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11.
For decades, organizational researchers have employed standard statistical methods to uncover relationships among variables and constructs. However, in complex organization systems, the prevalence of non-linearity and outliers is to be expected. Under such circumstances, the use of standard statistical methods becomes unreliable and, correspondingly, results in degraded predictions of the relationships within the organizational systems. We describe the use of neural network analyses to model team effectiveness so as to provide more accurate predictions for managers. 相似文献
12.
Naveed Ahmad Khan Fahad Sameer Alshammari Carlos Andrs Tavera Romero Muhammad Sulaiman 《Entropy (Basel, Switzerland)》2021,23(12)
In this paper, we have analyzed the mathematical model of various nonlinear oscillators arising in different fields of engineering. Further, approximate solutions for different variations in oscillators are studied by using feedforward neural networks (NNs) based on the backpropagated Levenberg–Marquardt algorithm (BLMA). A data set for different problem scenarios for the supervised learning of BLMA has been generated by the Runge–Kutta method of order 4 (RK-4) with the “NDSolve” package in Mathematica. The worth of the approximate solution by NN-BLMA is attained by employing the processing of testing, training, and validation of the reference data set. For each model, convergence analysis, error histograms, regression analysis, and curve fitting are considered to study the robustness and accuracy of the design scheme. 相似文献
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14.
Massless Dirac fermions in monolayer graphene exhibit total transmission when normally incident on a scalar potential barrier, a consequence of the Klein paradox originally predicted by O Klein for relativistic electrons obeying the 3 + 1 dimensional Dirac equation. For bilayer graphene, charge carriers are massive Dirac fermions and, due to different chiralities, electron and hole states are not coupled to each other. Therefore, the wavefunction of an incident particle decays inside a barrier as for the non-relativistic Schr?dinger equation. This leads to exponentially small transmission upon normal incidence. We show that, in the presence of magnetic barriers, such massive Dirac fermions can have transmission even at normal incidence. The general consequences of this behavior for multilayer graphene consisting of massless and massive modes are mentioned. We also briefly discuss the effect of a bias voltage on such magnetotransport. 相似文献
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16.
Kawatkar SP Kuntz DA Woods RJ Rose DR Boons GJ 《Journal of the American Chemical Society》2006,128(25):8310-8319
The X-ray crystal structures of mannose trimming enzyme drosophila Golgi alpha-mannosidase II (dGMII) complexed with the inhibitors mannostatin A (1) and an N-benzyl analogue (2) have been determined. Molecular dynamics simulations and NMR studies have shown that the five-membered ring of mannostatin A is rather flexible occupying pseudorotational itineraries between 2T3 and 5E, and 2T3 and 4E. In the bound state, mannostatin A adopts a 2T1 twist envelope conformation, which is not significantly populated in solution. Possible conformations of the mannosyl oxacarbenium ion and an enzyme-linked intermediate have been compared to the conformation of mannostatin A in the cocrystal structure with dGMII. It has been found that mannostatin A best mimics the covalent linked mannosyl intermediate, which adopts a 1S5 skew boat conformation. The thiomethyl group, which is critical for high affinity, superimposes with the C-6 hydroxyl of the covalent linked intermediate. This functionality is able to make a number of additional polar and nonpolar interactions increasing the affinity for dGMII. Furthermore, the X-ray structures show that the environment surrounding the thiomethyl group of 1 is remarkably similar to the arrangements around the methionine residues in the protein. Collectively, our studies contradict the long held view that potent inhibitors of glycosidases must mimic an oxacarbenium ion like transition state. 相似文献
17.
Abhisek Kar Dr. Jamsad Mannuthodikayil Sameer Singh Anamika Biswas Puneet Dubey Dr. Amit Das Dr. Kalyaneswar Mandal 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(35):14906-14911
We report an operationally simple method to facilitate chemical protein synthesis by fully convergent and one-pot native chemical ligations utilizing the fluorenylmethyloxycarbonyl (Fmoc) moiety as an N-masking group of the N-terminal cysteine of the middle peptide thioester segment(s). The Fmoc group is stable to the harsh oxidative conditions frequently used to generate peptide thioesters from peptide hydrazide or o-aminoanilide. The ready availability of Fmoc-Cys(Trt)-OH, which is routinely used in Fmoc solid-phase peptide synthesis, where the Fmoc group is pre-installed on cysteine residue, minimizes additional steps required for the temporary protection of the N-terminal cysteinyl peptides. The Fmoc group is readily removed after ligation by short exposure (<7 min) to 20 % piperidine at pH 11 in aqueous conditions at room temperature. Subsequent native chemical ligation reactions can be performed in presence of piperidine in the same solution at pH 7. 相似文献
18.
R. P. Rout R. Mishra R. Prajith S. Jalaluddin B. K. Sapra 《Journal of Radioanalytical and Nuclear Chemistry》2014,302(3):1495-1499
In the present study, the deposition velocities of 222Rn/220Rn decay products were measured experimentally using SSNTD based passive detectors, direct radon progeny sensor (DRPS) and direct thoron progeny sensor (DTPS) and the results were compared with obtained values by Monte-Carlo simulations. In both cases, deposition velocities were found to be log-normally distributed and also the experimentally measured geometric mean (GM) and geometric standard deviation (GSD) of (0.12, 1.85) m h?1 for radon decay products and (0.07, 1.75) m h?1 for thoron decay products were found to be in good agreement with the simulated values. 相似文献
19.
Sameer Chavda Elliot Coulbeck Gregory S. Coumbarides Marco Dingjan Jason Eames Stephanos Ghilagaber Yonas Yohannes 《Tetrahedron: Asymmetry》2006,17(24):3386-3399
The resolution of 2-phenylpropanoyl chloride using an equimolar combination of quasi-enantiomeric oxazolidinones is discussed. The levels of diastereoselectivity were found to be dependent upon the structural nature of the metallated oxazolidinone, temperature and metal counter-ion. 相似文献
20.
Haggenmueller R Rahatekar SS Fagan JA Chun J Becker ML Naik RR Krauss T Carlson L Kadla JF Trulove PC Fox DF Delong HC Fang Z Kelley SO Gilman JW 《Langmuir : the ACS journal of surfaces and colloids》2008,24(9):5070-5078
The use of single wall carbon nanotubes (SWCNTs) in current and future applications depends on the ability to process SWCNTs in a solvent to yield high-quality dispersions characterized by individual SWCNTs and possessing a minimum of SWCNT bundles. Many approaches for the dispersion of SWCNTs have been reported. However, there is no general assessment which compares the relative quality and dispersion efficiency of the respective methods. Herein we report a quantitative comparison of the relative ability of "wrapping polymers" including oligonucleotides, peptides, lignin, chitosan, and cellulose and surfactants such as cholates, ionic liquids, and organosulfates to disperse SWCNTs in water. Optical absorption and fluorescence spectroscopy provide quantitative characterization (amount of SWCNTs that can be suspended by a given surfactant and its ability to debundle SWCNTs) of these suspensions. Sodium deoxy cholate (SDOCO), oligonucleotides (GT)(15), (GT)(10), (AC)(15), (AC)(10), C(10-30), and carboxymethylcellulose (CBMC-250K) exhibited the highest quality suspensions of the various systems studied in this work. The information presented here provides a good framework for further study of SWCNT purification and applications. 相似文献