胆固醇修饰富勒烯/γ-环糊精包结复合物的生物活性

采用Bingel-Hirsch反应合成了胆固醇修饰的富勒烯(CHL-C60), 通过核磁共振(NMR)、质谱(MS)、元素分析对CHL-C60的化学结构进行了表征. γ-环糊精(γ-CD)对甾环具有较强的包结能力, 能够与CHL-C60形成包结复合物(CHL-C60/γ-CD), 从而有效提高CHL-C60的水溶性. 紫外-可见吸收光谱和荧光光谱研究结果表明, CHL-C60能够从γ-CD的疏水空腔中解离出来, 与人血清白蛋白(HSA)及牛血清白蛋白(BSA)形成稳定的复合体, 其结合常数分别为5.73×104和7.05×104 L·moL-1. 无氧条件下, CHL-C60/γ-CD通过光诱导电子转移作用断裂pBR322质粒脱氧核糖核酸(DNA), 其效率可达60.5%.     

基于像散与理想光源成像原理的高亮度半导体激光器光纤耦合设计方法

运用像散原理和理想光源成像原理,讨论了半导体激光器消像散设计.提出了一种基于消像散的高亮度半导体激光器光纤耦合系统的设计方法.以波长为808 nm,输出功率为10 W的半导体激光器的光纤耦合为例,给出了详细的计算方法和设计步骤.结果表明:采用该方法将半导体激光器光束耦合入数值孔径为0.22,芯径为50 μm的光纤中,耦...     

The Quantum Double Model with Boundary: Condensations and Symmetries

Associated to every finite group, Kitaev has defined the quantum double model for every orientable surface without boundary. In this paper, we define boundaries for this model and characterize condensations; that is, we find all quasi-particle excitations (anyons) which disappear when they move to the boundary. We then consider two phases of the quantum double model corresponding to two groups with a domain wall between them, and study the tunneling of anyons from one phase to the other. Using this framework we discuss the necessary and sufficient conditions when two different groups give the same anyon types. As an application we show that in the quantum double model for S ₃ (the permutation group over three letters) there is a chargeon and a fluxion which are not distinguishable. This group is indeed a special case of groups of the form of the semidirect product of the additive and multiplicative groups of a finite field, for all of which we prove a similar symmetry.     

二波混频高功率单频窄线宽光纤激光器

设计并制造了一种基于二波混频的高功率单频窄线宽光纤激光器.激光器采用长线形腔结构,以Er3+/Yb3+双包层光纤作为增益介质,利用输出信号光分束反馈注入,与腔内振荡激光混频干涉,形成分布的增益光栅与折射率光栅共同作用选模,获得稳定的1550.63 nm单频高功率激光输出.在975 nm多模激光二极管(LD)抽运下,激光...     

Minimal integer automaton behind crystal plasticity

Power law fluctuations and scale-free spatial patterns are known to characterize steady state plastic flow in crystalline materials. In this Letter we study the emergence of correlations in a simple Frenkel-Kontorova-type model of 2D plasticity which is largely free of arbitrariness, amenable to analytical study, and is capable of generating critical exponents matching experiments. Our main observation concerns the possibility to reduce continuum plasticity to an integer-valued automaton revealing inherent discreteness of the plastic flow.     

On the Constant Metric Dimension of Generalized Petersen Graphs P（n, 4）

In this paper,we consider the family of generalized Petersen graphs P(n,4).We prove that the metric dimension of P(n,4) is 3 when n ≡ 0(mod 4),and is 4 when n = 4k + 3(k is even).For n ≡ 1,2(mod 4) and n = 4k + 3(k is odd),we prove that the metric dimension of P(n,4) is bounded above by 4.This shows that each graph of the family of generalized Petersen graphs P(n,4)has constant metric dimension.     

点可迁图的限制边连通性

3限制边割是连通图的一个边割, 它将此图分离成阶不小于3的连通分支. 图G的最小3限制边割所含的边数称为此图的3限制边连通度, 记作λ\-3(G). 它以图G的3阶连通点导出 子图的余边界的最小基数ξ_3(G)为上界. 如果λ_3(G)=ξ_3(G), 则称图G是极大3限制边连通的 . 已知在某种程度上,3限制边连通度较大的网络有较好的可靠性. 作者在文中证明: 如果k正则连通点可迁图的 围长至少是5, 那么它是是极大3限制边连通的.     

A HYDROGEN BONDING ASSISTED CATALYST SCREENED OUT VIA COMBINATORIAL CHEMISTRY STRATEGY

1. INTRODUCTIONReduction of organic compounds by NaBH, is often used in organic synthesis. The reactiollis only proceeded in the interface between the organic phase and water phase because of the lowsolubility of NaBH. in organic compounds, and this results in the slow reaction rate and lowyield. In order to increase the reaction rate and yield, NaBH, was converted totetraalkylammonium borohydrides II' 'l, and this made the operating process complex and greatamount of quaternary ammon…     

原子相干态中的压缩现象

计算表明,与场的相干态类似的原子相干态,具有不同于场的相干态的压缩行为;进一步证明:直接类比于(?)(ξ)不能得到“原子压缩算符”.