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51.
Samer A. Kharroubi 《Computational Statistics》2018,33(1):213-234
We explore the use of importance sampling based on exponentially tilted signed root log-likelihood ratios for Bayesian computation. Approximations based on exponentially tilted signed root log-likelihood ratios are used in two distinct ways; firstly, to define an importance function with antithetic variates and, secondly, to define suitable control variates for variance reduction. These considerations give rise to alternative simulation-consistent schemes to other importance sampling techniques (for example, conventional and/or adaptive importance sampling) for Bayesian computation in moderately parameterized regular problems. The schemes based on control variates can also be viewed as usefully supplementing computations based on asymptotic approximations by supplying external estimates of error. The methods are illustrated by a censored regression model and a more challenging 12-parameter nonlinear repeated measures model for bacterial clearance. 相似文献
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New 1,2,3-thiadiazole and 1,2,3-selenadiazole derivatives, 14-23, were prepared from the ketones 1-5 via the corresponding semicarbazones or hydrazones 6-12. The Hurd-Mori and Lalezari methods were used, respectively, for the preparation of these 1,2,3-thiadiazole and 1,2,3-selenadiazole derivatives. The intermediate 13 was also trapped, separated and fully characterized. These derivatives are important for photocrosslinking processes and due to their potential biological activity. 相似文献
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Samara Fatin Al Shamsi Maitha Kanaan Faisal Kanan Sofian M. 《Research on Chemical Intermediates》2020,46(2):1017-1032
Research on Chemical Intermediates - Silver clusters were introduced into the framework of zeolite Y. Low-temperature solid-state luminescence indicates the formation of silver–silver... 相似文献
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Protocols for solid-phase syntheses of soluble peptidyl phosphoranes are presented. Various supported phosphoranylidene acetates were prepared on Rink amide or via alkylation of trialkyl- and triarylphosphines with bromoacetyl Wang ester. C-Acylation was conducted racemization-free with activated Fmoc-amino acids, followed by SPPS (solid-phase peptide synthesis). Acidic conditions released decarboxylated peptidyl phosphoranes into solution. The protocol allowed for the electronic variation of peptidyl phosphoranes which were investigated in ligation reactions with azides in organic and aqueous solvents. 相似文献
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Samer Israwi 《Nonlinear Analysis: Theory, Methods & Applications》2011,74(1):81-93
We consider here the 1D Green-Naghdi equations that are commonly used in coastal oceanography to describe the propagation of large amplitude surface waves. We show that the solution of the Green-Naghdi equations can be constructed by a standard Picard iterative scheme so that there is no loss of regularity of the solution with respect to the initial condition. 相似文献
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Rubén Fuentes-Fernández Samer Hassan Juan Pavón José M. Galán Adolfo López-Paredes 《Computational & Mathematical Organization Theory》2012,18(1):91-112
A major challenge in agent-based modelling is the management of the process to generate executable simulations from the initial
conceptual models. This process is complex and usually involves several roles, which may raise communication problems due
to the diverse backgrounds and perspectives of participants and the use of non-explicit knowledge. This situation demands
a clear separation and precise definition of the multiple aspects of the process, in order to facilitate their understanding,
grasp their relationships and develop them. This paper addresses this goal with a fine-step refinement process for information
based on the use of domain-specific languages. It considers analysis contexts that include a particular theoretical framework,
domain, type of problem and target platform. For a given context, the process formally defines modelling languages conceptually
close to the different aspects relevant to it. It also defines mappings between concepts in those languages. Researchers develop
simulations by specifying models with the languages, and share and refine information by using mappings between these models.
This infrastructure provides guidance throughout the process and makes the information involved explicit. A case study of
continuous double auctions illustrates the approach. 相似文献