyesters employing five different diol monomers. The resulting polyesters were complexed with copper (II) or silver (I). The new polymers were characterized by proton and carbon nuclear magnetic resonance spectroscopy, inherent viscosity, infrared spectroscopy, differential scanning calorimetry and thermogravimetric analysis. The corresponding metal complexes were characterized by differential scanning calorimetry and infrared spectroscopy. The amounts of complexed copper and silver were determined by atomic absorption spectrophotometry. Finally, the resulting composites were tested for their antibacterial potential and were found to effectively resist bacterial attachment and growth.  相似文献   
697.
Two at a time: α,β-Unsaturated iminium ions can be generated by laser flash photolysis of enaminophosphonium ions. The rate constants of their reactions with nucleophiles provide the first direct comparison of the electrophilicities of iminium ions derived from MacMillan's first- and second-generation catalysts.  相似文献   
698.
699.
Electrophilic substitution of pyrroles by α,β-unsaturated iminium ions is slow in acetonitrile when only weakly basic counterions are present. When the reactions are carried out in the presence of KCF(3)CO(2), fast deprotonation of the intermediate σ-adducts occurs, and the rate constant for the rate-determining CC bond-forming step can be predicted from the electrophilicity parameter E of the iminium ion and the N and s parameters of the pyrroles.  相似文献   
700.

This paper is devoted to the nonparametric estimation of the derivative of the regression function in a nonparametric regression model. We implement a very efficient and easy to handle statistical procedure based on the derivative of the recursive Nadaraya–Watson estimator. We establish the almost sure convergence as well as the asymptotic normality for our estimates. We also illustrate our nonparametric estimation procedure on simulated data and real life data associated with sea shores water quality and valvometry.

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