全文获取类型
收费全文 | 382篇 |
免费 | 16篇 |
国内免费 | 2篇 |
专业分类
化学 | 195篇 |
晶体学 | 7篇 |
力学 | 14篇 |
数学 | 119篇 |
物理学 | 65篇 |
出版年
2023年 | 1篇 |
2022年 | 12篇 |
2021年 | 16篇 |
2020年 | 8篇 |
2019年 | 10篇 |
2018年 | 8篇 |
2017年 | 13篇 |
2016年 | 16篇 |
2015年 | 18篇 |
2014年 | 18篇 |
2013年 | 37篇 |
2012年 | 29篇 |
2011年 | 23篇 |
2010年 | 21篇 |
2009年 | 26篇 |
2008年 | 18篇 |
2007年 | 16篇 |
2006年 | 12篇 |
2005年 | 14篇 |
2004年 | 9篇 |
2003年 | 8篇 |
2002年 | 8篇 |
2001年 | 8篇 |
2000年 | 8篇 |
1999年 | 4篇 |
1998年 | 3篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1987年 | 1篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1982年 | 2篇 |
1979年 | 2篇 |
1977年 | 4篇 |
1975年 | 3篇 |
1973年 | 2篇 |
1961年 | 1篇 |
排序方式: 共有400条查询结果,搜索用时 0 毫秒
11.
Mustafa A. Jihad Farah T. M. Noori Majid S. Jabir Salim Albukhaty Faizah A. AlMalki Amal A. Alyamani 《Molecules (Basel, Switzerland)》2021,26(11)
Flaky graphene oxide (GO) nanoparticles (NPs) were synthesized using Hummer’s method and then capped with polyethylene glycol (PEG) by an esterification reaction, then loaded with Nigella sativa (N. sativa) seed extract. Aiming to investigate their potential use as a smart drug delivery system against Staphylococcus aureus and Escherichia coli, the spectral and structural characteristics of GO-PEG NPs were comprehensively analyzed by XRD, AFM, TEM, FTIR, and UV- Vis. XRD patterns revealed that GO-PEG had different crystalline structures and defects, as well as a higher interlayer spacing. AFM results showed GONPs with the main grain size of 24.41 nm, while GONPs–PEG revealed graphene oxide aggregation with the main grain size of 287.04 nm after loading N. sativa seed extract, which was verified by TEM examination. A strong OH bond appeared in FTIR spectra. Furthermore, UV- Vis absorbance peaks at (275, 284, 324, and 327) nm seemed to be correlated with GONPs, GO–PEG, N. sativa seed extract, and GO –PEG- N. sativa extract. The drug delivery system was observed to destroy the bacteria by permeating the bacterial nucleic acid and cytoplasmic membrane, resulting in the loss of cell wall integrity, nucleic acid damage, and increased cell-wall permeability. 相似文献
12.
Tahira Foyzun Abdullah Al Mahmud Md. Salim Ahammed Md. Imran Nur Manik Md. Kamrul Hasan KM Monirul Islam Simin Sobnom Lopa Md. Yusuf Al-Amin Kushal Biswas Mst. Rejina Afrin AHM Khurshid Alam Golam Sadik 《Molecules (Basel, Switzerland)》2022,27(3)
Neurotoxicity is a serious health problem of patients chronically exposed to arsenic. There is no specific treatment of this problem. Oxidative stress has been implicated in the pathological process of neurotoxicity. Polyphenolics have proven antioxidant activity, thereby offering protection against oxidative stress. In this study, we have isolated the polyphenolics from Acacia nilotica and investigated its effect against arsenic-induced neurotoxicity and oxidative stress in mice. Acacia nilotica polyphenolics prepared from column chromatography of the crude methanol extract using diaion resin contained a phenolic content of 452.185 ± 7.879 mg gallic acid equivalent/gm of sample and flavonoid content of 200.075 ± 0.755 mg catechin equivalent/gm of sample. The polyphenolics exhibited potent antioxidant activity with respect to free radical scavenging ability, total antioxidant activity and inhibition of lipid peroxidation. Administration of arsenic in mice showed a reduction of acetylcholinesterase activity in the brain which was counteracted by Acacia nilotica polyphenolics. Similarly, elevation of lipid peroxidation and depletion of glutathione in the brain of mice was effectively restored to normal level by Acacia nilotica polyphenolics. Gallic acid methyl ester, catechin and catechin-7-gallate were identified in the polyphenolics as the major active compounds. These results suggest that Acacia nilotica polyphenolics due to its strong antioxidant potential might be effective in the management of arsenic induced neurotoxicity. 相似文献
13.
Launch power is limited to the milliwatt level by stimulated Brillouin scattering (SBS) in a single-channel, coherent fiber-optic network. Increasing the number of frequency-division multiplexed channels causes the power limit to decrease quickly to submilliwatt levels due to three-wave intermodulation to keep the signal-to-noise ratio from deteriorating significantly. As the number of channels increases, stimulated Raman scattering (SRS) begins to dominate. If a maximum of 0.5-dB depletion in the highest-frequency channel is allowed, SRS dominates when the number of multiplexed channels reaches about 300. Generally, the launch-power-limiting phenomenon is dependent on the number of channels being multiplexed. 相似文献
14.
Summary The author proves the consistency of a nearest neighbor estimator of the Lyapunov exponent for a general class of one-dimensional
ergodic dynamical systems. The author shows that this estimator has good practical properties on a set of simulations. 相似文献
15.
E. Elbaz M. Novello J. M. Salim M. C. Motta da Silva R. Klippert 《General Relativity and Gravitation》1997,29(4):481-487
We give a general Hamiltonian formulation of the Friedmann-Robertson-Walker (FRW) fundamental equations of a homogeneous and isotropic universe in the Standard Cosmological model. It gives some interesting insight on the 3-curvature of the universe, which is found to be obtained in terms of the scale factor (also termed radius of the universe) and its first derivative. It also leads to an easy determination of the Schrödinger equation for the (R) wave function of the universe, in the radiative era. 相似文献
16.
Salim Derrouiche 《Applied Surface Science》2007,253(13):5894-5898
The heats of adsorption at several coverages of the linear and bridged CO species (denoted L and B, respectively) adsorbed on the Pt0 sites of the 2.9 wt% Pt/10% K/Al2O3 catalyst are determined using the Adsorption Equilibrium Infrared spectroscopy method. The addition of K on 2.9% Pt/Al2O3 modifies significantly the adsorption of CO on the Pt particles: (a) the ratio L/B is decreased from 8.4 to 1, (b) a new adsorbed CO species is detected with an IR band at 1763 cm−1, (c) the heats of adsorption of L and B CO species are significantly altered and the positions of their IR bands are shifted. The heats of adsorption of L CO species are decreased: i.e. 206 and 105 kJ/mol at low coverages on Pt/Al2O3 and Pt/K/Al2O3 respectively. Two B CO species denoted B1 and B2, with different heats of adsorption are observed on Pt/K/Al2O3. The heats of adsorption of B2 CO species (major B CO species) are significantly larger than those measured in the absence of K: i.e. 94 and 160 kJ/mol at low coverages on Pt/Al2O3 and Pt/K/Al2O3 respectively, whereas those of B1 CO species (minor species) are similar: 90 kJ/mol at low coverages. These values are consistent with the qualitative High Resolution Electron Energy Loss Spectrometry literature data on Pt(1 1 1) modified by potassium. 相似文献
17.
18.
In this paper, firstly, our purpose is to give the relationship among the densities of the sets of collinear points, the relationship among the densities of the sets of noncollinear points, and the relationship among the densities of the sets of the intersecting lines in Euclidean plane, respectively. In addition to that, we define the density formulas for the sets of points and lines under the two‐parameter planar Euclidean motion. By means of these results, we obtain essential properties that explain the connection among the densities of the sets of points and among the densities of the sets of intersecting lines under the two‐parameter planar Euclidean motion. 相似文献
19.
Israr U. Hassan Hiba Salim Gowhar A. Naikoo Tasbiha Awan Riyaz A. Dar Fareeha Arshad Mohammed A. Tabidi Ratnesh Das Waqar Ahmed Abdullah M. Asiri Ahsanulhaq Qurashi 《Journal of Saudi Chemical Society》2021,25(5):101228
The remarkable significance of electrode materials in industrial processes, energy, sustainability and diabetes monitoring has captivated scientists to develop advance nanomaterials for the benefit of life across the globe. Here in, the recent developments in nanostructured porous metal and metal oxide composite materials for supercapacitor applications and non-enzymatic glucose sensors (NEGS) has been extensively discussed. The essential and active electrode materials from the research and application perspective has been emphasized in detail. We have also evaluated the worthiness, taxonomical classification, efficiency, specific capacitance and sensitivity of these materials for the aforementioned potential applications. Eventually, we concluded the review by providing the aspect ratio, surface morphology, particle size and specific surface area of these materials that plays an indispensable role for their promising potential applications. 相似文献
20.
Azaiez Ben Akacha Salim Barkallah Belgacem Baccar 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-2):163-166
Abstract Under the normal conditions, the reaction of hydrazine and methylhydrazine with OO-diethyl 1 oxoalkane phosphonates 1 proceeds by cleavage of the phosphorus-carbon bond and leads to the formation of diethylphosphite 2 and N-acylhydrazide 3 . A procedure has been developed for the synthesis of new primary hydrazone of OO-diethyl 1-oxoalkane phosphonates 4 . A mechanism is proposed. The structure of those compounds 4 was confirmed by NMR and IR spectroscopy. 相似文献