Purification of Single-walled Carbon Nanotubes Grown by a Chemical Vapour Deposition (CVD) Method

ＩｎｔｒｏｄｕｃｔｉｏｎＳｉｎｇｌｅ ｗａｌｌｅｄｃａｒｂｏｎｎａｎｏｔｕｂｅｓ(ＳＷＮＴｓ)ｈａｖｅｂｅｅｎｓｙｎｔｈｅｓｉｓｅｄｂｙｕｓｉｎｇｖａｒｉｏｕｓｍｅｔｈｏｄｓ[1— 3] ａｎｄｔｈｅｃｈｅｍｉｃａｌｖａｐｏｕｒｄｅｐｏｓｉｔｉｏｎ (ＣＶＤ )ｍｅｔｈｏｄｈａｓｂｅｅｎｃｏｎｓｉｄｅｒｅｄａｓａ ｐｒｏｍｉｓｉｎｇｍｅｔｈｏｄｔｏ ｐｒｏｄｕｃｅＳＷＮＴｓｏｎａｎｉｎｄｕｓｔｒｉａｌｓｃａｌｅ[3— 5] .Ｈｏｗｅｖｅｒ ,ａｌｌｔｈｅＳＷＮＴ ｐｒｏｄｕｃｔｓｓｙｎｔｈｅｓｉｓｅｄｔｏｄａｔｅｃｏ…     

Plutonium Isotopes in Sediments from the Sudanese Coast of the Red Sea

This paper presents the activity concentrations of Pu isotopes in surface marine sediments collected from the Sudanese coast of the Red Sea. The following concentration ranges were determined: ²³⁸Pu, 4.7–28.6 mBq/kg; ^239+240Pu, 53–343 mBq/kg dry weight. The average activity ratios of ²³⁸Pu/^239+240Pu (0.075±0.045 mBqk/kg) and ^239+240Pu/¹³⁷Cs (0.026±0.025 mBq/kg) are appropriately comparable to the literature values that are characteristic of the global fallout from the atmospheric nuclear weapon tests. However, ^239+240Pu/¹³⁷Cs ratio in sediments collected from the biologically rich fringing reef is an order of magnitude higher compared to other sampling locations.     

Poly(diphenylacetylene)s with Electron‐Donating Alkoxy and Electron‐Withdrawing Fluoroalkyl Groups: Effect of the Substituent on Fluorescence

New poly(diphenylacetylene)s with alkoxy and fluoroalkyl groups as electron‐donating and electron‐withdrawing groups, respectively, were synthesized by using a WCl₆‐n‐Ph₄Sn catalyst. The polymer solutions emitted strong, bluish‐green lights when photo‐excited. The polymers that contained the electron‐donating alkoxy groups showed longer fluorescence‐maximum peaks when compared to the polymers that contained the electron‐withdrawing fluoroalkyl groups. However, such an effect of the substituent on the absorption property was not clearly seen. The emission bands of the solid films did not show any significant red shift, relative to that of the dilute solution.

     

A study on radial directional natural frequency and damping ratio in a vehicle tire

The measurement of radial directional natural frequency and damping ratio in a vehicle tire has been studied. Natural frequencies and damping ratios in the radial direction of various tires, from passenger car tires to truck bus tires, are reported. The radial direction modal parameters of tires subjected to different levels of inflation pressure, have been determined by using a frequency response function method. To obtain the theoretical natural frequency and mode shape, the plane vibration of a tire has been modeled as though it were that of a circular beam. By using the Tielking method that is based on Hamilton’s principle, theoretical results have been determined by considering the rotational velocity, tangential and radial stiffness, radial directional velocity and tension force which is due to tire inflation pressure. The results show that experimental conditions can be considered as the parameters that shift the natural frequency and damping ratio.     

SCOTfluors: Small,Conjugatable, Orthogonal,and Tunable Fluorophores for In Vivo Imaging of Cell Metabolism

The transport and trafficking of metabolites are critical for the correct functioning of live cells. However, in situ metabolic imaging studies are hampered by the lack of fluorescent chemical structures that allow direct monitoring of small metabolites under physiological conditions with high spatial and temporal resolution. Herein, we describe SCOTfluors as novel small‐sized multi‐colored fluorophores for real‐time tracking of essential metabolites in live cells and in vivo and for the acquisition of metabolic profiles from human cancer cells of variable origin.     

Discretisation and duality of optimal Skorokhod embedding problems

We prove a strong duality result for a linear programming problem which has the interpretation of being a discretised optimal Skorokhod embedding problem, and we recover this continuous time problem as a limit of the discrete problems. With the discrete setup we show that for a suitably chosen objective function, the optimiser takes the form of a hitting time for a random walk. In the limiting problem we then reprove the existence of the Root, Rost, and cave embedding solutions of the Skorokhod embedding problem.The main strength of this approach is that we can derive properties of the discrete problem more easily than in continuous time, and then prove that these properties hold in the limit. For example, a consequence of the strong duality result is that dual optimisers exist, and our limiting arguments can be used to derive properties of the continuous time dual functions. These arguments are applied in Cox and Kinsley (2017), where the existence of dual solutions is required to prove characterisation results for optimal barriers in a financial application.     

Post Recognition Speech Localization

How much does knowledge regarding a certain spoken word or phrase help with its localization? This is a very fundamental question for speech processing, and will be partially addressed in this paper. In particular, this work will utilize prior information regarding the contents of a speech signal in order to improve the artificial localization of it using Time delay of arrival (TDOA) between two microphones. The prior information, which is used to develop a very simple frequency-selective phase transform (FPT), increases the effective SNR by only using a subset of the highest SNR frequencies in the Phase Transform. Simulations in a reverberant environment show that the proposed approach can more robustly and accurately localize speech sources. For 20 ms signal segments, it is shown that using a subset of 45 percent of available speech frequency bins is superior to using 30, 60, or 100, where using 100 corresponds to the standard Phase Transform.     

Local connectivity functions on arcwise connected spaces and certain continua

Types of spaces are given on which every local connectivity function is a connectivity function, a connected function, or a Darboux function. A complete determination such spaces is obtained when the spaces are assumed to be arc-like continua or circle-like continua. Results provide answers to a question asked by Stallings.     

Computations of flow over a flexible plate using the hybrid Cartesian/immersed boundary method

A hybrid Cartesian/immersed boundary code is developed and applied to interactions between a flexible plate and a surrounding fluid. The velocities at the immersed boundary (IB) nodes are reconstructed by interpolations along local normal lines to an interface. A new criterion is suggested to distribute the IB nodes near an interface. The suggested criterion guarantees a closed fluid domain by a set of the IB nodes and it is applicable to a zero‐thickness body. To eliminate the pressure interpolation at the IB nodes, the hybrid staggered/non‐staggered grid method is adapted. The developed code is validated by comparisons with other experimental and computational results of flow around an in‐line oscillating cylinder. Good agreements are achieved for velocity profiles and vorticity and pressure contours. As applications to the fluid–structure interaction, oscillations of flexible plate in a resting fluid and flow over a flexible plate are simulated. The elastic deformations of the flexible plate are modelled based on the equations of motion for plates considering the fluid pressure as the external load on the plate. Two non‐dimensional parameters are identified and their effects on the damping of the plate motion are examined. Grid convergence tests are carried out for both cases. Copyright © 2007 John Wiley & Sons, Ltd.     

Dependence of the heavy-hole exciton reduced mass on quantum-well size in InGaAs/GaAs heterostructures

We present low temperature photoluminescence investigations of the exciton ground state of In_0.14Ga_0.86As/GaAs quantum wells (QW) in the presence of pulsed magnetic fields up to 50 T. The exciton in-plane reduced mass and the heavy-hole in-plane mass are determined from the best fit of theoretical calculations to the magnetic field dependence of PL peaks. When the QW thickness decreases, their masses increases due to valence-band mixing effect.